☆ 4.6 Review

State-of-the-Art Review of Oxidative Dehydrogenation of Ethane to Ethylene over MoVNbTeOx Catalysts

CATALYSTS (2023)

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Article Chemistry, Physical

Plasma treated M1 MoVNbTeOx-CeO2 composite catalyst for improved performance of oxidative dehydrogenation of ethane

Shuairen Qian et al.

Summary: Plasma treatment can enhance the catalytic performance of MoVNbTeOx catalyst in oxidative dehydrogenation of ethane (ODHE) by capturing active oxygen species and transforming V4+ to V5+ without damaging the M1 structure, leading to a significant increase in ethylene yield.

GREEN ENERGY & ENVIRONMENT (2023)

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Article Engineering, Environmental

Industrially potential MoVNbTeOx@FoamSiC structured catalyst for oxidative dehydrogenation of ethane

Peng Yan et al.

Summary: The study utilized highly thermal conductive Foam SiC as the structured support and proposed three strategies to intensify the coating stability, achieving excellent heat transfer and meeting the industrial goal of catalytic performance. A Dual Interfaces coating stability mechanism was proposed, providing fundamental guidelines for successful development of stable coating strategies.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

High-pressure hydrothermal synthesis of MoVTeNbOx with high surface V5+ abundance for oxidative conversion of propane to acrylic acid

Yaoxin Fan et al.

Summary: The high-pressure hydrothermal method was used to synthesize a series of MoVTeNbOx-mixed metal oxides with high catalytic performance. The sample synthesized at 200 degrees Celsius for 30 minutes showed the highest selectivity for propane selective oxidation, attributed to its high surface V5+ abundance and largest proportion of terminating (001) plane. Additionally, the prepared MoVTeNbOx exhibited excellent stability in high temperature continuous reaction.

JOURNAL OF SUPERCRITICAL FLUIDS (2022)

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Article Chemistry, Physical

Phase-pure M1 MoVNbTeOx/TiO2 nanocomposite catalysts: high catalytic performance for oxidative dehydrogenation of ethane

Dan Dang et al.

Summary: Introduction of TiO2 enhances catalytic performance of phase-pure M1 MoVNbTeOx catalyst in oxidative dehydrogenation of ethane, with TiO2 content showing a significant impact on ethylene productivity. The M1/TiO2 composite catalysts exhibit stable crystal structure and surface morphology, with TiO2 improving reduction/re-oxidation rate of lattice oxygen species in the catalysts, thus enhancing catalytic performance.

CATALYSIS SCIENCE & TECHNOLOGY (2022)

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Article Chemistry, Physical

Mixed Metal Oxides of M1 MoVNbTeOx and TiO2 as Composite Catalyst for Oxidative Dehydrogenation of Ethane

Yuxin Chen et al.

Summary: Composite catalysts of M1-TiO2 were prepared by two methods and showed improved catalytic performance in the ODHE process. The introduction of TiO2 increased the V5+ content on the catalyst surface and the reactivity of active oxygen species, contributing to the promotion of catalytic performance.

CATALYSTS (2022)

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Article Engineering, Environmental

Photocatalytic degradation of xanthate in flotation plant tailings by TiO2/graphene nanocomposites

Man Jiang et al.

Summary: This study successfully prepared a TiO2/graphene (TiO2/G) composite photocatalytic material via the hydrothermal method. The TiO2/G nanocomposites showed a large specific surface area, small pore size, and low electron-hole pair complexation rate, resulting in efficient degradation of pollutants. By anchoring TiO2 on graphene oxide (GO), the photoresponse range of TiO2/G was broadened and its photocatalytic efficiency was significantly improved. This work is important for the development of photocatalytic systems for the treatment of mineral processing wastewater.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Chemical

MoVNbTeOx M1@CeO2@Cordierite structured catalysts for ODHE process

Yuxin Chen et al.

Summary: The phase-pure M1 MoVNbTeOx catalyst has been coated on cordierite monolith using PVP-sol binder solution. A layered M1@CeO2@Monolith structured catalyst has been prepared to enhance the catalytic performance and stability. The M1@CeO2@Monolith structured catalyst exhibits superior catalytic performance for ODHE reaction.

CHEMICAL ENGINEERING SCIENCE (2022)

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Article Chemistry, Physical

Evolution of the optimal catalytic systems for the oxidative dehydrogenation of ethane: The role of adsorption in the catalytic performance

Agustin de Arriba et al.

Summary: Three samples representing the evolution of optimal catalytic systems for the oxidative dehydrogenation of ethane were synthesized and compared in terms of catalytic behavior and adsorption properties. The catalytic performance was found to differ mainly in the extent of overoxidation of the formed ethylene. The selectivity to ethylene was highest for the MoVTeNb-M1 catalyst, followed by the NiSnOx catalyst, and lowest for the VOx/Al2O3 catalyst. Microcalorimetry studies showed that the highest heat of adsorption for both ethane and ethylene was observed for the MoVTeNb-M1 catalyst.

JOURNAL OF CATALYSIS (2022)

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Article Chemistry, Physical

Dual Functionalized Interstitial N Atoms in Co3Mo3N Enabling CO2 Activation

Kai Feng et al.

Summary: The introduction of light elements into the interstitial sites of metals can enhance the catalytic performance by modifying the surface structure and electronic properties. In this study, N atoms were incorporated into the CoMo system to synthesize Co3Mo3N catalyst for reverse water-gas shift reaction. The enhanced catalytic performance of Co3Mo3N was attributed to the dual functions of interstitial N atoms, which provide additional sites for hydrogenation and weaken the binding ability of Mo to O-containing intermediates. The findings provide insights into the relationship between interstitial light element-promoted catalytic performance.

ACS CATALYSIS (2022)

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Article Chemistry, Physical

Highly Selective Oxidative Dehydrogenation of Ethane to Ethylene via Chemical Looping with Oxygen Uncoupling through Structural Engineering of the Oxygen Carrier

Giancarlo Luongo et al.

Summary: This article presents a chemical-looping-based oxidative dehydrogenation (CL-ODH) scheme that eliminates the overoxidation of ethane through structural design modifications to the oxygen carrier, resulting in higher ethylene selectivity and yields. The CL-ODH scheme and material design strategy can be extended to other catalytic oxidation or dehydrogenation reactions requiring oxygen, offering enormous potential to intensify such processes.

ADVANCED ENERGY MATERIALS (2022)

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Article Chemistry, Physical

Determination of highly active and selective surface for the oxidative dehydrogenation of ethane over phase-pure M1 MoVNbTeOx catalyst

Yuxin Chen et al.

Summary: Using mechanical treatment with stirring water, the catalytic performance and stability of the phase-pure M1 MoVNbTeOx catalyst were improved. The catalyst particle size and basal surface proportion were changed significantly, leading to enhanced activity and selectivity.

JOURNAL OF CATALYSIS (2022)

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Article Chemistry, Physical

Identification of the Intrinsic Active Site in Phase-Pure M1 Catalysts for Oxidation Dehydrogenation of Ethane by Density Functional Theory Calculations

Shuairen Qian et al.

Summary: This study employed an atomic substitution strategy to investigate the active site of the M1 MoVNbTeOx catalyst for the oxidation dehydrogenation of ethane reaction and found that the synergistic interaction between Te-O and V-O sites is the intrinsic active site for the reaction.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

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Article Engineering, Chemical

Nanocomposite catalysts of non-purified MoVNbTeOx with CeO2 or TiO2 for oxidative dehydrogenation of ethane br

Yuxin Chen et al.

Summary: This study demonstrates that adding CeO2 to MoVNbTeOx using the sol-gel method can effectively enhance its catalytic performance. The characterization results show that the improved performance is attributed to the increased active species at the catalyst surface due to the addition of CeO2. This work provides a new solution to simplify the preparation procedure of MoVNbTeOx catalysts and avoid mass loss during purification.

CHEMICAL ENGINEERING SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Rational design of Ruddlesden-Popper perovskite electrocatalyst for oxygen reduction to hydrogen peroxide

Ning Han et al.

Summary: In recent years, the electrochemical synthesis of H2O2 through a 2e(-) transfer method of oxygen reduction reaction (ORR) has attracted interest from both academics and the industry. This study successfully improved the selectivity and activity of H2O2 by using a Ruddlesden-Popper perovskite oxide as a catalyst.

SUSMAT (2022)

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Article Chemistry, Physical

On the role of oxidation states in the electronic structure via the formation of oxygen vacancies of a doped MoVTeNbOx in propylene oxidation

Joel Ramirez-Salgado et al.

Summary: The influence of oxygen vacancies on the electronic properties of (K or Bi) doped MoVTeNb oxide was investigated in this study. The results showed a correlation between the number of oxygen vacancies and catalytic performance, particularly in terms of acrylic acid selectivity. The study also highlighted the role of V5+ species density and their reducibility to V4+ in the performance of (K or Bi) doped catalysts.

APPLIED SURFACE SCIENCE (2022)

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Article Chemistry, Applied

Oxidative dehydrogenation of ethane over M1 MoVNbTeO catalysts modified by the addition of Nd, Mn, Ga or Ge

E. Lazareva et al.

Summary: The modification by Nd, Mn, Ga, and Ge greatly influences the properties of MoVNbTeO oxides in ODE. The introduction of modifying additives changes the content of M1 phase, surface acidity, and surface composition, leading to positive effects on catalytic properties at a certain ratio.

CATALYSIS TODAY (2021)

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Article Chemistry, Applied

Comparison of structural and catalytic properties of monometallic Mo and V oxides and M1 phase mixed oxides for oxidative dehydrogenation

Leelavathi Annamalai et al.

Summary: This study investigates the catalytic properties of SiO2 supported VOx, unsupported V2O5, MoO3 and M1 phase MoV mixed oxide catalysts in oxidative dehydrogenation reactions. The loading of VOx on SiO2 significantly affects the activation rates and C2H6/C6H12 rate ratios, while MoO3 samples exhibit lower rates but similar rate ratios as V2O5. The M1 phase samples show higher selectivity and the presence of micropores plays a key role in selectively activating C2H6.

CATALYSIS TODAY (2021)

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Article Chemistry, Applied

Evaluation and analysis of ethylene production using oxidative dehydrogenation

Anne M. Gaffney et al.

Summary: The study focuses on utilizing new technologies and process improvements to enhance the efficiency of ODH production while reducing costs. By adding storage tanks to improve system safety, downtime due to failures can be minimized.

CATALYSIS TODAY (2021)

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Article Engineering, Chemical

Effects of surface species and homogeneous reactions on rates and selectivity in ethane oxidation on oxide catalysts

Yilang Liu et al.

Summary: Selective alkane oxidations on metal oxide catalysts involve complex mechanisms with multiple reactions in series and parallel, including contributions from gas-phase reactions. Kinetic simulations incorporating both surface and gas-phase reactions reveal that gas-phase reactions significantly impact C2H6 activation rates, while surface reactions predominantly occur via H abstraction by vanadium oxo species. The study also highlights the importance of reaction conditions and catalyst site density in influencing rates and selectivity in alkane oxidation reactions.

AICHE JOURNAL (2021)

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Article Engineering, Chemical

Oxidative dehydrogenation of ethane over mixed metal oxide catalysts: Autothermal or cooled tubular reactor design?

Jiakang Chen et al.

Summary: The kinetic model developed for the oxidative dehydrogenation of ethane over a MoVTeNbO catalyst suggests that autothermal reactor configurations are more favorable than multi-tubular ones for this highly exothermic reaction, especially with increasing active site density. The bifurcation analysis based on ignition and extinction behavior provides additional insights into strategies for successful scale-up of ODHE reactors.

AICHE JOURNAL (2021)

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Article Chemistry, Physical

Tuning surface V5+ concentration in M1 phase MoVSbOx catalysts for ethylene production from ethane through oxidative dehydrogenation reaction

Chunyu Xin et al.

Summary: MoVSbOx complex metal oxides are efficient catalysts for ODE, with the catalytic performance strongly correlated to surface V5+ concentration. The study results may be useful for developing highly efficient ODE catalysts.

APPLIED CATALYSIS A-GENERAL (2021)

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Article Chemistry, Physical

Roles of Enhancement of C-H Activation and Diminution of C-O Formation Within M1-Phase Pores in Propane Selective Oxidation

Yilang Liu et al.

Summary: The study investigates the selectivity of propane and propene oxidations on MoVTeNb mixed oxide catalysts, revealing a significant contribution of M1 phase pores to propane activation. Density functional theory shows that activation barriers for C-O formation are higher than C-H activation when reactions are restricted within the pores, leading to high selectivity towards desired products.

CHEMCATCHEM (2021)

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Article Chemistry, Physical

Highly-Dispersed Zinc Species on Zeolites for the Continuous and Selective Dehydrogenation of Ethane with CO2 as a Soft Oxidant

Jiaxu Liu et al.

Summary: This study presents the preparation, characterization, and catalytic performance of heterogeneous catalysts with highly dispersed zinc sites on zeolitic materials for the CO2-assisted oxidative ethane dehydrogenation reaction. The selective reactivity of the catalyst is attributed to the compositional structure and topology of the support.

ACS CATALYSIS (2021)

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Review Chemistry, Multidisciplinary

Oxidative dehydrogenation of ethane: catalytic and mechanistic aspects and future trends

Sara Najari et al.

Summary: Ethene, a key commodity chemical in manufacturing diverse consumer products, can be produced through oxidative dehydrogenation of ethane to reduce carbon emissions, but requires catalysts with improved selectivity. Recent advancements in catalytic technologies and CO2-assisted ethane dehydrogenation offer opportunities for economically feasible processes.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Applied

Optimizing Reflux Synthesis Method of Mo-V-Te-Nb mixed oxide Catalysts for Light Alkane Selective Oxidation

Amada Masso Ramirez et al.

CATALYSIS TODAY (2020)

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Article Engineering, Environmental

Intrinsic kinetic model for oxidative dehydrogenation of ethane over MoVTeNb mixed metal oxides: A mechanistic approach

Philipp J. Donaubauer et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

New Multicomponent MoVSbNbCeOx/SiO2Catalyst with Enhanced Catalytic Activity for Oxidative Dehydrogenation of Ethane to Ethylene

Galina A. Zenkovets et al.

CHEMCATCHEM (2020)

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Article Chemistry, Physical

Oxidative dehydrogenation of ethane to ethylene in an integrated CO2 capture-utilization process

Ahmed Al-Mamoori et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Energy & Fuels

Chemical looping oxidative dehydrogenation of propane: A comparative study of Ga-based, Mo-based, V-based oxygen carriers

Tianwei Wu et al.

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION (2020)

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Article Chemistry, Multidisciplinary

Facile sub-/supercritical water synthesis of nanoflake MoVTeNbOx-mixed metal oxides without post-heat treatment and their catalytic performance

Shuangming Li et al.

RSC ADVANCES (2020)

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Article Chemistry, Physical

Superior three-dimensional perovskite catalyst for catalytic oxidation

Ning Han et al.

ECOMAT (2020)

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Article Chemistry, Multidisciplinary

Role of CO2 in Catalytic Ethane-to-Ethylene Conversion Using a High-Temperature CO2 Transport Membrane Reactor

Peng Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Chemistry, Physical

NAP-XPS and in situ XRD study of the stability of Bi-modified MoVNbTeO catalysts for oxidative dehydrogenation of ethane

Dmitry A. Svintsitskiy et al.

APPLIED CATALYSIS A-GENERAL (2019)

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Article Engineering, Chemical

Theoretical investigation of ethane oxidative dehydrogenation over MoVTeNbO catalyst in fixed-bed reactors with intermediate water removal

Armin Fazlinezhad et al.

CHEMICAL ENGINEERING RESEARCH & DESIGN (2019)

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Article Chemistry, Physical

Improving the selectivity of Ni-Al mixed oxides with isolated oxygen species for oxidative dehydrogenation of ethane with nitrous oxide

Yanliang Zhou et al.

JOURNAL OF CATALYSIS (2019)

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Article Chemistry, Physical

Effects of Lattice O Atom Coordination and Pore Confinement on Selectivity Limitations for Ethane Oxidative Dehydrogenation Catalyzed by Vanadium-Oxo Species

Yilang Liu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

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Article Multidisciplinary Sciences

Design and synthesis of highly active MoVTeNb-oxides for ethane oxidative dehydrogenation

Daniel Melzer et al.

NATURE COMMUNICATIONS (2019)

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Article Engineering, Chemical

MnOx promoted phase-pure M1 MoVNbTe oxide for ethane oxidative dehydrogenation

Xin Chen et al.

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2019)

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Article Multidisciplinary Sciences

Intensified Ethylene Production via Chemical Looping through an Exergetically Efficient Redox Scheme

Luke M. Neal et al.

ISCIENCE (2019)

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Article Chemistry, Multidisciplinary

Nanosized-bulk V-containing mixed-oxide catalysts: a strategy for the improvement of the catalytic materials properties

Ricardo Lopez-Medina et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Article Chemistry, Physical

Promoting effect of cerium on MoVTeNb mixed oxide catalyst for oxidative dehydrogenation of ethane to ethylene

Yang Sik Yun et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Catalytic performance of phase-pure M1 MoVNbTeOx/CeO2 composite for oxidative dehydrogenation of ethane

Dan Dang et al.

JOURNAL OF CATALYSIS (2018)

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Article Chemistry, Physical

Influence of Tight Confinement on Selective Oxidative Dehydrogenation of Ethane on MoVTeNb Mixed Oxides

Leelavathi Annamalai et al.

ACS CATALYSIS (2018)

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Article Chemistry, Physical

Enhancing the capacity of oxygen carriers for selective oxidations through phase cooperation: bismuth oxide and ceria-zirconia

Martin S. C. Chan et al.

CATALYSIS SCIENCE & TECHNOLOGY (2018)

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Article Engineering, Chemical

Propane Ammoxidation Over MoVTeNb Oxide Catalyst in a Microchannel Reactor

Jinhan Lin et al.

AICHE JOURNAL (2018)

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Article Chemistry, Multidisciplinary

The evolution of the M1 local structure during preparation of VMoNbTeO catalysts for ethane oxidative dehydrogenation to ethylene

T. Yu Kardash et al.

RSC ADVANCES (2018)

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Article Chemistry, Multidisciplinary

Formation of Oxygen Radical Sites on MoVNbTeOx by Cooperative Electron Redistribution

Yuanyuan Zhu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Physical

Oxidative Dehydrogenation of Ethane over a Mo-V-Nb-Te-O Mixed-Oxide Catalyst in a Cyclic Mode

I. I. Mishanin et al.

KINETICS AND CATALYSIS (2017)

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Article Chemistry, Physical

Effect of Promoters on Manganese-Containing Mixed Metal Oxides for Oxidative Dehydrogenation of Ethane via a Cyclic Redox Scheme

Seif Yusuf et al.

ACS CATALYSIS (2017)

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Article Chemistry, Physical

The Impact of the Bulk Structure on Surface Dynamics of Complex Mo-V-based Oxide Catalysts

Annette Trunschke et al.

ACS CATALYSIS (2017)

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Article Chemistry, Applied

Process economics and safety considerations for the oxidative dehydrogenation of ethane using the M1 catalyst

Chinmoy Baroi et al.

CATALYSIS TODAY (2017)

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Article Chemistry, Applied

Ethylene production via Oxidative Dehydrogenation of Ethane using M1 catalyst

Anne M. Gaffney et al.

CATALYSIS TODAY (2017)

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Article Chemistry, Physical

Effect of Bi on catalytic performance and stability of MoVTeNbO catalysts in oxidative dehydrogenation of ethane

E. V. Ishchenko et al.

APPLIED CATALYSIS A-GENERAL (2017)

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Article Chemistry, Multidisciplinary

Atomic-Scale Determination of Active Facets on the MoVTeNb Oxide M1 Phase and Their Intrinsic Catalytic Activity for Ethane Oxidative Dehydrogenation

Daniel Melzer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Physical

Phase-pure M1 MoVNbTeOx catalysts with tunable particle size for oxidative dehydrogenation of ethane

Bozhao Chu et al.

APPLIED CATALYSIS A-GENERAL (2016)

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Article Chemistry, Physical

Effect of K and Bi doping on the M1 phase in MoVTeNbO catalysts for ethane oxidative conversion to ethylene

E. V. Ishchenko et al.

APPLIED CATALYSIS A-GENERAL (2016)

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Article Chemistry, Applied

The Mechanism of Alkane Selective Oxidation by the M1 Phase of Mo-V-Nb-Te Mixed Metal Oxides: Suggestions for Improved Catalysts

Mu-Jeng Cheng et al.

TOPICS IN CATALYSIS (2016)

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Article Chemistry, Physical

In Situ Environmental STEM Study of the MoVTe Oxide M1 Phase Catalysts for Ethane Oxidative Dehydrogenation

Mimoun Aouine et al.

ACS CATALYSIS (2016)

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Article Chemistry, Multidisciplinary

Better Catalysts through Microscopy: Mesoscale M1/M2 Intergrowth in Molybdenum-Vanadium Based Complex Oxide Catalysts for Propane Ammoxidation

Qian He et al.

ACS NANO (2015)

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Article Chemistry, Physical

Preparation, characterization and catalytic behavior for propane partial oxidation of Ga-promoted MoVTeO catalysts

S. Hernandez-Morejudo et al.

APPLIED CATALYSIS A-GENERAL (2015)

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Article Chemistry, Physical

Performance of phase-pure M1 MoVNbTeOx catalysts by hydrothermal synthesis with different post-treatments for the oxidative dehydrogenation of ethane

Bozhao Chu et al.

APPLIED CATALYSIS A-GENERAL (2015)

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Article Engineering, Environmental

Modeling of oxidative dehydrogenation of ethane to ethylene on a MoVTeNbO/TiO2 catalyst in an industrial-scale packed bed catalytic reactor

Gamaliel Che-Galicia et al.

CHEMICAL ENGINEERING JOURNAL (2015)

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Article Engineering, Environmental

Fluidized bed ODH of ethane to ethylene over VOx-MoOx/γ-Al2O3 catalyst: Desorption kinetics and catalytic activity

Idris A. Bakare et al.

CHEMICAL ENGINEERING JOURNAL (2015)

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Article Chemistry, Physical

A self-redox pure-phase M1 MoVNbTeOx/CeO2 nanocomposite as a highly active catalyst for oxidative dehydrogenation of ethane

Bozhao Chu et al.

JOURNAL OF CATALYSIS (2015)

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Article Chemistry, Physical

Redox Treatment of Orthorhombic Mo29V11O112 and Relationships between Crystal Structure, Microporosity and Catalytic Performance for Selective Oxidation of Ethane

Satoshi Ishikawa et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

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Article Chemistry, Multidisciplinary

In Silico Design of Highly Selective Mo-V-Te-Nb-O Mixed Metal Oxide Catalysts for Ammoxidation and Oxidative Dehydrogenation of Propane and Ethane

Mu-Jeng Cheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Article Chemistry, Physical

Oxidative dehydrogenation of ethane to ethylene over phase-pure M1 MoVNbTeOx catalysts in a micro-channel reactor

Bozhao Chu et al.

CATALYSIS SCIENCE & TECHNOLOGY (2015)

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Article Chemistry, Physical

A high-throughput reactor system for optimization of Mo-V-Nb mixed oxide catalyst composition in ethane ODH

Haibo Zhu et al.

CATALYSIS SCIENCE & TECHNOLOGY (2015)

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Article Chemistry, Multidisciplinary

Valence variation of phase-pure M1 MoVNbTe oxide by plasma treatment for improved catalytic performance in oxidative dehydrogenation of ethane

Xin Chen et al.

RSC ADVANCES (2015)

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Article Chemistry, Physical

Combinatorial design and preparation of transition metal doped MoVTe catalysts for oxidation of propane to acrylic acid

Gerhard Mestl et al.

APPLIED CATALYSIS A-GENERAL (2014)

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Article Chemistry, Physical

Heptagonal channel micropore of orthorhombic Mo3VOx as catalysis field for the selective oxidation of ethane

Satoshi Ishikawa et al.

APPLIED CATALYSIS A-GENERAL (2014)

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Article Chemistry, Applied

Catalysis field in orthorhombic Mo3VOx oxide catalyst for the selective oxidation of ethane, propane and acrolein

Satoshi Ishikawa et al.

CATALYSIS TODAY (2014)

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Article Engineering, Environmental

Kinetic modeling of the oxidative dehydrogenation of ethane to ethylene over a MoVTeNbO catalytic system

Gamaliel Che-Galicia et al.

CHEMICAL ENGINEERING JOURNAL (2014)

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Article Engineering, Chemical

Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst

Jaime S. Valente et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2014)

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Article Chemistry, Physical

The reaction network in propane oxidation over phase-pure MoVTeNb M1 oxide catalysts

Raoul Naumann d'Alnoncourt et al.

JOURNAL OF CATALYSIS (2014)

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Article Chemistry, Physical

Mo-V-Te-Nb oxide catalysts: Reactivity of different oxygen species in partial and deep oxidation

Ekaterina Sadovskaya et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2014)

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Article Chemistry, Physical

Chemical, Structural, and Morphological Changes of a MoVTeNb Catalyst during Oxidative Dehydrogenation of Ethane

Jaime S. Valente et al.

ACS CATALYSIS (2014)

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Article Chemistry, Physical

VOx/c-Al2O3 catalyst for oxidative dehydrogenation of ethane to ethylene: Desorption kinetics and catalytic activity

S. Al-Ghamdi et al.

APPLIED CATALYSIS A-GENERAL (2013)

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Review Chemistry, Physical

Oxidative Dehydrogenation of Ethane: Common Principles and Mechanistic Aspects

Christian A. Gaertner et al.

CHEMCATCHEM (2013)

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Article Chemistry, Physical

Work Function, Band Bending, and Microwave Conductivity Studies on the Selective Alkane Oxidation Catalyst MoVTeNb Oxide (Orthorhombic M1 Phase) under Operation Conditions

Christian Heine et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Article Chemistry, Applied

Redox State Dynamics at the Surface of MoVTe(Sb)NbO M1 Phase in Selective Oxidation of Light Alkanes

Benoit Deniau et al.

TOPICS IN CATALYSIS (2013)

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Article Chemistry, Physical

An orthorhombic Mo3VOx catalyst most active for oxidative dehydrogenation of ethane among related complex metal oxides

Takeshi Konya et al.

CATALYSIS SCIENCE & TECHNOLOGY (2013)

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Article Chemistry, Physical

Catalytic performance of MoVTeNbO catalyst supported on SiC foam in oxidative dehydrogenation of ethane and ammoxidation of propane

T. T. Nguyen et al.

APPLIED CATALYSIS A-GENERAL (2012)

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Article Chemistry, Physical

In-situ X-ray diffraction study of phase crystallization from an amorphous MoVTeNb oxide catalyst precursor

Frank Girgsdies et al.

CATALYSIS COMMUNICATIONS (2012)

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Article Chemistry, Physical

Optimizing the efficiency of MoVTeNbO catalysts for ethane oxidative dehydrogenation to ethylene

T. T. Nguyen et al.

CATALYSIS COMMUNICATIONS (2012)

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Article Chemistry, Applied

Spectroscopic surface characterization of MoVNbTe nanostructured catalysts for the partial oxidation of propane

Ricardo Lopez-Medina et al.

CATALYSIS TODAY (2012)

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Article Chemistry, Physical

Surface chemistry of phase-pure M1 MoVTeNb oxide during operation in selective oxidation of propane to acrylic acid

Michael Haevecker et al.

JOURNAL OF CATALYSIS (2012)

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Article Chemistry, Physical

On the nature of active sites in MoVTeO and MoVTeNbO catalysts: The influence of catalyst activation temperature

P. Concepcion et al.

APPLIED CATALYSIS A-GENERAL (2011)

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Article Chemistry, Physical

Phase formation and selective oxidation of propane over MoVTeNbOx catalysts with varying compositions

Frederik N. Naraschewski et al.

APPLIED CATALYSIS A-GENERAL (2011)

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Article Chemistry, Physical

Synthesis of MoVTeNb Oxide Catalysts with Tunable Particle Dimensions

Yury V. Kolen'ko et al.

CHEMCATCHEM (2011)

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Article Chemistry, Physical

STEM HAADF Image Simulation of the Orthorhombic M1 Phase in the Mo-V-Nb-Te-O Propane Oxidation Catalyst

Douglas A. Blom et al.

CHEMCATCHEM (2011)

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Article Chemistry, Multidisciplinary

Redox tunable reversible molecular sieves: orthorhombic molybdenum vanadium oxide

Masahiro Sadakane et al.

CHEMICAL COMMUNICATIONS (2011)

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Article Chemistry, Physical

Reflux method as a novel route for the synthesis of MoVTeNbOx catalysts for selective oxidation of propane to acrylic acid

Irmawati Ramli et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2011)

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Article Chemistry, Applied

Improvement of the Structural Model for the M1 Phase Mo-V-Nb-Te-O Propane (Amm)oxidation Catalyst

Xin Li et al.

TOPICS IN CATALYSIS (2011)

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Article Chemistry, Multidisciplinary

Real-Space Observation of Surface Termination of a Complex Metal Oxide Catalyst

Wei Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Article Chemistry, Physical

Kinetics and mechanism of partial oxidation of ethane to ethylene and acetic acid over MoV type catalysts

Faizur Rahman et al.

APPLIED CATALYSIS A-GENERAL (2010)

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Article Chemistry, Physical

Dynamics of the MoVTeNb Oxide M1 Phase in Propane Oxidation

Almudena Celaya Sanfiz et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

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Article Chemistry, Applied

Selective oxidation of ethane: Developing an orthorhombic phase in Mo-V-X (X = Nb, Sb, Te) mixed oxides

P. Botella et al.

CATALYSIS TODAY (2009)

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Article Chemistry, Multidisciplinary

Direct imaging of the MoVTeNbO M1 phase using an aberration-corrected high-resolution scanning transmission electron microscope

William D. Pyrz et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Article Engineering, Chemical

Propane ammoxidation with lattice oxygen of Mo-V-O-based complex metal oxide catalysts

J. Kubo et al.

CHEMICAL ENGINEERING SCIENCE (2008)

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Article Chemistry, Physical

How important is the (001) plane of M1 for selective oxidation of propane to acrylic acid?

A. Celaya Sanfiz et al.

JOURNAL OF CATALYSIS (2008)

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Article Chemistry, Physical

Using aberration-corrected STEM imaging to explore chemical and structural variations in the M1 phase of the MoVNbTeO oxidation catalyst

William D. Pyrz et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2008)

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Article Chemistry, Multidisciplinary

The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes: Propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase

N. Raveendran Shiju et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

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Article Chemistry, Applied

M1 to M2 Phase Transformation and Phase Cooperation in Bulk Mixed Metal Mo-V-M-O (M=Te, Nb) Catalysts for Selective Ammoxidation of Propane

P. Korovchenko et al.

TOPICS IN CATALYSIS (2008)

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Article Chemistry, Applied

Preparation of Single M1 Phase MoVTe(Sb) NbO Catalyst: Study of the Effect of M2 Phase Dissolution on the Structure and Catalytic Properties

B. Deniau et al.

TOPICS IN CATALYSIS (2008)

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Article Chemistry, Applied

Preparation of Phase-Pure M1 MoVTeNb Oxide Catalysts by Hydrothermal Synthesis-Influence of Reaction Parameters on Structure and Morphology

A. Celaya Sanfiz et al.

TOPICS IN CATALYSIS (2008)

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Article Chemistry, Applied

High-throughput parallel reactor system for propylene oxidation catalyst investigation

Jiang P. Yi et al.

JOURNAL OF COMBINATORIAL CHEMISTRY (2007)

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Review Chemistry, Applied

Oxidative dehydrogenation of ethane and propane: How far from commercial implementation?

F. Cavani et al.

CATALYSIS TODAY (2007)

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Article Chemistry, Physical

Structure characterization of orthorhombic phase in MoVTeNbO catalyst by powder X-ray diffraction and XANES

H. Murayama et al.

APPLIED CATALYSIS A-GENERAL (2007)

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Article Chemistry, Applied

New Cs-containing Mo-V4+ based oxides with the structure of the M1 phase -: Base for new catalysts for the direct alkane activation

H. Hibst et al.

CATALYSIS TODAY (2006)

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Article Chemistry, Applied

Active oxygen in selective oxidation catalysis

Gennady I. Panov et al.

CATALYSIS TODAY (2006)

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Article Chemistry, Applied

Active centers, catalytic behavior, symbiosis and redox properties of MoV(Nb,Ta)TeO ammoxidation catalysts

Robert K. Grasselli et al.

TOPICS IN CATALYSIS (2006)

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Review Chemistry, Physical

Kinetics of oxidative dehydrogenation of C2-C3 alkanes on oxide catalysts

R. Grabowski

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING (2006)

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Article Engineering, Chemical

Comparative study on the catalytic performance of single-phase Mo-V-O-based metal oxide catalysts in propane ammoxidation to acrylonitrile

N Watanabe et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2006)

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Article Chemistry, Applied

Dehydrogenation of paraffins: synergies between catalyst design and reactor engineering

D Sanfilippo et al.

CATALYSIS TODAY (2006)

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Article Chemistry, Physical

Synergetic effect between phases in MoVTe(Sb)NbO catalysts used for the oxidation of propane into acrylic acid

M Baca et al.

JOURNAL OF CATALYSIS (2005)

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Article Chemistry, Physical

A study of the surface region of the Mo-V-Te-O catalysts for propane oxidation to acrylic acid

VV Guliants et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2005)

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Article Chemistry, Inorganic & Nuclear

MoVTeNbO multifunctional catalysts:: Correlation between constituent crystalline phases and catalytic performance

P Botella et al.

SOLID STATE SCIENCES (2005)

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Article Chemistry, Physical

Mechanisms of initial propane activation on molybdenum oxides: A density functional theory study

G Fu et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2005)

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Article Chemistry, Physical

Bulk oxidation state of the different cationic elements in the MoVTe(Sb)NbO catalysts for oxidation or ammoxidation of propane

M Baca et al.

APPLIED CATALYSIS A-GENERAL (2005)

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Article Chemistry, Applied

Active centers in Mo-V-Nb-Te-Ox (amm)oxidation catalysts

RK Grasselli et al.

CATALYSIS TODAY (2004)

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Article Crystallography

Structural aspects of the M1 and M2 phases in MoVNbTeO propane ammomidation catalysts

P DeSanto et al.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE (2004)

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Article Chemistry, Applied

Combinatorial heterogeneous catalysis: oxidative dehydrogenation of ethane to ethylene, selective oxidation of ethane to acetic acid, and selective ammoxidation of propane to acrylonitrile

S Bergh et al.

TOPICS IN CATALYSIS (2003)

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Article Chemistry, Applied

Is true ethane oxydehydrogenation feasible?

MM Bhasin

TOPICS IN CATALYSIS (2003)

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Article Chemistry, Applied

Propane oxidation on MoVTeNbO mixed oxide catalysts: study of the phase composition of active and selective catalysts

M Baca et al.

TOPICS IN CATALYSIS (2003)

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Article Chemistry, Applied

A study of the functionalities of the phases in Mo-V-Nb-Te oxides for propane ammoxidation

J Holmberg et al.

TOPICS IN CATALYSIS (2003)

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Article Chemistry, Applied

Structural characterization of the orthorhombic phase M1 in MoVNbTeO propane ammoxidation catalyst

P DeSanto et al.

TOPICS IN CATALYSIS (2003)

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Article Chemistry, Applied

The selective oxidation of propane on Mo-V-Te-Nb-O catalysts The influence of Te-precursor

JM López Nieto et al.

CATALYSIS TODAY (2003)

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Article Chemistry, Physical

Study of the valence state and coordination of antimony in MoVSbO catalysts determined by XANES and EXAFS

JMM Millet et al.

APPLIED CATALYSIS A-GENERAL (2003)

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Article Chemistry, Applied

Catalytic oxidative activation of light alkanes over Mo-V-based oxides having controlled surface

K Oshihara et al.

TOPICS IN CATALYSIS (2001)

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Article Chemistry, Applied

Selective oxidation of ethane over hydrothermally synthesized Mo-V-Al-Ti oxide catalyst

NF Chen et al.

CATALYSIS TODAY (2001)

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Article Chemistry, Multidisciplinary

Crystal chemistry and phase composition of the MoVTeNbO catalysts for the ammoxidation of propane

M Aouine et al.

CHEMICAL COMMUNICATIONS (2001)

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Article Chemistry, Physical

Selective oxidation of light alkanes over hydrothermally synthesized Mo-V-M-O (M=Al, Ga, Bi, Sb, and Te) oxide catalysts

W Ueda et al.

APPLIED CATALYSIS A-GENERAL (2000)

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Article Chemistry, Physical

New synthesis route for Mo-V-Nb-Te mixed oxides catalyst for propane ammoxidation

H Watanabe et al.

APPLIED CATALYSIS A-GENERAL (2000)

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