期刊
JOURNAL OF POWER SOURCES
卷 333, 期 -, 页码 156-163出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2016.09.153
关键词
Nickel hydroxide; Fluffy graphene sheets; Pesudocapacitor; Nanocomposite
资金
- National Natural Science Foundation of China [51272045, 51503038]
A novel Ni(OH)(2)/graphene nanosheets (GNs) composite with Ni(OH)(2) nanoflakes dispersing within a 3D fluffy and conductive graphene network has been successfully prepared by a facile hydrothermal reaction for pseudocapacitor applications. Using the as-prepared Ni(OH)(2)/GNs composite as active material, the pseudocapacitor electrode exhibits very high capacitance and encouraging rate capability, as indicated by the experimental results that its specific capacitance is 2260 F g(-1) at a current density of 1 A g(-1) and 1401 F g(-1) when the current density is increased to 10 A g(-1) (61.9% retention). In addition, its shows remarkable long-term cycling stability, with a high capacitance retention of 115.6% at 100 mV s(-1) after 4000 cycles and only 2.6% of decay at a current density of 16 A g(-1) over 1000 cycles. The excellent electrochemical performance of the Ni(OH)(2)/GNs composite electrode is ascribed to its enhanced ion and electron transport kinetic arising from its unique microstructure, namely a 3D electron conductive graphene network with ion diffusive fluffy pathways. Therefore, the Ni(OH)2/GNs composite electrode is a promising candidate for high performance pseudocapacitors; the fluffy crystalline GNs are promising matrix for advanced energy materials with ensured ion and electron conductivities. (C) 2016 Elsevier B.V. All rights reserved.
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