☆ 4.6 Article

Cooperative catalysis of Co single atoms and nanoparticles enables selective CAr-OCH3 cleavage for sustainable production of lignin-based cyclohexanols

JOURNAL OF ENERGY CHEMISTRY (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Review Chemistry, Multidisciplinary

Conversion of biomass-derived feedstocks into value-added chemicals over single-atom catalysts

Sudipta De et al.

Summary: This review summarizes recent studies on the applications of single-atom catalysts (SACs) in the selective transformation of biomass-derived feedstocks into value-added products. SACs, with their selective nature, high atom efficiency, and tunable active sites, have shown great potential in achieving high selectivity towards complex molecules at a reduced cost.

GREEN CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Applied

Regulating the nanoscale intimacy of metal and acidic sites in Ru/γ-Al2O3 for the selective conversions of lignin-derived phenols to jet fuels

Shanshuai Chen et al.

Summary: The use of 4-trifuoromethyl salicylic acid (TFMSA) as an organic acid modifier on the catalyst surface successfully enhanced the efficiency of Ru/γ-Al2O3 catalyst in converting lignin-derived phenols to cycloalkanes, while demonstrating the crucial synergistic effect of metal nanoparticles and acidic sites on catalytic performance.

JOURNAL OF ENERGY CHEMISTRY (2022)

添加到收藏夹

Review Chemistry, Applied

Alcohol-assisted hydrodeoxygenation as a sustainable and cost-effective pathway for biomass derivatives upgrading

Hao Xu et al.

Summary: This review critically summarizes the potentials and challenges of alcohol-assisted hydrodeoxygenation (HDO) strategy from diverse perspectives including safety, economics, and catalytic efficiency. The alcohol-assisted strategy is divided into combined reforming-HDO route and catalytic transfer hydrogenation/hydrogenolysis (CTH) route based on the discrepancies of in-situ hydrogen generation. Different catalytic behaviors are described and their applications are elaborated in several upgrading processes of representative biomass model compounds, aiming to illustrate the potentials of alcohol-assisted HDO in biomass utilization.

JOURNAL OF ENERGY CHEMISTRY (2022)

添加到收藏夹

Review Chemistry, Applied

Catalyst activation: Surface doping effects of group VI transition metal dichalcogenides towards hydrogen evolution reaction in acidic media

Bibi Ruqia et al.

Summary: This review focuses on the effects of metal and non-metal doping on group VI TMDs for promoting hydrogen evolution reaction (HER) performances in acidic electrolytes. It provides an introduction to HER, synthetic methods for doped TMDs, and summarizes current challenges and future opportunities.

JOURNAL OF ENERGY CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Applied

D-band frontier: A new hydrogen evolution reaction activity descriptor of Pt single-atom catalysts

Guangming Zhan et al.

Summary: The hydrogen evolution reaction (HER) is crucial for sustainable development and carbon neutrality. Researchers have found that the d-band frontier descriptor of Pt single atoms on transition metal disulfides (Pt1/TMDs) is highly correlated with the Gibbs energy of H* adsorption. This descriptor can also be applied to Pt single atoms anchored on other supports.

JOURNAL OF ENERGY CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Applied

Scission of C-O and C-C linkages in lignin over RuRe alloy catalyst

Xinxin Li et al.

Summary: A multifunctional RuRe alloy catalyst was developed for efficient cleavage of C-O and C-C bonds in lignin model compounds and lignin, resulting in high yields of monocyclic compounds.

JOURNAL OF ENERGY CHEMISTRY (2022)

添加到收藏夹

Article Multidisciplinary Sciences

Transition-metal-free synthesis of pyrimidines from lignin β-O-4 segments via a one-pot multi-component reaction

Bo Zhang et al.

Summary: This study reports a novel method for synthesizing heterocyclic aromatic compounds from lignin, which is of great importance for expanding the product portfolio derived from biomass. The method is transition-metal free and sustainable, making it applicable for pharmaceutical synthesis.

NATURE COMMUNICATIONS (2022)

添加到收藏夹

Article Multidisciplinary Sciences

Subnanometric Ru clusters with upshifted D band center improve performance for alkaline hydrogen evolution reaction

Qi Hu et al.

Summary: The research shows that the size of Ru clusters affects their water dissociation activity, with subnanometric Ru clusters exhibiting stronger water dissociation ability and superior hydrogen evolution activity compared to single atoms and larger nanoparticles.

NATURE COMMUNICATIONS (2022)

添加到收藏夹

Review Chemistry, Applied

Transition metal-based single-atom catalysts (TM-SACs); rising materials for electrochemical CO2 reduction

Bishnupad Mohanty et al.

Summary: The continuous increase of atmospheric CO2 concentrations has led to severe environmental damage. Converting CO2 into valuable fuels and chemicals is a sustainable approach to reduce carbon intensity and support renewable energy. Transition metal-based single atoms catalysts (TM-SACs) have shown great potential in the electrochemical conversion of CO2, offering high activity and selectivity opportunities.

JOURNAL OF ENERGY CHEMISTRY (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

A unified view on catalytic conversion of biomass and waste plastics

Kyungho Lee et al.

Summary: This article summarizes the catalytic conversion of biomass and waste plastics, with a focus on bond activation chemistry and catalyst design. Tracking the historical and recent developments, it is found that biomass and plastic have started to influence each other's fields, providing new insights and opportunities for existing technologies and future advancements.

NATURE REVIEWS CHEMISTRY (2022)

添加到收藏夹

Article Multidisciplinary Sciences

Structural materials with afterglow room temperature phosphorescence activated by lignin oxidation

Keliang Wan et al.

Summary: In this study, an oxidation strategy was developed to convert lignin into long-lived phosphorescent materials. By modifying the structure of wood, sustainable wood materials with afterglow emission were successfully prepared, providing a new approach for the development of sustainable phosphorescent materials and structural materials.

NATURE COMMUNICATIONS (2022)

添加到收藏夹

Article Chemistry, Applied

Effect of TiO2 in supported NiWS catalysts for the hydrodeoxygenation of guaiacol

C. Garcia-Mendoza et al.

Summary: The research found that high acidity is beneficial for demethylation, while medium acidity may promote the cleavage of the aromatic-OCH3 bond. The higher the titania content, the stronger the catalyst's ability to produce completely deoxygenated compounds.

CATALYSIS TODAY (2021)

添加到收藏夹

Article Biotechnology & Applied Microbiology

Lignin valorization beyond energy use: has lignin's time finally come?

Chunbao Charles Xu et al.

Summary: Driven by the commercial availability of kraft lignin and hydrolysis lignin, there is a pressing need to valorize lignin for high-value chemical and material products. The engineering approach developed involves depolymerizing lignin into de-polymerized lignin and utilizing it to substitute petroleum-based compounds in the production of bio-based resins and foams, demonstrating technical and economic feasibility with a payback period of around 3 years for a commercial capacity of 40,000 t/y. This approach shows that lignin valorization beyond energy use can be profitable, marking a potential shift in the perception of lignin's value.

BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR (2021)

添加到收藏夹

Article Engineering, Chemical

Effect of the Support Functionalization of Mono- and Bimetallic Ni/Co Supported on Graphene in Hydrodeoxygenation of Guaiacol

Elodie Blanco et al.

Summary: The study shows that doping Ni/Co bimetallic catalysts with nitrogen can enhance catalytic activity through electron transfer from the support to metal particles and a synergistic effect between Ni and Co. The modification of graphene oxide with nitrogen can strengthen the effects of bimetallic catalysts.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

添加到收藏夹

Review Biochemistry & Molecular Biology

Lignin-to-chemicals: Application of catalytic hydrogenolysis of lignin to produce phenols and terephthalic acid via metal-based catalysts

Daobin Tang et al.

Summary: Utilizing metal catalysts for hydrogenolysis of lignin can produce lignin oil and further yield fine chemicals such as phenols and terephthalic acid. Current issues in lignin catalytic conversion are being investigated, but the future development prospects of this field are promising.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2021)

添加到收藏夹

Article Chemistry, Physical

Origin of the Activity of Co-N-C Catalysts for Chemoselective Hydrogenation of Nitroarenes

Muhong Li et al.

Summary: This study reveals several unusual generalities in the hydrogenation of nitroarenes, based on experiments with four typical Co-N-C materials derived from different methodologies, showing that the single-atom species Co-N-x are the main active sites of the Co-N-C catalysts in this process.

ACS CATALYSIS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Sustainable Production of Benzylamines from Lignin

Bo Zhang et al.

Summary: The study presents a new strategy for the direct transformation of lignin model compounds into benzylamines and phenols, with experimental data indicating the significance of dehydrogenation reaction and the role of secondary amines in the transformation. This work provides a novel opportunity for sustainable synthesis of benzylamines from renewable biomass, expanding the products pool of biomass conversion for future biorefinery demands.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Applied

H2-free demethoxylation of guaiacol in subcritical water using Pt supported on N-doped carbon catalysts: A cost-effective strategy for biomass upgrading

Laura Pastor-Perez et al.

Summary: The study demonstrates the viability of using Pt catalysts supported on N-doped activated carbons for the H2-free HDO process of guaiacol. The N-promoted samples showed higher selectivity towards oxygen-depleted products due to their modified electronic and acid-base properties. The best performing material, Pt/PANI-AC, achieved outstanding guaiacol conversion values and stable recycling operations.

JOURNAL OF ENERGY CHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

A review of hydrodeoxygenation of bio-oil: model compounds, catalysts, and equipment

Lu Qu et al.

Summary: This article reviews the model compounds, catalysts, and equipment involved in the hydrodeoxygenation (HDO) of bio-oils, aiming to summarize the progress in the utilization of the HDO process and provide useful insights for the efficient practical application of bio-oils.

GREEN CHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Physical

Recent Advancements of Porphyrin-Like Single-Atom Catalysts: Synthesis and Applications

Hongzhou Yang et al.

Summary: Porphyrin, an important biomimetic catalyst, shows high catalytic efficiency but has limitations such as decomposition and non-recyclability. With the development of single-atom catalysis, porphyrin-like single-atom catalysts are widely studied and possess good recyclability compared to traditional porphyrin catalysts. Porphyrin-like single-atom catalysts exhibit promising performance in various reactions.

SMALL STRUCTURES (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Sustainable production of pharmaceutical, nutraceutical and bioactive compounds from biomass and waste

Claudia Espro et al.

Summary: This tutorial review provides a general overview of processes, technologies, and challenges in producing pharmaceutical and bioactive compounds from food waste and lignocellulosic residues, with a focus on environmentally sustainable processes and novel green synthetic routes. Recent successful industrial applications of using food waste and lignocellulosic residues for pharmaceutical and nutraceutical purposes are also discussed.

CHEMICAL SOCIETY REVIEWS (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Emerging heterogeneous catalysts for biomass conversion: studies of the reaction mechanism

Longfei Lin et al.

Summary: Key recent advances in studying the reaction mechanisms of biomass conversion over emerging heterogeneous catalysts will inform the design of future catalytic systems showing improved activity and selectivity.

CHEMICAL SOCIETY REVIEWS (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis

Qi Wang et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Chemistry, Physical

Selective Hydrodeoxygenation of Guaiacol to Cyclohexanol Catalyzed by Nanoporous Nickel

Jiqing Lu et al.

CATALYSIS LETTERS (2020)

添加到收藏夹

Review Agricultural Engineering

A review on the catalytic hydrodeoxygenation of lignin-derived phenolic compounds and the conversion of raw lignin to hydrocarbon liquid fuels

Riyang Shu et al.

BIOMASS & BIOENERGY (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Chemicals from Lignin: A Review of Catalytic Conversion Involving Hydrogen

Yaxuan Jing et al.

CHEMSUSCHEM (2020)

添加到收藏夹

Article Chemistry, Physical

Highly-dispersed Ni on BEA catalyst prepared by ion-exchange-deposition-precipitation for improved hydrodeoxygenation activity

Penghui Yan et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Hydrodeoxygenation of lignin-derived phenolics - a review on the active sites of supported metal catalysts

Xinchao Wang et al.

GREEN CHEMISTRY (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Heterogeneous Atomic Catalysts Overcoming the Limitations of Single-Atom Catalysts

Hojin Jeong et al.

ACS NANO (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Downstream processing of lignin derived feedstock into end products

Sie Shing Wong et al.

CHEMICAL SOCIETY REVIEWS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Recent advances in the selective catalytic hydrodeoxygenation of lignin-derived oxygenates to arenes

Jianghao Zhang et al.

GREEN CHEMISTRY (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Selectively transform lignin into value-added chemicals

Qingqing Mei et al.

CHINESE CHEMICAL LETTERS (2019)

添加到收藏夹

Article Energy & Fuels

Hydrodeoxygenation of guaiacol as a model compound of lignin-derived pyrolysis bio-oil over zirconia-supported Rh catalyst: Process optimization and reaction kinetics

Yifeng He et al.

FUEL (2019)

添加到收藏夹

Article Chemistry, Physical

From Lignin to Chemicals: Hydrogenation of Lignin Models and Mechanistic Insights into Hydrodeoxygenation via Low-Temperature C-O Bond Cleavage

Charles E. J. J. Vriamont et al.

ACS CATALYSIS (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

Lukas Alig et al.

CHEMICAL REVIEWS (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Advances in porous and nanoscale catalysts for viable biomass conversion

Putla Sudarsanam et al.

CHEMICAL SOCIETY REVIEWS (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Bright Side of Lignin Depolymerization: Toward New Platform Chemicals

Zhuohua Sun et al.

CHEMICAL REVIEWS (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading

W. Schutyser et al.

CHEMICAL SOCIETY REVIEWS (2018)

添加到收藏夹

Article Chemistry, Physical

Elucidating the reactivity of methoxyphenol positional isomers towards hydrogen-transfer reactions by ATR-IR spectroscopy of the liquid-solid interface of RANEY® Ni

Ilton Barros Daltro de Castro et al.

CATALYSIS SCIENCE & TECHNOLOGY (2018)

添加到收藏夹

Article Chemistry, Physical

Optimum Cu nanoparticle catalysts for CO2 hydrogenation towards methanol

Xue Zhang et al.

NANO ENERGY (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Functionalised heterogeneous catalysts for sustainable biomass valorisation

Putla Sudarsanam et al.

CHEMICAL SOCIETY REVIEWS (2018)

添加到收藏夹

Article Chemistry, Physical

Ni nanoparticles entrapped in nickel phyllosilicate for selective hydrogenation of guaiacol to 2-methoxycyclohexanol

Xun Wang et al.

APPLIED CATALYSIS A-GENERAL (2018)

添加到收藏夹

Article Multidisciplinary Sciences

MOF-derived cobalt nanoparticles catalyze a general synthesis of amines

Rajenahally V. Jagadeesh et al.

SCIENCE (2017)

添加到收藏夹

Article Multidisciplinary Sciences

Manufacture of highly loaded silica-supported cobalt Fischer-Tropsch catalysts from a metal organic framework

Xiaohui Sun et al.

NATURE COMMUNICATIONS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Water-Assisted Selective Hydrodeoxygenation of Guaiacol to Cyclohexanol over Supported Ni and Co Bimetallic Catalysts

Minghao Zhou et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalysis Meets Nonthermal Separation for the Production of (Alkyl)phenols and Hydrocarbons from Pyrolysis Oil

Zhengwen Cao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Hydrothermally stable Ru/HZSM-5-catalyzed selective hydrogenolysis of lignin-derived substituted phenols to bio-arenes in water

Zhicheng Luo et al.

GREEN CHEMISTRY (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Catalytic Transformation of Lignin for the Production of Chemicals and Fuels

Changzhi Li et al.

CHEMICAL REVIEWS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synergistic effects of Ni and acid sites for hydrogenation and C-O bond cleavage of substituted phenols

Wenji Song et al.

GREEN CHEMISTRY (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

Lignin depolymerisation strategies: towards valuable chemicals and fuels

Chunping Xu et al.

CHEMICAL SOCIETY REVIEWS (2014)

添加到收藏夹

Review Multidisciplinary Sciences

Lignin Valorization: Improving Lignin Processing in the Biorefinery

Arthur J. Ragauskas et al.

SCIENCE (2014)

添加到收藏夹

Article Chemistry, Physical

Hierarchical H-ZSM-5-supported cobalt for the direct synthesis of gasoline-range hydrocarbons from syngas: Advantages, limitations, and mechanistic insight

Sina Sartipi et al.

JOURNAL OF CATALYSIS (2013)

添加到收藏夹

Article Chemistry, Physical

Stability and Hydrolyzation of Metal Organic Frameworks with Paddle-Wheel SBUs upon Hydration

Kui Tan et al.

CHEMISTRY OF MATERIALS (2012)

添加到收藏夹

Review Chemistry, Organic

Oxidative dearomatization of phenols:: Why, how and what for?

Stephane Quideau et al.

SYNLETT (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior

DN Dybtsev et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.