期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 20, 期 1-4, 页码 45-60出版社
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1088424616300020
关键词
porphyrins; microwave irradiation; environmentally friendly processes; solventless reactions; microporous materials; ionic liquids
资金
- FCT-Portugal (Portuguese Foundation for Science and Technology)
- FEDER - European Regional Development Fund through the COMPETE Programme (Operational Programme for Competitiveness) [PEst-OE/QUI/UI0313/2014, UID/QUI/00313/2013]
- [SFRH/BD/84146/2012]
- [SFRH/BPD/84619/2012]
- [SERH/BPD/99698/2014]
The easy access and low price of pyrrole and aldehydes, conjugated with the simplicity in preparing meso-substituted porphyrins, makes this type of porphyrins very attractive for a broad range of applications. However, there is an increasing demand for the development of new synthetic processes involving more sustainable chemical principles substituting, whenever possible, dangerous organic solvents by alternative solvents, chromatographic purifications by precipitations and energy-intensive procedures by alternative energy sources such as microwaves and ultrasounds. In this review we will address some recent strategies to synthesize meso-substituted porphyrins using alternative energy sources, reaction media and catalysts, namely microwave irradiation, water as solvent, or solid microporous acid catalysts.
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