期刊
JOURNAL OF POWER SOURCES
卷 307, 期 -, 页码 678-683出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2016.01.032
关键词
Polymeric ionic liquid; Plastic crystal; Succinonitrile; Composite polymer electrolyte; Lithium ion battery
资金
- National Natural Science Foundation of China [21373136]
- Hitachi Chemical Co. Ltd.
In this work, composite polymer electrolytes (CPEs), that is, 80%[(1-x)PIL-(x)SNI-20%LiTFSI, are successfully prepared by using a pyrrolidinium-based polymeric ionic liquid (P(DADMA)TFSI) as a polymer host, succinonitrile (SN) as a plastic crystal, and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) as a lithium salt. XRD and DSC measurements confirm that the as-obtained CPEs have amorphous structures. The 80%[50%PIL-50%SN]-20%LiTFSI (50% SN) electrolyte reveals a high room temperature ionic conductivity of 5.74 x 10(-4) S cm(-1), a wide electrochemical window of 5.5 V, as well as good mechanical strength with a Young's modulus of 4.9 MPa. Li/LiFePO4 cells assembled with the 50% SN electrolyte at 0.1C rate can deliver a discharge capacity of about 150 mAh g(-1) at 25 degrees C, with excellent capacity retention. Furthermore, such cells are able to achieve stable discharge capacities of 131.8 and 121.2 mAh g(-1) at 0.5C and 1.0C rate, respectively. The impressive findings demonstrate that the electrolyte system prepared in this work has great potential for application in lithium ion batteries. (C) 2016 Elsevier B.V. All rights reserved.
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