期刊
JOURNAL OF PHYSICS-CONDENSED MATTER
卷 28, 期 30, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/28/30/304001
关键词
polycyclic aromatic hydrocarbon; charge transfer; orbital degeneracy; supramolecular rotor; molecular conductor
资金
- Japan Society for the Promotion of Science (JSPS) [23225005, 25288041, 26110512, 26286002]
- Grants-in-Aid for Scientific Research [16H04139, 26286002, 25288041, 26110512] Funding Source: KAKEN
Recent developments in the arena of charge-transfer complexes composed of the D-6h-symmetric polycyclic aromatic hydrocarbon, coronene, are highlighted with emphasis on the structural and physical properties of these complexes. Because of the dual electron-donating and - accepting abilities of coronene, this group involves structurally-defined four cation salts and three anion salts. The Jahn-Teller distortions and in-plane motion of coronene molecules in the solids, both of which are closely associated with the high symmetry of coronene molecules, and syntheses of clathrate-type complexes are also presented.
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