4.6 Article

In situ formed cross-linked polymer networks as dual-functional layers for high-stable lithium metal batteries

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Constructing Binder- and Carbon Additive-Free Organosulfur Cathodes Based on Conducting Thiol-Polymers through Electropolymerization for Lithium-Sulfur Batteries

Jiaoyi Ning et al.

Summary: This study proves the concept of constructing binder- and carbon additive-free organosulfur cathode using thiol-containing conducting polymer PTBT. The PTBT-based cathode exhibits good reversible capacity and cycling performance, and eliminates the influence of additives, making it suitable for operando analysis as a model electrode.

CHEMSUSCHEM (2022)

Article Polymer Science

Synthesis of Proton Conductive Copolymers of Inorganic Polyacid Cluster Polyelectrolytes and PEO Bottlebrush Polymers

Zhuo-Qun Lu et al.

Summary: The characteristics of POMs and PEOs were combined to develop proton-conducting solid electrolytes. Copolymer polyelectrolytes composed of POM-polyelectrolyte complexes and PEO bottlebrush polymers showed high proton conductivities.

MACROMOLECULES (2022)

Article Chemistry, Physical

Scalable, Ultrathin, and High-Temperature-Resistant Solid Polymer Electrolytes for Energy-Dense Lithium Metal Batteries

Yinxing Ma et al.

Summary: This study reports a novel scalable, ultrathin, and high-temperature-resistant solid polymer electrolyte (SPE) for all-solid-state batteries (ASSBs), which exhibits advantages in terms of stability and mechanical strength at the solid electrolyte/lithium interface, as well as safe operation at high temperatures, showing great potential for practical applications.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Applied

A flexible, robust, and high ion-conducting solid electrolyte membranes enabled by interpenetrated network structure for all-solid-state lithium metal battery

Zhenchuan Tian et al.

Summary: Poly(vinyl alcohol)/poly(ethylene glycol) (PVA/PEG) semi-interpenetrating networks (s-IPN) were synthesized as solid electrolyte membranes for lithium metal batteries. The s-IPN structure suppressed crystallinity, resulting in enhanced lithium-ion conductivity and mechanical strength. The synthesized membranes exhibited high capacity and stable cycling performance.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Chemistry, Physical

Chitosan-grafted-Gallic Acid as a Nature-Inspired Multifunctional Binder for High-Performance Silicon Anodes in Lithium-Ion Batteries

K. K. Rajeev et al.

Summary: In this study, a rational design of a polymer binder using a plant-inspired adhesive phenolic moiety grafted onto a marine-based polymer improved the cycle performance of silicon in lithium-ion batteries.

ACS APPLIED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Revealing the Anion Chemistry Effect on Transport Properties of Ternary Gel Polymer Electrolytes

Maria Martinez-Ibanez et al.

Summary: The study focuses on the fundamental properties of PIL-based GPEs utilizing sulfonimide anions, aiming to provide a detailed understanding of the diffusion and conduction properties when different anions are involved. The results suggest that the FSI-based system exhibits higher ionic conductivities and better selectivity in cationic transport compared to other systems, potentially leading to the design of new GPEs with improved electrochemical performance.

CHEMISTRY OF MATERIALS (2022)

Article Chemistry, Physical

Interfacial optimization between cathode and 20 μm-thickness solid electrolyte membrane via in-situ polymerization for lithium metal batteries

Jian Ma et al.

Summary: This study demonstrates an optimization strategy for improving the interfacial contact between electrodes and solid electrolyte membranes in solid-state lithium batteries. By fabricating an ultrathin solid polymer electrolyte membrane and applying in-situ polymerization, the interfacial resistance is significantly reduced, resulting in better rate performance and cycle life. The application of in-situ polymerization shows promising prospects for enhancing the performance of solid-state lithium batteries.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Applied

Deep eutectic solvent-based polymer electrolyte for solid-state lithium metal batteries

Panpan Dong et al.

Summary: This study presents a novel solid-state PEO-deep eutectic solvent (DES) electrolyte and investigates its enhanced ionic conductivity and lithium-ion transference number. The in situ formation of DES reduces the crystallinity of PEO matrix and allows more Li+ ions to move freely. Molecular dynamics simulations reveal that more Li+ ions can be dissociated from Li salts in PEO-DES electrolyte. The PEO-DES electrolyte exhibits improved ionic conductivity and Li-ion transference number compared to conventional electrolytes, and shows good compatibility with Li metal.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Chemistry, Physical

Shape-memory and self-healing polyurethane-based solid polymer electrolytes constructed from polycaprolactone segment and disulfide metathesis

Yingjie Huang et al.

Summary: This study presents a polyurethane-based solid polymer electrolyte with shape-memory performance and readily healable ability, which can control shape with the help of soft segments and is suitable for assembling flexible batteries.

ENERGY STORAGE MATERIALS (2022)

Review Chemistry, Multidisciplinary

Research progress in stable interfacial constructions between composite polymer electrolytes and electrodes

Jun Pan et al.

Summary: Composite polymer electrolytes (CPEs) have great potential for commercialization due to their high ionic conductivity, good electrode contacts, and strong mechanical strength. However, the interface between CPE and electrode materials remains a challenge for the practical development of polymer solid-state lithium batteries.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Applied

Enhancing interfacial stability in solid-state lithium batteries with polymer/garnet solid electrolyte and composite cathode framework

Long Chen et al.

Summary: The newly prepared flexible polymer/garnet solid electrolyte exhibits a high ionic conductivity, improved mechanical properties, a wide electrochemical window, and enhanced thermal stability, providing a stable electrode/electrolyte interfacial contact for solid-state lithium batteries.

JOURNAL OF ENERGY CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Critical Current Density in Solid-State Lithium Metal Batteries: Mechanism, Influences, and Strategies

Yang Lu et al.

Summary: Solid-state lithium metal batteries have gained attention for their improved safety and high energy density, but issues such as dendrite-induced short circuits and contact-loss-induced high impedance hinder practical applications. The critical current density (CCD) is crucial for SSLMBs and future research should focus on strategies to enhance CCD for practical use.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Polycationic Polymer Layer for Air-Stable and Dendrite-Free Li Metal Anodes in Carbonate Electrolytes

Jingyi Wu et al.

Summary: Controllable dendrite growth in lithium metal batteries has been a major obstacle to their commercialization. A polycationic and hydrophobic polymer protective layer has been developed to address this issue, allowing for stable and efficient Li metal anodes. This protective layer enables steady Li plating/stripping, improved Li utilization efficiency, and enhanced electrochemical performance in cells utilizing LiNi0.8Mn0.1Co0.1O2 and LiFePO4. The layer also contributes to the formation of a stable solid electrolyte interphase (SEI), as demonstrated through mechanism investigation.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

An Organic/Inorganic Composite Gel Electrolyte Inducing Uniformly Lithium Deposition at High Current Density and Capacity

Xue Li et al.

Summary: A novel organic/inorganic composite gel electrolyte (PPPL) with excellent electrochemical performance, including high lithium transference number, wide electrochemical window, and satisfactory mechanical strength, has been proposed in this study. PPPL effectively suppresses lithium dendrite growth by forming stable and flexible solid electrolyte interface, providing important insights for the design of advanced GPEs.

ADVANCED MATERIALS INTERFACES (2021)

Review Chemistry, Physical

Stabilizing metal battery anodes through the design of solid electrolyte interphases

Qing Zhao et al.

Summary: The solid electrolyte interphase (SEI) is a chemically distinct material phase formed by a combination of electrochemical reduction and chemical reactions at both the explicit and implicit interfaces in all electrochemical cells. Understanding the structure, chemistry, and thermodynamics of the materials that accumulate in such interfacial material phases plays a crucial role in achieving high levels of anode reversibility in secondary batteries. Strategies focusing on the rational design of the SEI at metal anodes, including taking advantage of redox chemistry of electrolyte components and creating artificial SEI outside the cell, are highlighted in the study.
Article Chemistry, Multidisciplinary

High Energy Density Solid State Lithium Metal Batteries Enabled by Sub-5 μm Solid Polymer Electrolytes

Fei He et al.

Summary: Solid-state batteries (SSBs) are favored for their ability to address safety concerns and ensure high energy density. This study introduces an ultrathin bilayer solid-state electrolyte to enhance the safety and performance of SSBs, achieving high energy density goals.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Free-standing polymer electrolyte for all-solid-state lithium batteries operated at room temperature

Shih-Ting Hsu et al.

JOURNAL OF POWER SOURCES (2020)

Article Chemistry, Multidisciplinary

Fast Li+ Conduction Mechanism and Interfacial Chemistry of a NASICON/Polymer Composite Electrolyte

Nan Wu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Physical

Air-Stable and Dendrite-Free Lithium Metal Anodes Enabled by a Hybrid Interphase of C60 and Mg

Qingshuai Xu et al.

ADVANCED ENERGY MATERIALS (2020)

Article Multidisciplinary Sciences

Waterproof lithium metal anode enabled by cross-linking encapsulation

Ye Xiao et al.

SCIENCE BULLETIN (2020)

Article Chemistry, Physical

PAN/PI functional double-layer coating for dendrite-free lithium metal anodes

Fei Shen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

Facile Generation of Polymer-Alloy Hybrid Layers for Dendrite-Free Lithium-Metal Anodes with Improved Moisture Stability

Zhipeng Jiang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Applied

About the endothermal transitions of galactomannans: A multi-analytical DSC, LF-1H NMR and DMA study

Veronica M. Busch et al.

CARBOHYDRATE POLYMERS (2019)

Article Multidisciplinary Sciences

An air-stable and waterproof lithium metal anode enabled by wax composite packaging

Yunbo Zhang et al.

SCIENCE BULLETIN (2019)

Article Chemistry, Multidisciplinary

A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery

Tiantian Dong et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Nanoscience & Nanotechnology

2D MoS2 as an efficient protective layer for lithium metal anodes in high-performance Li-S batteries

Eunho Cha et al.

NATURE NANOTECHNOLOGY (2018)

Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

Review Chemistry, Multidisciplinary

Photochemically Driven Polymeric Network Formation: Synthesis and Applications

Eva Blasco et al.

ADVANCED MATERIALS (2017)

Article Materials Science, Composites

Polylactide-based nanocomposites with stereocomplex networks enhanced by GO-g-PDLA

Dongge Zhang et al.

COMPOSITES SCIENCE AND TECHNOLOGY (2017)

Article Chemistry, Multidisciplinary

Elemental-Sulfur-Mediated Facile Synthesis of a Covalent Triazine Framework for High-Performance Lithium-Sulfur Batteries

Siddulu Naidu Talapaneni et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications

Mao Chen et al.

CHEMICAL REVIEWS (2016)

Article Chemistry, Multidisciplinary

Ambient-Air Stable Lithiated Anode for Rechargeable Li-Ion Batteries with High Energy Density

Zeyuan Cao et al.

NANO LETTERS (2016)

Article Nanoscience & Nanotechnology

Facile Fabrication of Polymerizable Ionic Liquid Based-Gel Beads via Thiol-ene Chemistry

Mona Taghavikish et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

Article Electrochemistry

Effect of lithium bis(trifluoromethylsulfonyl)imide salt-doped UV-cured glycidyl methacrylate

Nurul Nabilah Mohd Radzir et al.

JOURNAL OF SOLID STATE ELECTROCHEMISTRY (2015)

Article Multidisciplinary Sciences

A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles

Snehashis Choudhury et al.

NATURE COMMUNICATIONS (2015)

Article Engineering, Chemical

Investigations on PEO/PVP/NaBr complexed polymer blend electrolytes for electrochemical cell applications

K. Kiran Kumar et al.

JOURNAL OF MEMBRANE SCIENCE (2014)

Article Chemistry, Physical

Nanoindentation testing of separators for lithium-ion batteries

Ion C. Halalay et al.

JOURNAL OF POWER SOURCES (2013)

Article Chemistry, Physical

New structural lithium battery electrolytes using thiol-ene chemistry

Markus Willgert et al.

SOLID STATE IONICS (2013)

Review Chemistry, Physical

Li-O2 and Li-S batteries with high energy storage

Peter G. Bruce et al.

NATURE MATERIALS (2012)

Article Polymer Science

Nanoindentation of shape memory polymer networks

Edem Wornyo et al.

POLYMER (2007)