期刊
INORGANIC CHEMISTRY FRONTIERS
卷 10, 期 1, 页码 280-287出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qi02118h
关键词
-
资金
- Natural Science Foundation of Gansu Province
- [20JR10RA241]
This study demonstrates the potential of p-block Sn-based materials as NORR catalysts and develops a SnS2-x catalyst using a defect engineering strategy. The catalyst exhibits exceptional NH3-faradaic efficiency and NH3 yield rate, and theoretical computations reveal that its high NORR performance is attributed to the active Sn-V-S sites.
Electrocatalytic NO reduction to NH3 (NORR) has emerged as an attractive approach for simultaneously realizing NO abatement and ammonia generation. Herein, we demonstrate for the first time that p-block Sn-based materials are promising NORR catalysts. A defect engineering strategy is employed to develop a SnS2-x catalyst enriched with S-vacancy (V-S) defects. SnS2-x delivers an exceptional NH3-faradaic efficiency of 90.3% with an NH3 yield rate of 78.6 mu mol h(-1) cm(-2), outperforming most reported d-block NORR catalysts. Theoretical computations unveil that the high NORR performance of SnS2-x arises from the active Sn-V-S sites which can selectively activate NO and reduce the energy barriers of the NORR pathway.
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