4.6 Article

Preliminary Assessment of Pyrolysis Biochar Derived from Milk/Dairy Processing Sludge as a Potential Component of Fertilizers

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AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c06093

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P-recycling; P-fertilizer; nutrients; organic contaminants; heavy metals

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The disposal of waste-activated sludge from milk processing companies is an increasing concern due to nutrient loss and soil contamination. This study proposes the recovery of nutrients through biochar obtained from the slow pyrolysis of the waste. The properties of the biochar were examined, and it was found that most biochars meet the specified limits for nutrients and contaminants required for organic-mineral fertilizer. However, a minimum solid content of 30% in the waste is necessary for energetically sustainable biochar production.
Disposal of waste-activated sludge [dairy processing sludge, (DPS)] from wastewater treatment plants located in milk processing companies is an increasing concern. DPS is usually applied to farmlands in the vicinity of the dairy companies. This practice is becoming unsustainable due to uncontrolled nutrient loss and potential soil contamination. We propose to recover nutrients in the form of biochar. This paper examines the properties of biochars obtained from slow pyrolysis of DPS. DPS samples were pyrolyzed at laboratory and pilot scale at 600 and 700 degrees C. The elemental properties of biochars, the content of primary and secondary nutrients, as well as contaminants were examined and compared against the European Union Fertilizing Products Regulation. The biochars meet the specified limits for hydrogen-to-organic carbon ratio, chloride, and polycyclic aromatic hydrocarbons intended for gasification and pyrolysis component category materials. In six out of eight biochars, the content of phosphorus (P) as a single declared nutrient and the level of contaminants meet those required for an organo-mineral fertilizer. Only two biochars meet the required concentrations of nitrogen, phosphorus, and potassium. A minimum solid content of 30% in DPS is required to make the process of biochar production energetically sustainable.

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