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Editorial Material
Physics, Condensed Matter
Zheng Tang et al.
JOURNAL OF SEMICONDUCTORS
(2023)
Article
Chemistry, Multidisciplinary
Liuyang Zhou et al.
Summary: The study successfully synthesized three D-A(1)-D-A(2) type terpolymers using a random ternary copolymerization strategy, with PZ-T as the second A-unit, to improve the photovoltaic performance of polymer solar cell donors.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Hao Lu et al.
Summary: In this study, two acceptors with different terminal groups but identical backbones were designed to enhance the PLQY of low bandgap acceptors. The results showed that improving the PLQY through terminal group engineering strategy effectively reduces nonradiative voltage loss in OSCs. A high power conversion efficiency of 17.1% was achieved in ternary OSCs based on the third component, SM16.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Hang Wang et al.
Summary: Three regioregular benzodithiophene-based donor-donor (D-D)-type polymers were designed, synthesized, and used in organic solar cells (OSCs), with one of them, PBDTT1Cl, demonstrating superior performance in terms of power conversion efficiency, charge mobility, and nonradiative energy loss.
ADVANCED MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Chenkai Sun et al.
Summary: This review article summarizes the recent developments of Qx-based D-A copolymer donors, including synthetic methods, backbone modulation, side chain optimization, and functional substitutions. Furthermore, the application of Qx-based D-A copolymers as hole transport material in pero-SCs is also introduced.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Kaien Chong et al.
Summary: This work demonstrates highly efficient polymer solar cells by improving charge extraction and suppressing charge recombination through side-chain engineering, adopting ternary blends, and introducing volatilizable solid additives. The optimized molecular structure and blend morphology lead to improved fill factor and power conversion efficiency.
ADVANCED MATERIALS
(2022)
Article
Engineering, Environmental
Qiang Zhang et al.
Summary: The simple halogenation strategy of side-chains has been proven effective in boosting the photovoltaic performance of organic solar cells. In this study, two novel D-A copolymer donors, PBDTTS-2FQx and PBDTTS-2ClQx, were developed and compared. The PBDTTS-2ClQx with chlorobenzene side chains exhibited redshifted absorption, suppressed energy levels, increased extinction coefficient, and improved electron mobility compared to PBDTTS-2FQx with fluorobenzene side chains. After blending with BTP-eC9, the PBDTTS-2ClQx:BTP-eC9 blend film showed higher and balanced hole/electron mobilities, improved aggregation, reduced charge carrier recombination, and better molecular order. Consequently, the OSCs based on PBDTTS-2ClQx:BTP-eC9 achieved an impressive power conversion efficiency of 16.1%, while the PBDTTS-2FQx-based OSCs only reached 12.2%. Chlorine side-chain engineering of the Qx-based copolymer donors was identified as a simple and effective approach to further enhance their photovoltaic performance.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Liang Xie et al.
Summary: The low-bandgap nonfullerene acceptor TIT-2FIC exhibits red-shifted absorption and higher HOMO energy level compared to analogues. It has broad miscibility with various donor materials, leading to promising power conversion efficiencies in both binary and ternary organic solar cells.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Mingrui Pu et al.
Summary: This study reports a method to manipulate the bicontinuous interpenetrating network morphology in organic solar cells by gradually introducing chlorine atoms. By utilizing this method, polymer donors with excellent photovoltaic performance are obtained, showing efficient exciton separation, faster charge transport, balanced charge mobilities, and suppressive bimolecular recombination in the solar cell devices. As a result, an outstanding power conversion efficiency is achieved.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Polymer Science
Yang Liu et al.
Summary: In this study, the carbon chain length modulation of poly(3-alkylthiophene) was found to have a significant impact on molecular packing and charge transport behavior, resulting in improved efficiency of polythiophene solar cells. The odd-even effects of the carbon chain length on polythiophene:nonfullerene blends were revealed, providing insights for optimizing low-cost polythiophene solar cells and other promising electronics.
Article
Chemistry, Multidisciplinary
Yueyue Gao et al.
Summary: The study introduces a series of simple non-fused-ring electron donors, PF1 and PF2, with small synthetic complexity and high synthetic yield. These new polymers, PF1 and PF2, exhibit larger conjugated plane and higher hole mobility compared to their all-thiophene-backbone counterpart, leading to improved device efficiencies. The optimized PF2-based devices, with the introduction of PC71BM as the third component, achieve the highest efficiency.
Article
Chemistry, Physical
Zongliang Ou et al.
Summary: Manipulation of the alkyl chain branching point can enhance the performance of conjugated polymers in optoelectronic devices. In this study, a new polymer donor was developed by shifting the branching point position, resulting in improved photovoltaic performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Physical
Wenhong Peng et al.
Summary: Ternary blending and random terpolymerization strategies have been proven effective for enhancing the performance of organic solar cells, with the construction of a new terpolymer PM6-Si30 showing improved efficiency in OSCs through improved charge transport and molecular arrangement.
Article
Chemistry, Multidisciplinary
Bing Zheng et al.
Summary: In this study, a new mesopolymer MePBDFClH is designed and synthesized as a donor material for high-performance organic solar cells (OSCs) and achieves a record power conversion efficiency (PCE) of 15.06%. Comparing with traditional polymers, mesopolymers show lower differentiation and great potential in producing high-performance organic photovoltaic materials.
Article
Chemistry, Multidisciplinary
Jianqiang Qin et al.
Summary: The study introduces a volatile solid additive-assisted sequential deposition strategy to optimize the morphology of the active layer in organic solar cells, resulting in enhanced performance. The combination of a volatile solid additive and sequential deposition method proves to be effective in developing high-performance OSCs.
Article
Chemistry, Multidisciplinary
Xiyue Yuan et al.
Summary: This paper reports a new PT with cyano-group substituents for high-efficiency OSCs. The cyano-group endows the PT with a deep-lying energy level and strong interchain interaction, resulting in improved device performance and power conversion efficiency.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jinglong Chen et al.
Summary: In this study, a new low-bandgap asymmetric small molecule acceptor TIT-2Cl based on thieno[3,2-b]indole core was introduced into PM6:Y6-based polymer solar cells (PSCs) to suppress the over-aggregation of Y6 molecules and improve the efficiency. The addition of TIT-2Cl contributed to improved light harvesting, charge separation, transport, and extraction. By using the layer-by-layer (LBL) progressive spin-coating method, the PSCs achieved a champion efficiency of 18.18%, the highest reported for PM6:Y6-based PSCs, with superior stability and compositional insensitivity.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Rui Sun et al.
Summary: The ternary strategy is an effective approach to achieve high-efficiency OSCs, but the nonradiative voltage loss limits further efficiency improvements. By incorporating an asymmetric guest acceptor BTP-2F2Cl, the OSCs show improved photoluminescence quantum yield, exciton diffusion length, and absorption spectrum, leading to enhanced power conversion efficiency.
ADVANCED MATERIALS
(2022)
Article
Engineering, Environmental
Qing Guo et al.
Summary: Regulating molecular aggregation state via chemical modification of photovoltaic materials to optimize the blend morphology is an effective strategy to improve the photovoltaic performance of organic solar cells (OSCs). In this study, a random terpolymer PF1 was developed by incorporating 1,3-bis(5bromo-4-fluorothiophen-2-yl)-5,7-bis(2-ethylhexyl)-4H,8H-benzo[1,2-c:4,5-c']bisthiophene-4,8-dione (BFT, 30 mol%) unit with fluorinated pi-bridges into the molecular backbone of PM6. The energy levels, molecular ordering, and aggregation properties of the polymer donors were precisely regulated, resulting in optimized photovoltaic properties of the related devices. The PF1:Y6-based OSCs achieved a power conversion efficiency (PCE) of up to 17.3%, outperforming the controlled OSCs based on PM6:Y6 (PCE = 16.2%).
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Haijun Bin et al.
Summary: Efficient organic solar cells based on a blend of PBDS-T and BTP-eC9 as the active layer materials are reported. The optimized device shows high open-circuit voltage, low photon-energy loss, and high internal quantum efficiency, leading to a power conversion efficiency of 16.4%. PBDS-T is a promising donor polymer due to its good solubility, wide optical bandgap, and high molecular weight synthesis capability. By annealing the as-cast films in solvent vapor, the device performance is significantly improved.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Polymer Science
Yang Liu et al.
Summary: Regulating the regioregularity of P3HT is crucial for enhancing its performance, but eco-friendly methods are limited. This study introduces a simple strategy to finely modulate the regioregularity of P3HT and elucidates its effect on non-fullerene solar cells for the first time. The experimental results indicate that regioregularity strongly impacts the polymer crystallinity, phase separation, and device performance. This research provides optimism for the application of eco-friendly polythiophenes in low-cost solar cells and beyond.
Article
Chemistry, Physical
Lei Zhu et al.
Summary: Morphological control of donor and acceptor domains is crucial for efficient organic photovoltaics, and this study demonstrates a double-fibril network strategy to achieve a high power conversion efficiency of 19.3%.
Article
Chemistry, Multidisciplinary
Wei Liu et al.
Summary: This study proposes a new design strategy for organic solar cell electron acceptors and successfully develops a quasi-macromolecule with an A-π-A structure. This quasi-macromolecule improves the long-term stability and power conversion efficiency of organic solar cells, and possesses synthetic flexibility and high molecular weight.
SCIENCE CHINA-CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Guilong Cai et al.
Summary: The study achieved a high open-circuit voltage binary D18-Cl/L8-BO system with the use of a volatile solid additive, 1,4-diiodobenzene (DIB), increasing crystalline packing and decreasing vertical domain sizes of phase separation. This led to improved exciton dissociation, charge transport, and collection, resulting in the best-performing device with an efficiency of 18.7%, making it the highest V-OC reported among OSCs with efficiencies over 17%. This work demonstrates the potential of solid additives with two iodine atoms to tune morphology in the vertical direction for future optimization of OSCs.
Article
Chemistry, Physical
Xiyue Yuan et al.
Summary: A new promising electron donor polythiophene has been developed for organic solar cells, which shows improved performance due to cyano-group substitutions and varied fluorination degrees. The incorporation of cyano-group provides deep-lying energy levels, and fluorination leads to enhanced interchain interaction and improved crystallinity, resulting in a record efficiency of 17.2% in the new polythiophene-based solar cells.
Editorial Material
Chemistry, Physical
Kaihu Xian et al.
Summary: Compared to complex and tedious synthesis of prevailing photovoltaic polymers, polythiophenes show greater commercial promise, despite their poor photovoltaic performances due to energy level mismatch and unfavorable mixing with non-fullerene acceptors. In a recent study, Duan and colleagues successfully developed a new series of polythiophene-based donors via only four steps, achieving a record-high efficiency of over 17%. The crucial roles of polymer solubility and molecular miscibility were also emphasized.
Article
Physics, Condensed Matter
Ke Jin et al.
JOURNAL OF SEMICONDUCTORS
(2022)
Article
Chemistry, Multidisciplinary
Qing Liao et al.
Summary: Although organic solar cells (OSCs) have achieved high photovoltaic efficiency, their practical use is limited by poor lifetime due to material decomposition caused by UV radiation. In this study, researchers have successfully fabricated highly efficient and exceptionally stable OSCs by incorporating a UV-resistant cathode interlayer (NDI-B) to protect the photovoltaic materials from UV-induced decomposition.
Article
Chemistry, Multidisciplinary
Hao Lu et al.
Summary: In this study, three terpolymer donors with enhanced solubility in nonhalogenated solvents were synthesized by random copolymerization. Among them, PL1-based OSCs exhibit higher charge mobilities and better power conversion efficiency compared to PM6 and D18.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Wei Gao et al.
Summary: By adopting the asymmetric selenium substitution strategy and using a pseudosymmetric electron acceptor, the power conversion efficiency of planar-mixed heterojunction organic solar cells (PMHJ OSCs) can be significantly improved. The increased dielectric constant and improved dimer packing lead to lower exciton binding energy, more efficient exciton dissociation, and reduced radiative recombination loss. These findings provide an effective way to develop highly efficient acceptor materials for OSCs.
ADVANCED MATERIALS
(2022)
Editorial Material
Physics, Condensed Matter
Jiamin Cao et al.
JOURNAL OF SEMICONDUCTORS
(2022)
Editorial Material
Physics, Condensed Matter
Min Li et al.
JOURNAL OF SEMICONDUCTORS
(2022)
Article
Engineering, Environmental
Jingnan Wu et al.
Summary: This study demonstrates a facile method to significantly improve the thin film morphology of active-layer materials in organic photovoltaic (OPV) cells, leading to enhanced photovoltaic performance and thermal stability. By fine-tuning the chemical structure of electron-deficient units in the wide bandgap donor polymer, the resulting terpolymers exhibited improved phase separation and favorable exciton dissociation, charge transport, and extraction. The achieved fill factor and power conversion efficiency were outstanding at 77.2% and 17.8%, respectively. The study highlights the importance of molecular structure variations in OPV materials and provides valuable insights for practical applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Pengqing Bi et al.
Summary: This study introduces PTVT-BT, a poly(thienylene vinylene) derivative with a simple molecular structure and high-performance in terms of power conversion efficiency. The findings suggest that PTVT-BT holds promise for future industrialization of organic photovoltaics.
Editorial Material
Physics, Condensed Matter
Erming Feng et al.
JOURNAL OF SEMICONDUCTORS
(2022)
Article
Chemistry, Multidisciplinary
Cunbin An et al.
Summary: In recent years, advancements in photovoltaic materials, particularly polymer donors and nonfullerene acceptors, have greatly increased the power conversion efficiencies of bulk heterojunction single-junction organic photovoltaic cells. The rational design of polymer donors is crucial for achieving high efficiencies by ensuring matching energy levels and absorption spectra with nonfullerene acceptors, as well as optimizing the morphology and electroluminescence quantum efficiency of the cells. Among various polymer donors, benzo[1,2-b:4,5-b']dithiophene-containing conjugated polymers have shown promising results. This review emphasizes the molecular design strategies of these polymer donors and discusses their impact on the photovoltaic efficiencies of organic photovoltaic cells.
ACCOUNTS OF MATERIALS RESEARCH
(2022)
Article
Chemistry, Physical
Zhihui Liao et al.
Summary: Researchers synthesized a series of terpolymer donors with varying fractions of ester-substituted thiazole (E-Tz) units using random ternary copolymerization. They found that fine-tuning the E-Tz content can optimize the energy levels, electrostatic potentials, molecular aggregation, miscibility, and morphology, resulting in improved performance parameters for photovoltaic devices.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Editorial Material
Physics, Condensed Matter
Baoqi Wu et al.
JOURNAL OF SEMICONDUCTORS
(2021)
Article
Physics, Condensed Matter
Xiongfeng Li et al.
JOURNAL OF SEMICONDUCTORS
(2021)
Article
Physics, Condensed Matter
Yufan Jiang et al.
JOURNAL OF SEMICONDUCTORS
(2021)
Article
Physics, Condensed Matter
Ke Jin et al.
JOURNAL OF SEMICONDUCTORS
(2021)
Article
Chemistry, Multidisciplinary
Sunan Bao et al.
Summary: Controlling the self-assembly of organic semiconductors to form well-developed nanoscale phase separation is critical for building high-performance organic solar cells. A new approach utilizing the synergistic effect of DTT and CN is developed to tune the morphology of the photoactive layer, leading to a significant increase in power-conversion efficiency and fill factor in ternary OSCs processed with dual additives of CN and DTT.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Qi Wang et al.
Summary: Polythiophenes, known for their low cost and high synthesis scalability, have gained attention in organic solar cell research. However, their performance in polythiophene:nonfullerene blend solar cells is hindered by poor miscibility between polythiophene and acceptors, necessitating efforts in engineering the molecular structure for better compatibility. Through group contribution calculations, the miscibility of these blends has been successfully adjusted by altering the ratios of specific chains in ester-substituted polythiophenes, leading to record-high power conversion efficiencies.
SCIENCE CHINA-CHEMISTRY
(2021)
Article
Chemistry, Physical
Haijun Ning et al.
Summary: NTI, synthesized in a one-step reaction, has a low-lying HOMO energy level, and when mixed with Y6, solar cell devices exhibit a high efficiency of 15.18%. NTI is a promising building unit for high-performance polymer donors due to its high efficiency and avoidance of multi-step synthesis.
CHEMISTRY OF MATERIALS
(2021)
Article
Chemistry, Physical
Jiabin Zhang et al.
Summary: Novel polymerized small molecular acceptors, PJTVT and PJTET, were designed with conjugated and unconjugated linking units respectively, demonstrating improved efficiency and stability for all-polymer solar cells through molecular modulation in the linking unit of the polymer acceptor.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Xiaodong Wang et al.
Summary: NFREAs with increasing pi-conjugation length show enhanced molar extinction coefficient and electron mobility in blend films. The molecular conformation of 2BTh-2F is planar, supported by S···N and S···O intramolecular interactions, and it forms a 3D network packing structure compared to the 2D packing of 2Th-2F. 2BTh-2F:PBDB-T-based organic solar cells achieve a high power conversion efficiency of 14.53%, reaching a record efficiency of 15.44% when D18 is used as the donor polymer.
ADVANCED ENERGY MATERIALS
(2021)
Article
Multidisciplinary Sciences
Junzhen Ren et al.
Summary: In this study, a new ester substituted poly(thiophene vinylene) derivative, PTVT-T, was successfully synthesized with commercially available raw materials. PTVT-T showed excellent compatibility with fullerene- and NF-based acceptors, exhibiting high efficiency in OSCs. With a power conversion efficiency of 16.20% in a PTVT-T:BTP-eC9-based device, this work demonstrates the huge potential of PTVT-T for the future commercialization of OSCs.
NATIONAL SCIENCE REVIEW
(2021)
Article
Chemistry, Multidisciplinary
Yuanyuan Zhou et al.
Summary: A series of tetrathiophene-based fully non-fused ring acceptors have been developed for efficient organic solar cells, with the ability to tune solubility and packing through lateral chain size adjustments. Incorporating 2-ethylhexyl chains enhances compatibility with donor polymers and achieves high power conversion efficiencies.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Can Zhu et al.
Summary: Side-chain engineering is a crucial strategy for enhancing the power conversion efficiency of organic solar cells. In this study, two copolymers were designed and synthesized, with PBQ6 exhibiting superior performance and achieving a high efficiency of 17.62% for organic solar cells.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Ye Xu et al.
Summary: This study demonstrates the design and application of a new wide-bandgap polymer, PBQx-TCl, in photovoltaic and light-emitting devices. Devices fabricated with nonfullerene acceptors show high power conversion efficiency under various lighting conditions, showcasing the potential of PBQx-TCl-based devices in both photovoltaic and light-emitting functions.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Jingyang Xiao et al.
Summary: A novel fluorinated polythiophene derivative, P4T2F-HD, is introduced to significantly improve the morphology of bulk heterojunction active layers in organic solar cells. By optimizing the film morphology and interface structure, a record power conversion efficiency of 13.65% for polythiophene-based OSCs was achieved through the use of P4T2F-HD:Y6-BO films processed from nonhalogenated solvents.
ADVANCED MATERIALS
(2021)
Article
Physics, Condensed Matter
Anxin Sun et al.
JOURNAL OF SEMICONDUCTORS
(2021)
Editorial Material
Physics, Condensed Matter
Xiaoyan Du et al.
JOURNAL OF SEMICONDUCTORS
(2021)
Article
Physics, Condensed Matter
Xianyi Meng et al.
JOURNAL OF SEMICONDUCTORS
(2021)
Article
Chemistry, Physical
Wenyan Yang et al.
Summary: The research found that as the thickness of the active layer of organic solar cells decreases, the thermal stability gradually increases, leading to the development of a new industrial index, i-FOM2.0, which helps address the balance between efficiency, stability, and cost, and accelerates the commercialization of OSCs.
Article
Chemistry, Physical
Rui Sun et al.
Summary: The study focuses on developing high-performance all-polymer solar cells by designing a novel polymer acceptor PY2F-T and enhancing efficiency through ternary blend with PYT in the PM6: PY2F-T host system. This approach significantly improves power conversion efficiency and stability, marking a promising future for the application of all-PSCs.
Article
Chemistry, Multidisciplinary
Chunyu Xu et al.
Summary: The study successfully prepared efficient semitransparent organic photovoltaic devices using a wide bandgap polymer and a small molecule blend system, achieving high visible light transmittance and high photovoltaic conversion efficiency through adjusting the blend ratio and optimizing the electrode structure.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Yong Cui et al.
Summary: By combining material design and ternary blending strategy, a maximum power conversion efficiency of 19.0% is achieved in single-junction OPV cells. Optimized active layer structure significantly improves the photovoltaic parameters, enhancing the performance and PCE values of the cells.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Tao Zhang et al.
Summary: This study introduces a new thiadiazole-based conjugated polymer PB2F with a deep HOMO level, achieving high PCE in OSCs when blended with IT-4F. Furthermore, adding PB2F as a third component to PBDB-TF:BTP-eC9 blend leads to outstanding PCE, one of the highest in OSCs.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Hang Yang et al.
Summary: In recent years, the innovation of narrow bandgap acceptor materials combined with wide bandgap donor materials has significantly improved the power conversion efficiencies of organic solar cells to exceed 18%. Key factors determining the photovoltaic performance of organic solar cells include absorption spectra, molecular orbital energy levels, molecular packing, and charge carrier mobilities. Strategies such as heteroatom substitution on the molecular backbone and halogen atom substitution can optimize the photovoltaic properties of donor materials, while flexible side chains like alkylthio and alkylsilyl can improve solubility and modulate energy levels and absorption spectra of photovoltaic materials.
ACCOUNTS OF MATERIALS RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Haijun Ning et al.
Summary: This study presents an effective method to develop high-performance polymer donors for layer-by-layer processed organic solar cells (LBL-OSCs) by manipulating their solubility properties, leading to improved efficiency and reproducibility. The research demonstrates that the solubility property of a polymer significantly impacts electron acceptor penetration, phase separation, and photovoltaic performance of LBL-OSCs.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Xiyue Yuan et al.
Summary: A new building block, 3-cyanothiophene (CT), was reported for constructing high-performance donor polymers in organic solar cells (OSCs). The donor polymer (PBCT-2F) based on the CT unit achieved a remarkable power conversion efficiency (PCE) of 17.1% and exhibited excellent batch-to-batch reproducibility, showing great potential for industrial synthesis and large-scale manufacturing.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Lijiao Ma et al.
Summary: The morphology of the bulk heterojunction is crucial for the efficiency of OPV cells, and modulating electrostatic interaction plays a key role in improving efficiency. Compatibility between the donor and acceptor in the active layer is important for phase separation morphology, and a specific molecular design strategy is proposed to optimize the D:A bulk morphology.
ACS MATERIALS LETTERS
(2021)
Review
Chemistry, Physical
Shreyam Chatterjee et al.
Summary: This review summarizes the critical evolution of various non-fullerene acceptors (NFAs) in combination with poly(3-hexylthiophene) (P3HT) in organic solar cells (OSCs) over the past decade, highlighting some important NFAs with new diversity and excellent performance. Additionally, it provides clear guidelines for further developing NFAs compatible with P3HT-based OSCs for future commercialization.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Review
Chemistry, Multidisciplinary
Yahui Liu et al.
Summary: The article discusses the application of organic semiconductors in photovoltaic materials, with a focus on the design and synthesis of conjugated polymers and small molecules, as well as the effectiveness of the intramolecular noncovalent interaction design strategy.
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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ACS ENERGY LETTERS
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NATURE COMMUNICATIONS
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Zuo Xiao et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2016)
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Jingbo Zhao et al.
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Yuze Lin et al.
ADVANCED MATERIALS
(2015)
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Xia Guo et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2012)
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Deping Qian et al.