4.7 Article

Ion Lithography of Single Ions Irradiation for Spatially Regular Arrays of Pores in Membranes of Polyethylene Terephthalate

期刊

NANOMATERIALS
卷 12, 期 22, 页码 -

出版社

MDPI
DOI: 10.3390/nano12223927

关键词

polyethylene terephthalate; ion lithography; membrane; STIM; pore size-shape simulation; microfluidics; organ-on-chips

资金

  1. RDE, MEYS, Czech Republic under the project CANAM OP [CZ.02.1.01/0.0/0.0/16_013/0001812]
  2. Czech Science Foundation [22-10536S]
  3. Research Infrastructure NanoEnviCz [LM2018124]
  4. project Pro-NanoEnviCz - Ministry of Education, Youth and Sports of the Czech Republic [CZ.02.1.01/0.0/0.0/16_013/0001821, CZ.02.1.01/0.0/0.0/18_046/0015586]
  5. European Union-European Structural and Investments Funds in the frame of the Operational Programme Re-search Development and Education

向作者/读者索取更多资源

This study focuses on using low-energy ions to fabricate membranes with higher surface density and negligible overlapping pores. The results have potential applications in fields such as microfluidics and organ-on-chip microsystems.
Routinely, in membrane technology, the decay from radioactive particles or the bombardment of ions with MeV energy per nucleon have been employed for the production of narrow and long pores in membranes. Presently, the ion lithography is proposed to make the fabrication cost more affordable. It is prospective for the use of medium capacity accelerators making more feasible the fabrication of customized membranes. Thin polyethylene terephthalate foils have been patterned using 12 MeV O5+ ions and then processed to obtain good aspect ratio ion track pores in membranes. Pores of micrometric diameter with the following profiles were fabricated in the membranes: truncated cone, double conical, ideal cone, and cylindrical. Monitoring of the shape and size of pores has been attempted with a combination of Scanning Transmission Ion Microscope and a newly designed simulation program. This study is focused on the use of low-energy ions, accomplished in all laboratories, for the fabrication of membranes where the pores are not randomly traced and exhibit higher surface density and negligible overlapping than in membranes commonly manufactured. The good reproducibility and the ordered pore locations can be potentially utilized in applications such as microfluidics and organ-on-chip microsystems, where cells growing over porous substrates are used in simulation of biological barriers and transport processes.

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