期刊
JOURNAL OF POWER SOURCES
卷 325, 期 -, 页码 682-689出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2016.06.081
关键词
Li-ion battery; Scanning microscopy; Micropipette; Nanoparticles; Electrochemistry
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC) [CRDPJ 445519-12]
- General Motors Canada [NSERC/McMaster/APCPJ 412488-11]
- iNano
- Nanoquebec [R7-RD022]
We present herein localized galvanostatic and potentiodynamic measurements on lithium iron phosphate (LFP) particles, using the combination of a scanning micropipette contact method (SMCM) and scanning electron microscopy (SEM). The proposed technique allows small substrate areas (similar to 10 mu m in diameter) decorated with LFP particles to be probed within a lithium electrolyte solution in organic carbonate solvents (0.1 M LiClO4 in propylene carbonate in the present study). SEM images of the scanned area allow the correlation of each electrochemical response to the number, and volume of the probed particles. Under favorable conditions, single particles are found within the measurement areas, thus enabling the determination of single particle properties in an anaerobic environment without the additional complications arising from the presence of binders and electronically conductive fillers. The ability to analyze a material with complementary experimental techniques at the single particle level should create new opportunities for fundamental studies and for the quality control of granular materials. (C) 2016 Elsevier B.V. All rights reserved.
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