4.7 Article

Regulatory Significance of Plastic Manufacturing Air Pollution Discharged into Terrestrial Environments and Real-Time Sensing Challenges

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ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS
卷 10, 期 2, 页码 152-158

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AMER CHEMICAL SOC
DOI: 10.1021/acs.estlett.2c00710

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Air chemical monitoring; Volatile organic compounds (VOCs); Plastic lining; Low-cost VOC sensors; Emission factors

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CIPP is a plastic manufacturing technology used in the U.S. that has not been evaluated for compliance with federal air pollution laws. The study found that the emissions of VOCs during CIPP manufacturing were not limited to the curing period but also before and after. Styrene and other hazardous air pollutants were emitted. The estimated VOC emissions for styrene CIPPs ranged from 0.9 to 16.6 U.S. tons, and for nonstyrene CIPPs ranged from 0.09 to 1.6 U.S. tons. Low-cost VOC sensors were found to be unreliable for accurately measuring styrene emissions.
Cured-in-place-pipe (CIPP) is an onsite plastic manufacturing technology used in the U.S. and has not been evaluated for regulatory compliance with federal air pollution laws. The practice involves the discharge of manufacturing waste into the environment. The study goal was to estimate the magnitude of volatile organic compounds (VOCs) discharged into the atmosphere for styrene and nonstyrene composite manufacture and examine low-cost air monitoring sensor reliability. Time -resolved emission analysis revealed that VOC emission was not only isolated to the thermal curing period but also occurred before and after curing. In addition to the styrene monomer, other gas -phase hazardous air pollutants regulated under the Clean Air Act were also emitted. Based on typical CIPP installations, 0.9 to 16.6 U.S. tons of emitted VOCs were estimated for styrene CIPPs, and 0.09 to 1.6 U.S. tons of emitted VOCs were estimated for nonstyrene CIPPs. Because the number and size of CIPPs manufactured in a single community can vary, the total air pollution burden will significantly differ across communities. Low-cost VOC sensors commonly utilized near CIPP manufacturing activities did not accurately quantify styrene and should not be relied upon for that purpose. Up to several thousand-fold detection differences were observed. Regulatory evaluation of CIPP air pollution and PID sensor reliability assessments are recommended.

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