期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 54, 期 19, 页码 3057-3070出版社
WILEY
DOI: 10.1002/pola.28195
关键词
click chemistry; functionalization of polymers; sequential reactions; structure; synthesis
资金
- NTU [M4081566, M4011547]
- National Research Foundation of Korea grant - Korea government (MSIP) [2015R1D1A1A01057796]
- National Research Foundation of Korea [21A20131812182, 2015R1D1A1A01057796] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Base-catalyzed reaction between a thiol and an epoxide group is a simple fusion process that leads to the formation of a -hydroxythio-ether linkage. This reaction is efficient, regio-selective, and fast. In addition, it produces a reactive hydroxyl group upon completion. Therefore, it is of considerable potential in synthesis of reactive and functional soft materials. Here, we discuss the fundamental aspects of this process, the so-called thiol-epoxy click reaction, and its utility in the preparation and post-polymerization functionalization of polymers and crosslinked networks. Furthermore, its application in surface modification of solid substrates is also considered. Finally, utility of multifunctional materials created using the thiol-epoxy reaction is discussed in the biomedical arena. (c) 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 3057-3070
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