Protection Effect of Ammonia on CeNbTi NH3-SCR Catalyst from SO2 Poisoning

CeNbTi catalyst was poisoned in different sulfur poisoning atmospheres at 300 degrees C for 6 h and then was evaluated for selective catalytic reduction (SCR) of NOx with NH3. The catalyst deactivation upon SO2 exposure was effectively inhibited in the presence of NH3. Temperature-programmed decomposition (TPD) analyses were applied to identify deposit species on the poisoned catalysts by comparison with several groups of reference samples. Diffuses reflectance infrared Fourier transform spectroscopy (DRIFTS) over CeNbTi catalysts with different poisoning pretreatments and gas purging sequences were designed to investigate the roles of NH3 in the removal of surface sulfites and sulfates. More ammonium sulfates including ammonium bisulfate and ammonium cerium sulfate were generated instead of inert cerium sulfate in these conditions. The mechanisms about the formation and transformation of surface deposits upon sulfur poisoning w/wo NH3 were explored, which provided a basis for developing Ce-based mixed oxides as SCR catalysts for stationary sources.

Automated summary

CeNbTi catalyst was poisoned by sulfur in different atmospheres, and the addition of NH3 effectively inhibited catalyst deactivation. The roles of NH3 in removing surface sulfates were studied using TPD analysis and DRIFTS experiments, and it was found that ammonium sulfates were generated under certain conditions.