期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 10, 期 48, 页码 15642-15647出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c05307
关键词
Biomass conversion; Bioderived pyridinium salts; 5-Hydroxymethylfurfural (HMF); Green chemistry; Benign solvent
资金
- Leibniz Association
- Strategic Networking Funding Programme
A new sustainable protocol for the synthesis of bio-derived N-substituted 3-hydroxypyridinium salts from 5-hydroxymethylfurfural using water as a reaction medium is presented. The synthesis of 3-hydroxypyridine, 3-hydroxypyridinium N-oxide, 3-hydroxypiperidine, and a pyridostigmine analogue also highlights the application potentials of this approach.
We present a new sustainable protocol for the syntheses of bio-derived N-substituted 3-hydroxypyridinium salts with a broad substrate scope from 5-hydroxymethylfurfural using water as a reaction medium. 3-Hydroxypyridine, 3-hydroxypyridinium N-oxide, 3-hydroxypiperidine, and a pyridostigmine analogue were also synthesized, highlighting the application potentials of this approach.
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