A New 2D Metal-Organic Framework for Photocatalytic Degradation of Organic Dyes in Water

Two-dimensional (2D) metal-organic frameworks (MOFs) are fascinating photocatalytic materials because of their unique physical and catalytic properties. Herein, we report a new (E)-4-(3-carboxyacrylamido) benzoic acid [ABA-MA] ligand synthesized under facile conditions. This ABA-MA ligand is further utilized to synthesize a copper-based 2D MOF via the solvothermal process. The resulting 2D MOF is characterized for morphology and electronic structural analysis using advanced techniques, such as proton nuclear magnetic resonance, Fourier-transform infrared spectroscopy, ultraviolet-visible spectroscopy, and scanning electron microscopy. Furthermore, 2D MOF is employed as a photocatalyst for degrading organic dyes, demonstrating the degradation/reduction of methylene blue (MeBl) dye with excellent catalytic/photodegradation activity in the absence of any photosensitizer or cocatalyst. The apparent rate constant (k(ap)) values for the catalytic degradation/reduction of MeBl on the Cu(II)-[ABA-MA] MOF are reported to be 0.0093 min(-1), 0.0187 min(-1), and 0.2539 min(-1) under different conditions of sunlight and NaBH4. The kinetics and stability evaluations reveal the noteworthy photocatalytic potential of the Cu(II)-[ABA-MA] MOF for wastewater treatment. This work offers new insights into the fabrication of new MOFs for highly versatile photocatalytic applications.

Automated summary

This study reports the synthesis of a new copper-based 2D metal-organic framework using a newly synthesized ABA-MA ligand. The resulting material exhibits excellent photocatalytic activity for degrading organic dyes, making it a promising candidate for wastewater treatment.