期刊
JOURNAL OF POWER SOURCES
卷 318, 期 -, 页码 228-234出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2016.03.105
关键词
Diphenyl carbonate; Methyl phenyl carbonate; Electrolyte additives; Li[Ni0.8Mn0.1Co0.1]O-2/graphite cells; Long lifetime; High voltage
资金
- 3M Canada
- NSERC under Industrial Research Chairs program
- National Basic Research Program of China (973)
The effectiveness of methyl phenyl carbonate and diphenyl carbonate as electrolyte additives either singly or in combination with methylene methyl disulfonate and tris(-trimethyl-silyl)-phosphite has been systematically investigated in LiNi0.8Mn0.1Co0.1O2/graphite pouch cells. Experiments conducted included ultrahigh precision coulometry, electrochemical impedance spectroscopy, automated storage, gas evolution measurements as well as long-term cycling. The results showed that adding methyl phenyl or diphenyl carbonate increases the coulombic efficiency, reduces charge end-point capacity slippage rate, decreases the self-discharge rate during storage and improves the capacity retention during long-term cycling compared to cells with control electrolyte [1 M LiPF6 ethylene carbonate:ethyl methyl carbonate 3:7] or control electrolyte with 2% vinylene carbonate. 1% diphenyl carbonate appears to be the best among the systems studied. Based on these experiments, diphenyl carbonate seems to be a very beneficial additive for improving the performance of high voltage LiNi0.8Mn0.1Co0.1O2/graphite pouch cells. (C) 2016 Elsevier B.V. All rights reserved.
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