Neomangiferin defect-engineering ZIF-8 for visually differentiating aprotic/protic solvents and real-time sensing trace water

The fabrication of unique and robust luminescent metal-organic frameworks (LMOFs) with new mechanisms and superior stability is urgently needed for multidimensional sensing applications; however, this remains a huge challenge. Herein, defective neomangiferin-ZIF-8, a novel LMOF with a unique ligand-ligand charge transfer mechanism, was fabricated by a facile de novo strategy. The obtained neomangiferin-ZIF-8 is highly stable with a reversible solvatochromic behavior and hydrogen-bonding-induced quenching effect. Thus, neomangiferin-ZIF-8 has been developed for the ultrafast (<1 s) visual differentiation of aprotic/protic solvents, and the rapid (8 s) and sensitive detection of trace water in organic solvents with high sensitivity (limit of detection 0.01-0.30%). Besides, the on-site real-time sensing of relative humidity in air with satisfying selectivity and reversibility was realized based on solid-state fluorescence. The excellent fluorescence properties of neomangiferin-ZIF-8 have demonstrated great potential in real environmental applications, and the proposed defect-engineering strategy offers guidance for the construction of novel LMOFs sensors.

Automated summary

A new metal-organic framework (MOF) with a unique ligand-ligand charge transfer mechanism has been successfully fabricated using a novel strategy. The MOF exhibits reversible solvatochromic behavior and hydrogen-bonding-induced quenching effect, enabling fast differentiation of solvents and sensitive detection of trace water in organic solvents. Furthermore, the MOF allows for real-time sensing of humidity in air with satisfying selectivity and reversibility.