Facile and scalable synthesis of un-doped, doped and co-doped graphene quantum dots: a comparative study on their impact for environmental applications

In recent years, graphene quantum dots (GQDs) received huge attention due to their unique properties and potential applicability in different area. Here, we report simple and facile method for the synthesis of GQDs and their functionalization by doping and co-doping using different heteroatom under the optimized conditions. The doping and co-doping of GQDs using boron and nitrogen have been confirmed by FTIR and TEM. The UV-visible and fluorescence techniques have been used to study the optical properties and stability of functionalized GQDs. Further, the screening for enhancement of quantum yields of all GQDs were performed with fluorescence and UV-visible spectra under the optimized conditions. The average QY was obtained as 16.0%, 83.6%, 18.2% and 29.6% for GQDs, B-GQDs, N-GQDs and B,N-GQDs, respectively. The sensor was used to determine paraoxon in water samples. The LOD was observed to be 1.0 x 10(-4) M with linearity range of 0.001 to 0.1 M. The RSD was calculated for the developed B,N-GQDs based sensor and observed to be 2.99% with the regression coefficient as 0.997. All the doped, co-doped and un-doped GQDs possess remarkable properties as a fluorescent probe.

Automated summary

A simple and facile method for the synthesis and functionalization of graphene quantum dots (GQDs) using doping and co-doping has been reported. The optical properties and stability of the functionalized GQDs were studied, and the quantum yields were enhanced under optimized conditions. A B,N-GQDs sensor was developed for the detection of paraoxon in water samples, showing a good linear range and low detection limit.