Highly Dispersed Ni on Nitrogen-Doped Carbon for Stable and Selective Hydrogen Generation from Gaseous Formic Acid

Article Chemistry, Physical

Efficient nickel and copper-based catalysts supported on modified graphite materials for the hydrogen production from formic acid decomposition

B. M. Faroldi et al.

Summary: The bimetallic Ni-Cu catalyst doped with potassium exhibited the best catalytic performance in the formic acid decomposition reaction, with high conversion rate and selectivity to hydrogen.

APPLIED CATALYSIS A-GENERAL (2022)

添加到收藏夹

Review Chemistry, Physical

Catalysts with single metal atoms for the hydrogen production from formic acid

Dmitri A. Bulushev et al.

Summary: Formic acid can be used as a hydrogen donor in hydrogen production and transfer reactions catalyzed by metal and metal-complex catalysts. This review highlights the potential of heterogeneous catalysts with single metal atoms stabilized by pyridinic nitrogen atoms on the edge or vacancy sites of graphene sheets. Understanding the nature and coordination of single-atom active sites is crucial for enhancing the performance of catalysts in these reactions, with the aim of developing novel and efficient catalysts.

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING (2022)

添加到收藏夹

Article Chemistry, Physical

Ni-based electrocatalysts for unconventional CO2 reduction reaction to formic acid

Enrico Lepre et al.

Summary: Electrochemical reduction of CO2 is an important utilization method, and the loading of nickel single atoms on carbon supports offers a promising catalytic solution. The use of carbonaceous supports with high heteroatom content allows for efficient and stable reduction reactions, producing products with high selectivity.

NANO ENERGY (2022)

添加到收藏夹

Article Chemistry, Physical

Constructing single-atomic nickel sites in carbon nanotubes for efficient CO2 electroreduction

Shide Wu et al.

Summary: This study presents a one-pot pyrolysis strategy to construct N-coordinated single-atomic Ni active sites embedded in porous carbon nanotubes as an efficient electrocatalyst for electrochemical CO2 reduction (ECR). The electrocatalyst exhibits excellent ECR performance with high CO faradaic efficiency and turnover frequency, and maintains stability over a wide potential range.

CARBON (2022)

添加到收藏夹

Article Engineering, Environmental

Selective transfer hydrogenation coupling of nitroaromatics to azoxy/azo compounds by electron-enriched single Ni-N4 sites on mesoporous N-doped carbon

Ting Zhang et al.

Summary: This study presents a microwave-assisted pyrolysis strategy to prepare a unique non-precious metal catalyst with high turnover frequency and selectivity for the transfer hydrogenation coupling reaction of nitroaromatics.

CHEMICAL ENGINEERING JOURNAL (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dynamic Activation of Adsorbed Intermediates via Axial Traction for the Promoted Electrochemical CO2 Reduction

Xinyue Wang et al.

Summary: An axial traction strategy was developed to optimize the electronic structure of the M-N-4 moiety, leading to atomically dispersed nickel sites coordinated with four nitrogen atoms and one axial oxygen atom embedded within the carbon matrix (Ni-N-4-O/C). This Ni-N-4-O/C electrocatalyst exhibited excellent CO2RR performance with a high CO Faradic efficiency close to 100% at -0.9 V, maintaining the CO FE above 90% in a wide potential window. The superior CO2RR activity is attributed to the axial traction effect induced by the Ni-N-4-O active moiety.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Physical

Ni-N4 sites in a single-atom Ni catalyst on N-doped carbon for hydrogen production from formic acid

Dmitri A. Bulushev et al.

Summary: The study synthesized single-atom 1 wt% Ni catalysts for hydrogen production from formic acid through simple impregnation, and elucidated the nature of the Ni site and proposed a reaction mechanism. The catalytic activities of single-atom and traditional catalysts were similar, with the mechanism involving participation of Ni and N atoms in formate formation and a highest energy barrier of 1.088 eV for the recombination of hydrogen atoms.

JOURNAL OF CATALYSIS (2021)

添加到收藏夹

Article Chemistry, Physical

Porosity and composition of nitrogen-doped carbon materials templated by the thermolysis products of calcium tartrate and their performance in electrochemical capacitors

Alina D. Nishchakova et al.

Summary: Porous nitrogen-doped carbon materials were synthesized using template nanoparticles produced by the decomposition of calcium tartrate in thermal shock conditions. Increasing the synthesis temperature led to more ordered graphitic layers but decreased specific surface area and total pore volume. The material synthesized at 750 degrees Celsius showed the best electrochemical performance due to the presence of pyridinic nitrogen, graphitic nitrogen, and large-size mesopores.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Recent strategies for enhancing the catalytic activity of CO2 hydrogenation to formate/formic acid over Pd-based catalyst

Priyanka Verma et al.

Summary: This review systematically summarizes the state-of-the-art of Pd-based heterogeneous catalysts for the catalytic conversion of CO2 to formate/formic acid. It discusses key factors influencing catalytic performance, major achievements in designing efficient Pd nanometals supported on various materials, and successful strategies for maximizing catalytic activity in CO2 conversion. Special attention is given to the mechanism of the catalytic reaction and a brief perspective on challenges and new directions in the development of innovative catalytic materials is proposed for achieving high catalytic activity in CO2 conversion towards carbon-neutrality in the near future.

JOURNAL OF CO2 UTILIZATION (2021)

添加到收藏夹

Article Chemistry, Physical

Inducing Electron Dissipation of Pyridinic N Enabled by Single Ni-N4 Sites for the Reduction of Aldehydes/Ketones with Ethanol

Yunchao Feng et al.

Summary: The usage of ethanol as a hydrogen source for the transfer hydrogenation of aldehydes/ketones shows high activity and selectivity with single-atom Ni-N-4 site catalysts. The presence of single-atom Ni at the pyridinic N active center reduces electron density and achieves high catalytic activity, demonstrating the possibility of catalytic reactions over metal-free sites.

ACS CATALYSIS (2021)

添加到收藏夹

Review Chemistry, Physical

Synthesis strategies of templated porous carbons beyond the silica nanocasting technique

Noel Diez et al.

Summary: The review discusses the importance of porous carbons in environmental remediation and emerging energy applications. It highlights sustainable templating strategies using easily removable inorganic particles or polymeric materials. The fundamental aspects, advances, applications, and challenges of producing porous carbons with various morphologies and pore structures are analyzed in detail.

CARBON (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

N-Doped Biochar as a New Metal-Free Activator of Peroxymonosulfate for Singlet Oxygen-Dominated Catalytic Degradation of Acid Orange 7

Ruirui Han et al.

Summary: A composite catalyst NRSBC800 was synthesized using rice straw and urea, and its catalytic performance for degrading AO7 was studied. The results show that NRSBC800 exhibited better catalytic performance and high stability during the degradation process.

NANOMATERIALS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Efficiency of Wood-Dust of Dalbergia sisoo as Low-Cost Adsorbent for Rhodamine-B Dye Removal

Dibyashree Shrestha

Summary: Wood-dust of Dalbergia sisoo was successfully converted into activated carbon for removing rhodamine B dye from aqueous solution. The activated carbon exhibited high surface area and abundant micropores and mesopores, making it effective in dye removal.

NANOMATERIALS (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Porous Carbons: Structure-Oriented Design and Versatile Applications

Wenjie Tian et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

添加到收藏夹

Article Chemistry, Physical

Structure Sensitivity and Evolution of Nickel-Bearing Nitrogen-Doped Carbons in the Electrochemical Reduction of CO2

Simon Buchele et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

High-Efficiency Oxygen Reduction to Hydrogen Peroxide Catalyzed by Nickel Single-Atom Catalysts with Tetradentate N2O2 Coordination in a Three-Phase Flow Cell

Yulin Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Single-Atom Catalysts across the Periodic Table

Selina K. Kaiser et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Chemistry, Physical

Thermal Transformation of Molecular Ni2+-N4 Sites for Enhanced CO2 Electroreduction Activity

Young Jin Sa et al.

ACS CATALYSIS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Application of Single-Site Catalysts in the Hydrogen Economy

Luning Chen et al.

TRENDS IN CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Physical

Highly Effective Methods of Obtaining N-Doped Graphene by Gamma Irradiation

Piotr Kamedulski et al.

MATERIALS (2020)

添加到收藏夹

Review Nanoscience & Nanotechnology

Metal-support interaction for heterogeneous catalysis: from nanoparticles to single atoms

Y. Lou et al.

MATERIALS TODAY NANO (2020)

添加到收藏夹

Article Energy & Fuels

Boosting Hydrogen Production from Formic Acid over Pd Catalysts by Deposition of N-Containing Precursors on the Carbon Support

Fedor S. Golub et al.

ENERGIES (2019)

添加到收藏夹

Article Energy & Fuels

Effects of the Carbon Support Doping with Nitrogen for the Hydrogen Production from Formic Acid over Ni Catalysts

Alina D. Nishchakova et al.

ENERGIES (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Highly Efficient Electroreduction of CO2 on Nickel Single-Atom Catalysts: Atom Trapping and Nitrogen Anchoring

Kaiwen Mou et al.

SMALL (2019)

添加到收藏夹

Article Multidisciplinary Sciences

A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts

Hongzhou Yang et al.

NATURE COMMUNICATIONS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content

B. Faroldi et al.

NANOMATERIALS (2019)

添加到收藏夹

Article Chemistry, Physical

MOF-derived hierarchical hollow spheres composed of carbon-confined Ni nanoparticles for efficient CO2 methanation

Xiahui Lin et al.

CATALYSIS SCIENCE & TECHNOLOGY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction

Yi Cheng et al.

ADVANCED MATERIALS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Durable Nickel Single-Atom Catalyst for Hydrogenation Reactions and Cellulose Valorization under Harsh Conditions

Wengang Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹

Review Chemistry, Physical

Nitrogen-doped carbon materials

Michio Inagaki et al.

CARBON (2018)

添加到收藏夹

Review Chemistry, Physical

Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates

Dmitri A. Bulushev et al.

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Towards Sustainable Production of Formic Acid

Dmitri A. Bulushev et al.

CHEMSUSCHEM (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Coordinatively unsaturated nickel-nitrogen sites towards selective and high-rate CO2 electroreduction

Chengcheng Yan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

添加到收藏夹

Article Chemistry, Physical

Amorphous Ni(OH)(2) encounter with crystalline CuS in hollow spheres: A mesoporous nano-shelled heterostructure for hydrogen evolution electrocatalysis

Shao-Qing Liu et al.

NANO ENERGY (2018)

添加到收藏夹

Article Energy & Fuels

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

Hong Bin Yang et al.

NATURE ENERGY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

InSitu Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts

Jian Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition

Olga Y. Podyacheva et al.

CHEMSUSCHEM (2018)

添加到收藏夹

Article Chemistry, Physical

Design of active nickel single-atom decorated MoS2 as a pH-universal catalyst for hydrogen evolution reaction

Qi Wang et al.

NANO ENERGY (2018)

添加到收藏夹

Article Chemistry, Physical

Novel nanoporous N-doped carbon-supported ultrasmall Pd nanoparticles: Efficient catalysts for hydrogen storage and release

Katherine Koh et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Sustainable carbon materials

Maria-Magdalena Titirici et al.

CHEMICAL SOCIETY REVIEWS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Expanding the scope of biogenic substrates for the selective production of formic acid from water-insoluble and wet waste biomass

Jakob Albert et al.

GREEN CHEMISTRY (2015)

添加到收藏夹

Article Engineering, Electrical & Electronic

The effect of carbonization temperature on the electrocatalytic performance of nitrogen-doped porous carbon as counter electrode of dye-sensitized solar cells

Juan Zhang et al.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2015)

添加到收藏夹

Article Materials Science, Multidisciplinary

Nano-CaO templated carbon by CVD: From nanosheets to nanocages

Bin Xu et al.

MATERIALS LETTERS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electrochemical fabrication of Ni(OH)2/Ni 3D porous composite films as integrated capacitive electrodes

Hong Jiang et al.

RSC ADVANCES (2015)

添加到收藏夹

Article Chemistry, Applied

Combination of dry reforming and partial oxidation of methane on NiO-MgO-ZrO2 catalyst: Effect of nickel content

Yvan J. O. Asencios et al.

FUEL PROCESSING TECHNOLOGY (2013)

添加到收藏夹

Article Chemistry, Physical

Jaguar: A high-performance quantum chemistry software program with strengths in life and materials sciences

Art D. Bochevarov et al.

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY (2013)

添加到收藏夹

Article Chemistry, Physical

Hydrogen generation from formic acid decomposition on Ni(211), Pd(211) and Pt(211)

Qiquan Luo et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2013)

添加到收藏夹

Article Chemistry, Physical

Formic Acid Dehydrogenation on Ni(111) and Comparison with Pd(111) and Pt(111)

Qiquan Luo et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2012)

添加到收藏夹

Article Astronomy & Astrophysics

Ab initio theory and calculations of X-ray spectra

John J. Rehr et al.

COMPTES RENDUS PHYSIQUE (2009)

添加到收藏夹

Article Chemistry, Physical

Theoretical and spectroscopic study of nickel(II) porphyrin derivatives

Cristhian Berrios et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2007)

添加到收藏夹

Article Chemistry, Physical

Assessment of a long-range corrected hybrid functional

Oleg A. Vydrov et al.

JOURNAL OF CHEMICAL PHYSICS (2006)

添加到收藏夹

Highly Dispersed Ni on Nitrogen-Doped Carbon for Stable and Selective Hydrogen Generation from Gaseous Formic Acid

相关参考文献

导出引文

分享论文