Influence of Calcination Temperature on Photocatalyst Performances of Floral Bi2O3/TiO2 Composite

Heterojunction photocatalytic materials show excellent performance in degrading toxic pollutants. This study investigates the influence of calcination temperature on the performances of floral Bi2O3/TiO2 composite photocatalyst crystal, which was prepared with glycerol, bismuth nitrate, and titanium tetrachloride as the major raw materials via the solvothermal method. XRD, SEM/TEM, BET, Uv-vis, and XPS were employed to analyze the crystal structure, morphology, specific surface area, band gap, and surface chemical structure of the calcined temperature catalysts. The calcination temperature influence on the catalytic performance of composite photocatalysis was tested with rhodamine B (RhB) as the degradation object. The results revealed the high catalytic activity and higher photocatalytic performance of the Bi2O3/TiO2 catalyst. The degradation efficiency of the Bi2O3/TiO2 catalyst to RhB was 97%, 100%, and 91% at 400 degrees C, 450 degrees C, and 500 degrees C calcination temperatures, respectively, in which the peak degradation activity appeared at 450 degrees C. The characterization results show that the appropriate calcination temperature promoted the crystallization of the Bi2O3/TiO2 catalyst, increased its specific surface area and the active sites of catalytic reaction, and improved the separation efficiency of electrons and holes.

Automated summary

Heterojunction photocatalytic materials, specifically the Bi2O3/TiO2 composite, demonstrate excellent catalytic and photocatalytic performance in the degradation of toxic pollutants. The calcination temperature plays a crucial role in influencing the crystallization, specific surface area, and electron-hole separation efficiency of the catalyst. A temperature of 450 degrees C was found to exhibit the highest degradation activity for the RhB pollutant.