Enhanced oxygen reduction reaction activity of iron-containing nitrogen-doped carbon nanotubes for alkaline direct methanol fuel cell application

Non-precious metal catalysts for electrochemical oxygen reduction reaction are synthesised by pyrolysis of multi-walled carbon nanotubes in the presence of nitrogen and iron precursors. For the physicochemical characterisation of the catalysts transmission electron microscopy, scanning electron microscopy, X-ray photoelectron spectroscopy and X-ray diffraction are used. The electrocatalytic activity of the catalysts for oxygen reduction is studied in 0.1 M KOH solution using the rotating disk electrode method. The Fe-containing nitrogen-doped carbon nanotubes exhibit an enhanced electrocatalytic performance as compared to metal-free counterparts and their electrocatalytic activity is comparable to that of commercial Pt/C catalyst. Alkaline direct methanol fuel cell tests also show performance close to Pt/C. Thus, these materials can be considered as promising cathode catalysts for application in alkaline fuel cells. (C) 2016 Elsevier B.V. All rights reserved.