期刊
MATERIALS
卷 16, 期 2, 页码 -出版社
MDPI
DOI: 10.3390/ma16020499
关键词
coal gangue; acid leaching; CaF2; extraction of aluminum and iron ions
In this study, CaF2 and hydrochloric acid were used to extract Al3+ and Fe3+ from coal gangue calcined powder. The results showed that adding 3% CaF2 increased the extraction ratios of Al3+ and Fe3+. The mechanism of CaF2 as an auxiliary to improve the leaching ratio of Fe3+ was explained, and the CaF(2-)assisted acid leaching process was optimized. The research provides a reference for future production.
To reveal how CaF2 improves the dissolution ratios of aluminum and iron ions in coal gangue, CaF2 and hydrochloric acid are used to extract Al3+ and Fe3+ from the coal gangue calcined powder. The leaching ratios of Al3+ and Fe3+ are measured, and the filter residues are analyzed by BET, XRD, and SEM. The results show that adding 3% CaF2 could increase the extraction ratio of Al3+ from 62.96% to 92.10% under optimized conditions, and that of Fe3+ is increased from 85.12% to 95.73%. The mechanism of CaF2 as an auxiliary to improve the leaching ratio of Fe3+ is that HF reacts with the thin layers of gangue calcined powder containing silica to form soluble SiF4, thus forming pores that promote the diffusion of H+ and inner ions, improving the leaching ratios of Al3+ and Fe3+. Finally, the CaF(2-)assisted acid leaching process is optimized. The results showed that it is efficient and feasible to extract Al3+ and Fe3+ with the assistance of CaF2 and that HF has a catalytic effect in the reaction system. This work provides a reference for the next step of actual production.
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