期刊
NANOMATERIALS
卷 13, 期 3, 页码 -出版社
MDPI
DOI: 10.3390/nano13030530
关键词
lithium aluminosilicate glass-ceramics; cluster-plus-glue-atom model; average cation valence; light-transmitting glass-ceramics; mechanical property; structural analysis
For the first time, a cluster-plus-glue-atom model was used to optimize the composition of lithium aluminosilicate glass-ceramics. By adjusting the ratio of {M2O3} and {Li2O}, the composition of the basic glass was optimized. After heat treatment, the crystal size, proportion, and crystallinity of the glass-ceramics changed significantly. The optimized glass-ceramics showed improved crystallinity, with a maximum crystallinity over 90%, as well as higher bending strength, microhardness, and visible light transmission rate.
In this study, for the first time, a cluster-plus-glue-atom model was used to optimize the composition of lithium aluminosilicate glass-ceramics. Basic glass in glass-ceramics was considered to be a 16-unit combination of three-valence {M2O3} and one-valence {Li2O} units. By adjusting the ratio of {M2O3} and {Li2O}, the composition of basic glass could be optimized. After optimization, the average cation valence of the base glass was increased to 2.875. After heat treatment of the optimized base glass, it is found that the crystal size, proportion, and crystallinity changed obviously compared with that before optimization. The main crystalline phases of all the lithium aluminosilicate glass-ceramics prepared in this work were Li2Si2O5 and LiAlSi4O10. All optimized glass-ceramics had an obvious improvement in the crystallinity, with one of the largest having a crystallinity of over 90%. Furthermore, its bending strength was 159 MPa, the microhardness was 967 Hv, and the visible light transmission rate exceeded 90%. Compared with the widely used touch panel cover glass, the optical properties were close, and the mechanical properties were greatly improved. Due to its excellent performance, it could be used in microelectronics, aerospace, deep-sea exploration, and other fields.
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