期刊
MOLECULAR CATALYSIS
卷 535, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.mcat.2022.112819
关键词
Alkylation; DHPs; Radical cascade cyclization; Ynones
In this study, a direct and efficient visible-light-induced cascade cyclization reaction of aryl ynones with 4-alkyl-DHPs was investigated to achieve the divergent synthesis of indenones, thioflavones, and spiro[5.5]trienones via a 5-exo-trig or 6-exo-trig radical cyclization. This cascade reaction demonstrates operational simplicity, metal- and oxidant-free conditions, and excellent functional group tolerance.
A direct and efficient visible-light-induced cascade cyclization reaction of aryl ynones with 4-alkyl-DHPs for the divergent synthesis of indenones, thioflavones and spiro[5.5]trienones via a 5-exo-trig or 6-exo-trig radical cyclization. This cascade reaction features operational simplicity, metal-and oxidant-free, and excellent func-tional group tolerance.
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