4.6 Review

MXene-Based Nanomaterials for Multifunctional Applications

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Article Chemistry, Multidisciplinary

Electronic Modulation of Metal-Organic Frameworks by Interfacial Bridging for Efficient pH-Universal Hydrogen Evolution

Luqi Wang et al.

Summary: This study reports a facile in situ growth strategy for the synthesis of tightly connected 2D/2D heterostructures by coupling MXene with CoBDC nanosheets. The optimized CoBDC/MXene exhibits superior hydrogen evolution reaction activity.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Engineering, Biomedical

Piezoresistive MXene/Silk fibroin nanocomposite hydrogel for accelerating bone regeneration by Re-establishing electrical microenvironment

Zhi-Chao Hu et al.

Summary: The electrical microenvironment plays a crucial role in bone repair, but the mechanism by which electrical stimulation promotes bone regeneration is unclear. In this study, an electroactive hydrogel based on regenerated silk fibroin (RSF) and MXene nanosheets was developed to efficiently promote bone regeneration. The hydrogel also functioned as a piezoresistive pressure transducer for monitoring the electrophysiological microenvironment.

BIOACTIVE MATERIALS (2023)

Article Chemistry, Multidisciplinary

Simplified Synthesis of Fluoride-Free Ti3C2Tx via Electrochemical Etching toward High- Performance Electrochemical Capacitors

Jizhang Chen et al.

Summary: A facile and time-saving electrochemical etching method is developed to synthesize F-free and Cl-containing Ti3C2Tx. Sonification alone is able to delaminate Ti3C2Tx without using any hazardous organic intercalant. The obtained Ti3C2Tx flakes exhibit suitable size and stability, and show excellent performance in supercapacitors and hybrid capacitors.

ACS NANO (2022)

Article Engineering, Biomedical

Electrically conductive 3D printed Ti 3 C 2 T x MXene-PEG composite constructs for cardiac tissue engineering

Gozde Basara et al.

Summary: A new composite construct has been developed in this study, which can provide both conductive and topographical cues for cardiac tissue engineering applications, potentially for the treatment of myocardial infarction.

ACTA BIOMATERIALIA (2022)

Article Engineering, Manufacturing

Flexible polyvinylidene fluoride(PVDF)/MXene(Ti3C2Tx)/Polyimide(PI) wearable electronic for body Monitoring, thermotherapy and electromagnetic interference shielding

Min Sang et al.

Summary: The multifunctional PVDF/MXene/PI electronic device exhibits strong mechanical performance, excellent mechanosensation ability, outstanding Joule heating capability, and effective electromagnetic interference shielding.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2022)

Article Electrochemistry

Fabrication of Ti3C2Tx MXene/polyaniline composite films with adjustable thickness for high-performance flexible all-solid-state symmetric supercapacitors

Wenlong Luo et al.

Summary: This study successfully fabricated adjustable thickness flexible Ti3C2Tx (MXene)/polyaniline (PANI) films as high-performance supercapacitor electrode materials. Introducing PANI nanofibers increases the specific capacitance of the MXene film, but excessive nanofibers lead to increased film thickness and decreased specific capacitance. The assembled device based on the optimal composite film exhibited high specific capacitance and capacitance retention rate, as well as excellent energy density.

ELECTROCHIMICA ACTA (2022)

Article Chemistry, Multidisciplinary

Freestanding and Sandwich MXene-Based Cathode with Suppressed Lithium Polysulfides Shuttle for Flexible Lithium-Sulfur Batteries

Xiongwei Zhong et al.

Summary: This paper reports a method of preparing large-area MXene film through drop-casting, and using this film to improve the adhesion and capacity retention of lithium-sulfur batteries. At the same time, titanium oxide anchored on MXene was prepared by oxidation treatment, which further promotes lithium ion transport and prevents the shuttle effect of lithium polysulfides.

NANO LETTERS (2022)

Article Chemistry, Multidisciplinary

Multiple Stimuli-Responsive MXene-Based Hydrogel as Intelligent Drug Delivery Carriers for Deep Chronic Wound Healing

Xin Yang et al.

Summary: A novel MXene-based hydrogel drug delivery system for efficient treatment of deep chronic wounds is introduced in the study. This system demonstrates multiple response capability and controllable drug delivery ability, reducing toxic side effects of drugs and promoting wound healing process. The practical performance of the system in treating rat models indicates great prospect in clinical wound healing and related biomedical fields.
Review Chemistry, Physical

Potential of MXene-Based Heterostructures for Energy Conversion and Storage

Jinbo Pang et al.

Summary: This focus review summarizes the recent progress in applications of MXenes and provides general guidelines for the rational design of MXene structures. The coupling of mixed-dimensional nanomaterials and the introduction of single atoms in hydrogen production, ammonia synthesis, multi-carbon compound generation, and energy storage applications are discussed. In addition, in situ characterization tools are briefly introduced as a potential means of understanding MXenes' chemical activity. Finally, an outlook on future opportunities is provided to stimulate discussion and further research into MXene material synthesis and mechanisms.

ACS ENERGY LETTERS (2022)

Article Materials Science, Composites

Mechanically and environmentally robust composite nanofibers with embedded MXene for wearable shielding of electromagnetic wave

Lixia Liu et al.

Summary: The newly designed EMI shielding PVDF-HFP composite fabric with MXene embedded in nanofibers shows excellent specific EMI shielding effectiveness, remains unchanged after exposure to acidic, alkaline, or saline solutions for 10 days, and can greatly enhance the strength and modulus of the fabric.

COMPOSITES COMMUNICATIONS (2022)

Article Chemistry, Physical

Platinum Nanoparticle-Electrodeposited Ti3C2Tx MXene as a Binder-Free Electrocatalyst for Improved Hydrogen Evolution

Xuan Jian et al.

Summary: This work presents a facile electrochemical method for the fabrication of a binder-free Ti3C2Tx MXene-supported low-Pt loading electrocatalyst. The Pt nanoparticle-deposited Ti3C2Tx MXene demonstrates better electrocatalytic activity for hydrogen evolution. Density functional theory calculations reveal the synergistic effect between Pt and Ti3C2Tx MXene.

ACS APPLIED ENERGY MATERIALS (2022)

Article Biochemistry & Molecular Biology

The Preparation of High-Performance and Stable MXene Nanofiltration Membranes with MXene Embedded in the Organic Phase

Qiang Xue et al.

Summary: Nanomaterials embedded in nanofiltration membranes, such as MXene, have shown promising results in improving separation performance. In this study, MXene nanocomposite membranes were achieved by dispersing MXene in the organic phase, resulting in enhanced negative charge and smaller effective pore size. The MXene membranes demonstrated high rejection for salts and maintained stability even after long-term water immersion. These findings provide theoretical guidance for future research in different addition methods and properties.

MEMBRANES (2022)

Article Chemistry, Multidisciplinary

Rational Design of Coordination Bond Connected Metal Organic Frameworks/MXene Hybrids for Efficient Solar Water Splitting

Litong Shi et al.

Summary: Metal organic frameworks (MOFs) are widely used as photocatalysts, but carrier recombination limits their activity. In this study, carboxyl groups on MXene were used to coordinate with UiO-66-NH2(Zr/Ti) (UZT) and create a tightly connected UiO-66-NH2(Zr/Ti)/carboxyl-functionalized MXene (UZT/CFMX) heterostructure. This unique heterostructure showed efficient solar-driven photocatalytic performance for water splitting, with a hydrogen evolution rate much higher than other MOF-based photocatalysts.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Analytical

Superhydrophobic Functionalized Ti3C2Tx MXene-Based Skin-Attachable and Wearable Electrochemical pH Sensor for Real-Time Sweat Detection

Lijuan Chen et al.

Summary: A sensitive, miniaturized, and flexible electrochemical sweat pH sensor was developed for real-time monitoring of hydrogen-ion concentration in human sweat. The sensor exhibited continuous and accurate measurement of sweat pH during exercise through the use of flexible electrodes and surface functionalization.

ANALYTICAL CHEMISTRY (2022)

Article Chemistry, Physical

Vertically Aligned MXene Nanosheet Arrays for High-Rate Lithium Metal Anodes

Qian Chen et al.

Summary: In this study, vertically aligned Ti3C2Tx MXene nanosheet arrays were used to regulate Li metal nucleation and deposition, resulting in high Coulombic efficiencies and stability.

ADVANCED ENERGY MATERIALS (2022)

Article Nanoscience & Nanotechnology

Wrinkle-structured MXene film assists flexible pressure sensors with superhigh sensitivity and ultrawide detection range

Yuhuan Lv et al.

Summary: In this study, a novel flexible pressure sensor with superhigh sensitivity and ultrawide detection range is designed and prepared based on wrinkle-structured MXene film. The sensor exhibits outstanding performance including high sensitivity, wide detection range, short response/recover time, high stability, and the ability to detect small movements in real time. It is expected to have significant potentials in future physiological detection and precision instrument monitoring systems.

NANOCOMPOSITES (2022)

Article Materials Science, Multidisciplinary

MXenes: The two-dimensional influencers

Mostafa Dadashi Firouzjaei et al.

Summary: MXenes, discovered in 2011, have made a significant impact on materials science and nanotechnology. With unique characteristics, they have shown promise in various applications and attracted a growing number of researchers in recent years.

MATERIALS TODAY ADVANCES (2022)

Article Chemistry, Multidisciplinary

3D printed MXene (Ti2AlN)/polycaprolactone composite scaffolds for in situ maxillofacial bone defect repair

Zhimin Xu et al.

Summary: This study prepared polycaprolactone (PCL) composite scaffolds with different contents of MXene (Ti2AlN) using 3D printing technology. The effects of Ti2AlN content on mechanical properties, hydrophilicity, cytocompatibility, and osteogenic differentiation ability were studied. The results showed that scaffolds containing 5% Ti2AlN exhibited the best cell adhesion and proliferation ability, and could significantly promote new bone formation.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Co7Fe3 Nanoparticles Confined in N-Doped Carbon Nanocubes for Highly Efficient, Rechargeable Zinc-Air Batteries

Teng-xiu Tu et al.

Summary: This study introduces a convenient method to prepare a difunctional catalyst with abundant active components through one-step pyrolysis. The catalyst, which is an Fe-, Co-, and N-codoped carbon-based cube hybrid, exhibits impressive activity and stability in electrocatalysis. Furthermore, it shows superior cycling stability in practical applications for zinc-air batteries.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Chemistry, Analytical

Ti3C2Tx MXene/urchin-like PANI hollow nanosphere composite for high performance flexible ammonia gas sensor

Yang Cai et al.

Summary: This study presents the fabrication of a high performance NH3 sensor based on Ti3C2Tx MXene nanosheet/urchin-like PANI hollow nanosphere composite through template method and in situ polymerization. The optimized sensor shows high response, excellent selectivity, good repeatability, satisfactory flexibility, and low detection limit. It also demonstrates successful application in monitoring the spoilage process of fresh pork.

ANALYTICA CHIMICA ACTA (2022)

Article Chemistry, Physical

Ultrafine Ru nanoparticles derived from few- layered Ti3C2Tx MXene templated MOF for highly efficient alkaline hydrogen evolution

Rong Luo et al.

Summary: The search for efficient and inexpensive electrocatalysts for hydrogen evolution reaction (HER) is of great significance due to the energy crisis and environmental pollution. In this study, ultrafine Ru nanoparticles were prepared using a hybrid of ZIF-L(Co) MOF and polydopamine coated few-layered Ti3C2Tx MXene (FL-Ti3C2Tx) as a template. The obtained Ru@ZIF-L(Co)/FL-Ti3C2Tx nanocomposite exhibited outstanding HER performance with low overpotential and excellent stability. This work provides a new strategy for the design and synthesis of highly efficient HER catalysts.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Rational design of MXene/activated carbon/polyoxometalate triple hybrid electrodes with enhanced capacitance for organic-electrolyte supercapacitors

Jun-Jie Zhu et al.

Summary: In this study, a triple hybrid electrode (MXene/activated carbon (AC)/polyoxometalates (POMs)) was developed, which combines the advantages of three different materials. The MXene/AC/POMs triple hybrids demonstrated enhanced charge storage efficiency through surface capacitive processes, achieving higher gravimetric and volumetric capacitance compared to the individual components. Substituting the cations in the POMs further improved the capacitance, and coupling with AC positive electrodes significantly increased the energy density.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Biotechnology & Applied Microbiology

GelMA-MXene hydrogel nerve conduits with microgrooves for spinal cord injury repair

Jiaying Cai et al.

Summary: The GelMA-MXene hydrogel nerve conduit with microgroove structures showed effective promotion of NSCs adhesion, proliferation, and differentiation. When loaded with NSCs and implanted into the injured spinal cord site, it demonstrated an effective repair capability for complete transection of SCI, resulting in remarkable nerve recovery.

JOURNAL OF NANOBIOTECHNOLOGY (2022)

Review Nanoscience & Nanotechnology

Electrospun MXene Nanosheet/Polymer Composites for Electromagnetic Shielding and Microwave Absorption: A Review

Yu-Rui Zhang et al.

Summary: This review presents the recent advances on electrospun MXene nanosheet/polymer composites for multifunctional EMI shielding, and addresses the challenges and prospects of the combination of MXene and electrospinning technology.

ACS APPLIED NANO MATERIALS (2022)

Article Nanoscience & Nanotechnology

Tannic Acid-Modified MXene as a Nanocarrier for the Delivery of β-Cyfluthrin as a Sustained Release Insecticide

Minghui Wan et al.

Summary: This study presents a smart pesticide delivery system based on MXene, which exhibits pH-responsive controlled release and improved leaf affinity. The system shows better insecticidal activity compared to conventional pesticides and has high biosafety to crops.

ACS APPLIED NANO MATERIALS (2022)

Article Chemistry, Multidisciplinary

MXene-based film electrode and all-round hydrogel electrolyte for flexible all-solid supercapacitor with extremely low working temperature

Juanjuan Yin et al.

Summary: This study reports a flexible supercapacitor assembled using designed MXene/carboxymethyl cellulose film electrode and all-round polyvinyl alcohol/LiCl hydrogel electrolyte. The supercapacitor exhibits excellent mechanical deformation, ultra-low temperature tolerance, high specific capacitance, and good electrochemical stability.

CELL REPORTS PHYSICAL SCIENCE (2022)

Article Public, Environmental & Occupational Health

Safe Synthesis of MAX and MXene: Guidelines to Reduce Risk During Synthesis

Christopher E. Shuck et al.

Summary: MXenes are emerging as promising materials in various fields, attracting increasing attention from researchers; ensuring the safe production of MXenes, with a focus on HF-based etching approaches, is crucial; discussing safety risks associated with each step of MXenes synthesis and taking necessary precautions are essential for safe, reproducible, and reliable synthesis.

ACS CHEMICAL HEALTH & SAFETY (2021)

Article Chemistry, Multidisciplinary

Halogenated Ti3C2 MXenes with Electrochemically Active Terminals for High-Performance Zinc Ion Batteries

Mian Li et al.

Summary: Experimental exploration of various halogen terminals on the surface of Ti3C2 MXenes showed that the presence of Br and I elements resulted in improved electrochemical performance for aqueous zinc ion batteries. The Lewis-acidic-melt etching route proved to be effective in tuning the surface chemistry of MXenes for expanding their potential applications.

ACS NANO (2021)

Article Nanoscience & Nanotechnology

Two-Dimensional F-Ti3C2Tx@Ag Composite for an Extraordinary Long Cycle Lifetime with High Specific Capacity in an Aluminum Battery

Xiaogeng Huo et al.

Summary: The research demonstrates that the two-dimensional material F-Ti3C2Tx@Ag exhibits excellent electrochemical performance in aluminum batteries, with long cycle lifetime and high specific capacity.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

2D MXenes: Tunable Mechanical and Tribological Properties

Brian C. Wyatt et al.

Summary: MXenes, as two-dimensional materials, have wide applications in energy, electronics, sensors, etc., with their mechanical properties, flexibility, and strong adhesion playing key roles. Despite the critical nature of MXenes' performance, further exploration is needed in understanding their mechanical and tribological behavior.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

In situ polymerized polyaniline/MXene (V2C) as building blocks of supercapacitor and ammonia sensor self-powered by electromagnetic-triboelectric hybrid generator

Xingwei Wang et al.

Summary: This study demonstrates the in situ polymerization of PANI/MXene composites for supercapacitor and ammonia sensor applications, powered by an electromagnetic-triboelectric hybrid generator. The PANI/MXene materials show high performance in terms of capacitance, energy density, and sensor response, making them promising candidates for self-powered gas sensing in industrial and agricultural settings.

NANO ENERGY (2021)

Article Chemistry, Physical

Induction of Co2P Growth on a MXene (Ti3C2Tx)-Modified Self-Supporting Electrode for Efficient Overall Water Splitting

Zepeng Lv et al.

Summary: This study demonstrates the controlled growth of Co2P NAs on the surface of a MXene-modified electrode as a competent bifunctional electrocatalyst for efficient water splitting. The optimized adsorption free energy and enhanced reaction activity contribute to the excellent water-splitting performance in alkaline solution.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Review Chemistry, Physical

Role of Ti3C2 MXene as Prominent Schottky Barriers in Driving Hydrogen Production through Photoinduced Water Splitting: A Comprehensive Review

Areen Sherryna et al.

Summary: Ti3C2 MXene stands out as a photocatalyst for its unique structure and excellent photochemical properties, offering alternatives for clean, sustainable, and renewable energy generation, especially in promoting photocatalytic hydrogen production.

ACS APPLIED ENERGY MATERIALS (2021)

Article Nanoscience & Nanotechnology

Flexible Ti3C2Tx MXene/PANI/Bacterial Cellulose Aerogel for e-Skins and Gas Sensing

Hui Zhi et al.

Summary: The study developed a flexible pressure sensor using a MXene/polyaniline/bacterial cellulose (MXene/PANI/BC) aerogel, capable of monitoring subtle motion signals such as finger bending, wrist bending, and pulse beating, as well as being sensitive to NH3. Bluetooth wireless transmission allows real-time monitoring of pressure distribution on a mobile phone, making it an ideal candidate for e-skins.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

High-Entropy 2D Carbide MXenes: TiVNbMoC3 and TiVCrMoC3

Srinivasa Kartik Nemani et al.

Summary: A study reports the synthesis of multi-principal-element high-entropy M4C3Tx MXenes, including two new high-entropy MXenes and their precursor MAX phases. The research utilized various characterization techniques to determine the structure and distribution of four transition metals in high-entropy MAX and MXene phases, along with first-principles calculations for formation energies. Experimental results show that using three transition metals instead of four can lead to the formation of two different MAX phases under similar synthesis conditions, highlighting the significance of configurational entropy in stabilizing high-entropy MAX phases.

ACS NANO (2021)

Article Energy & Fuels

Sphere-Shaped Bimetallic Sulphoselenide: An Efficient Electrocatalyst for Hydrogen Evolution Reaction

Kartick Chandra Majhi et al.

Summary: Bimetallic chalcogenides Fe2PdSe2 and Fe2PdSSe were prepared and characterized using various techniques. Fe2PdSSe exhibited superior electrocatalytic performance for hydrogen evolution reaction compared to Fe2PdSe2 due to its sphere-shaped surface morphology which creates more active sites.

ENERGY & FUELS (2021)

Article Chemistry, Physical

Effects of Intercalation on the Interlayer Electron-Transfer Process in Mo-Based Multilayered MXene Flakes

Junyan Chen et al.

Summary: MXene, a highly conductive 2D material with high cation capacity, is considered a promising choice for next-generation electrodes in energy-storage batteries. In practical applications, the electron transfer process across different layers in multilayered MXene flakes should be carefully investigated to improve performance. Temperature, cation intercalation, and flake morphology were found to influence the interlayer electron-transfer process sensitivity. Additionally, ultrafast time-resolved measurements showed suppression of the thermal-active regime for interlayer electron transfer in intercalated MXene flakes.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Properties of S-Functionalized Nitrogen-Based MXene (Ti2NS2) as a Hosting Material for Lithium-Sulfur Batteries

Chenghao Yao et al.

Summary: A method using Ti2NS2 as the sulfur cathode host material is proposed to improve the performance of Li-S batteries by effectively inhibiting the shuttle effect through moderate adsorption energies for Li2Sx species. This work provides a reference for the design of high-performance sulfur cathode materials.

NANOMATERIALS (2021)

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MXenes for electromagnetic interference shielding: Experimental and theoretical perspectives

A. Iqbal et al.

Summary: MXenes, as two-dimensional transition metal carbides, nitrides, and carbonitrides, show excellent electromagnetic interference shielding performance due to their intrinsic properties and extrinsic modifications. This review showcases the potential of MXene-based materials for the future electronics industry.

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Qin Yue et al.

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