期刊
ADVANCED MATERIALS
卷 27, 期 38, 页码 5720-5725出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201405573
关键词
self-assembly; statistical mechanics; surfaces
类别
资金
- Office of Science, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-AC02-05CH11231]
The self-assembly of molecules at surfaces can be caused by a range of physical mechanisms. Assembly can be driven by intermolecular forces, or molecule-surface forces, or both; it can result in structures that are in equilibrium or that are kinetically trapped. Here we review examples of self-assembly at surfaces focusing on a physical understanding of what causes patterns seen in experiment. Some apparently disparate systems can be described in similar physical terms, indicating that simple factors - such as the geometry and energy scale of intermolecular binding - are key to understanding the self-assembly of those systems.
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