期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 54, 期 18, 页码 2907-2918出版社
WILEY-BLACKWELL
DOI: 10.1002/pola.28176
关键词
conjugated polymers; copolymerization; polyaromatics; direct arylation polymerisation; solar cells
资金
- Villum Foundation
- National Science Foundation (CBET Energy for Sustainability) [CBET-1436875]
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1436875] Funding Source: National Science Foundation
- Villum Fonden [00007258] Funding Source: researchfish
Despite the emergence of direct arylation polymerization (DArP) as an alternative method to traditional cross-coupling routes like Stille polymerization, the exploration of DArP polymers in practical applications like polymer solar cells (PSCs) is limited. DArP polymers tend to have a reputation for being marginally inferior to Stille counterparts due to the increased presence of defects that result from unwanted side reactions in direct arylation, such as unselective C-H bond activation and homocoupling. We report ten DArP protocols across the three major classes of DArP to generate poly[(2,5-bis(2-hexyldecyloxy) phenylene)-alt-(4,7-di(thiophen-2-yl) benzo[c][1,2,5]thiadiazole)] (PPDTBT). Through evaluation of the method and resulting photophysical and electronic properties, we show not all DArP methods are suitable for generating device-quality alternating copolymers. When DArP PPDTBT was synthesized in superheated THF with Cs2CO3, neodecanoic acid, and P(o-anisyl) 3, it generated polymers of exceptional quality that performed comparably to Stille counterparts in both roll coated ITO-free and spin-coated ITO devices. (C) 2016 Wiley Periodicals, Inc.
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