期刊
JOURNAL OF POWER SOURCES
卷 319, 期 -, 页码 271-280出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2016.04.030
关键词
Graphene hybrid fibers; Poly(vinyl alcohol); Liquid-crystals; Wet-spinning; Wearable supercapacitors
资金
- Natural Science Foundation of China [51273040]
- Program for Changjiang Scholars and Innovative Research Team in University [T2011079, IRT1221]
- National Natural Science Foundation for Distinguished Young Scholar of China [50925312]
- Program of Introducing Talents of Discipline to Universities in China [111-2-04]
Graphene fibers based flexible supercapacitors have great potential as wearable power sources for textile electronics. However, their electrochemical performance is limited by the serious stacking of graphene sheets and their hydrophobicity in aqueous electrolytes. Meanwhile, their brittleness is unfavorable for practical application. Incorporation of nanofillers into graphene fibers has been proved effective for enhancing their capacitance, whereas often leading to deteriorated mechanical strength. Herein we demonstrate that the strength, toughness and capacitive performance of graphene-based fibers can be significantly enhanced simultaneously, simply by incorporating hydrophilic poly(vinyl alcohol) (PVA) into a non-liquid-crystalline graphene oxide (GO) dispersion before wet spinning and chemical reduction. The structure and properties of the resulted PVA/graphene hybrid fibers are systematically investigated, and the mechanism behind these enhancements is discussed in detail. The hybrid fiber with a PVA/GO weight ratio of 10/90 possesses a strength of 186 MPa, a toughness of 11.3 J cm(-3), and a capacitance of 241 F cm(-3) in 1 M H2SO4. A solid-state yarn supercapacitor assembled from these fibers exhibits a device energy of 5.97 mW h cm(-3), and features excellent flexibility and bending stability. This device is robust enough to be integrated into textile and thus promising as wearable power supply for smart textiles. (C) 2016 Elsevier B.V. All rights reserved.
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