期刊
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
卷 54, 期 22, 页码 2284-2297出版社
WILEY
DOI: 10.1002/polb.24139
关键词
cellulose nanocrystal; crystallization; melt extrusion; poly(butylene adipate-co-terephthalate); polymer nanocomposite
资金
- Brazilian National Council for Scientific and Technological Development (CNPq)
- Ciencia Sem Fronteiras (CsF) program
- LabEx Tec 21 Investissements d'Avenir-grant [ANR-11-LABX-0030]
- PolyNat Carnot Institut Investissements d'Avenir-grant [ANR-11-CARN-030-01]
Cellulose nanocrystals (CNCs) are appealing nanomaterials for the reinforcement of polymeric materials. It is now well established that high mechanical properties are obtained when preparing the nanocomposite by casting/evaporation methods and using CNC contents above the percolation threshold. This phenomenon results from the formation of a stiff CNC network within the matrix meaning that the properties of the matrix play only a limited role on the mechanical properties of the material when the matrix is in the rubbery state. In subpercolation concentration or when using a different processing technique, the level of understanding is less clear, mainly when the CNC-induced crystallization of the matrix interferes with the reinforcing mechanism. In this study, we used CNCs with different aspect ratios to prepare nanocomposites by extrusion with polybutyrate adipate terephthalate as matrix. The impact of CNC on the crystallinity of the matrix and mechanical properties of the nanocomposite has been investigated. (C) 2016 Wiley Periodicals, Inc.
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