Functional Metal/Carbon Composites Derived from Metal-Organic Frameworks: Insight into Structures, Properties, Performances, and Mechanisms

Article Nanoscience & Nanotechnology

Controlling the Interfacial Charge Polarization of MOF-Derived 0D-2D vdW Architectures as a Unique Strategy for Bifunctional Oxygen Electrocatalysis

Md Ariful Ahsan et al.

Summary: This study reports a synthetic strategy using metal-organic frameworks (MOFs) to fabricate low-dimensional nanohybrids and demonstrates their excellent performance in oxygen reduction/oxygen evolution electrocatalysis.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Engineering, Environmental

Environmentally persistent free radicals in bismuth-based metal-organic layers derivatives: Photodegradation of pollutants and mechanism unravelling

Ziwei Wang et al.

Summary: Formation of environmentally persistent free radicals (EPFRs) on carbonaceous material has attracted increasing research attention. In this study, EPFRs were detected in Bi-metal organic layers (Bi-MOLs) derivatives, as well as in HKUST-1 and UiO-66 based derivatives. The system with the highest EPFRs concentration showed superior photocatalytic performance, mainly attributed to the interaction between EPFRs and photoinduced active species, leading to more generation of reactive oxygen species (ROS) radicals. Mechanism investigation and DFT calculation suggested that EPFRs not only promote the generation of ROS but also enhance water oxidation by holes, paving the way for further implication of MOFs derivatives and understanding the role of EPFRs in photocatalysis.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Thickness-controllable synthesis of MOF-derived Ni@N-doped carbon hexagonal nanoflakes with dielectric-magnetic synergy toward wideband electromagnetic wave absorption

Liqiang Jin et al.

Summary: By controlling the adding dosage of pyridine, thickness controllable MOF-derived Ni@N-doped carbon (Ni@NC) hexagonal nanoflakes with increased content of doped N atoms and tunable morphology were obtained. The controllable dimension and morphology of N-doped carbon skeleton endowed more electronic transportation paths, better anti-reflection surfaces, higher conduction loss and polarization relaxation, while the evenly distributed Ni nanoparticles provided considerable multiple resonances and eddy current for improved electromagnetic wave absorption.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Engineering, Environmental

When bimetallic oxides and their complexes meet Fenton-like process

Wenhong Fu et al.

Summary: The heterogeneous Fenton-like reaction is efficient in removing organic contaminants. Bimetallic oxides and their complexes are gaining attention due to their high catalytic performance and stability. synergistic effect of the two metals in the bimetallic catalysts can enhance the utilization of hydrogen peroxide and improve catalytic performance.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Environmental Sciences

Iron-based metal-organic framework derived pyrolytic materials for effective Fenton-like catalysis: Performance, mechanisms and practicability

Yi Ren et al.

Summary: In this study, a new catalyst was developed for Fenton-like catalysis with high activity and stability. The catalyst was fabricated through pyrolysis under nitrogen atmosphere using MIL-53(Fe) as the precursor. Under optimized conditions, the new Fenton-like system showed low iron leaching and achieved high removal rates of bisphenol S (BPS). The main active species for BPS degradation were identified as hydroxyl radicals. This catalyst also demonstrated good potential for practical application in real wastewater.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Review Chemistry, Multidisciplinary

Macroscopic MOF Architectures: Effective Strategies for Practical Application in Water Treatment

Yiyuan Yao et al.

Summary: This article discusses successful strategies for fabricating macroscopic materials from MOFs and their applications in removing pollutants from water; the macroscopic performance of MOFs ranging from 0D to 3D can be utilized for water treatment through adsorption, separation, and advanced oxidation processes.

SMALL (2022)

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Article Chemistry, Applied

Novel fusiform core-shell-MOF derived intact metal@carbon composite: An efficient cathode catalyst for aqueous and solid-state Zn-air batteries

Di Zhou et al.

Summary: The Co/CoO@NSC bifunctional catalyst with interconnected porous architecture and intact metal@carbon structure shows superior electrocatalytic activities in ORR and OER comparable to Pt/C and RuO2 catalysts. The resulting Zn-air batteries exhibit high specific capacity, energy density, and long rechargeable properties, highlighting its potential as a rechargeable power source.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Cobalt Single Atoms Anchored on Oxygen-Doped Tubular Carbon Nitride for Efficient Peroxymonosulfate Activation: Simultaneous Coordination Structure and Morphology Modulation

Ziwei Wang et al.

Summary: By simultaneously regulating the coordination environment of single-atom catalysts and engineering architectures with efficient exposed active sites, the activation of peroxymonosulfate (PMS) can be greatly enhanced. This study successfully isolated cobalt atoms with dual nitrogen and oxygen coordination on oxygen-doped tubular carbon nitride, resulting in impressive mass activity and high selectivity for oxygen generation. The catalysts were also attached to a poly(vinylidene fluoride) microfiltration membrane for antibiotic wastewater treatment, achieving a high rejection rate for ciprofloxacin.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Physical

In-situ fabrication from MOFs derived MnxCo3-x@C modified graphite felt cathode for efficient electro-Fenton degradation of ciprofloxacin

Shuhong Huang et al.

Summary: In this study, MnxCo3-x@C-GF cathodes were fabricated for the treatment of ciprofloxacin (CIP) wastewater by adjusting the Mn/Co ratio. The optimized Mn2Co1@C-GF cathode showed excellent catalytic performance and stability, achieving a degradation efficiency of 99.8% for CIP within 60 minutes.

APPLIED SURFACE SCIENCE (2022)

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Review Chemistry, Inorganic & Nuclear

Modified UiO-66 as photocatalysts for boosting the carbon-neutral energy cycle and solving environmental remediation issues

Hongda Liu et al.

Summary: UiO-66, a water-resistant zirconium-based metal-organic framework, shows excellent environmental resistances and can be used in photocatalytic applications. The photoresponse range and charge separation efficiency of UiO-66 can be significantly improved by rational design and adjustment. This review provides an overview of the modification and design of UiO-66 and its applications in various fields, highlighting the reaction mechanisms.

COORDINATION CHEMISTRY REVIEWS (2022)

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Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks template-directed growth of layered double hydroxides: A fantastic conversion of functional materials

Guangfu Wang et al.

Summary: Template derivatization of metal-organic frameworks (MOFs) is an effective strategy for preparing functionalized materials. Chemically treated MOF precursors can be transformed into layered double hydroxides (LDHs), which enhance the stability, conductivity, and mass transfer capability of MOFs. This review summarizes the progress of MOF-derived LDHs and discusses their applications in the energy and environment fields.

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Engineering, Environmental

Metal-organic framework-derived magnetic carbon for efficient decontamination of organic pollutants via periodate activation: Surface atomic structure and mechanistic considerations

Yangke Long et al.

Summary: This study reports a surface atomic engineering strategy to obtain a novel hybrid activator exhibiting outstanding periodate activation properties, high stability, magnetic reusability, and great potential for application in complex water matrices. Density functional theory modeling suggests that the strong activation capability of the activator is related to its surface atomic structure.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Chemistry, Physical

Metal-organic frameworks-derived Ni2P@C Nanocomposite as a high-performance catalyst for hydrazine electrooxidation

Wentao Dai et al.

Summary: Metal-organic frameworks (MOFs) derived Ni2P@C nanocomposite has been successfully synthesized and applied as a promising anode electrocatalyst for direct hydrazine fuel cells (DHFCs). The electrocatalyst exhibits a large active surface area, 3D hierarchical porous structure, and good conductivity, resulting in impressive high activity, excellent stability, and nearly 100% selectivity toward N2H4 electrooxidation.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Chemistry, Physical

Metallic Co and crystalline Co-Mo oxides supported on graphite felt for bifunctional electrocatalytic hydrogen evolution and urea oxidation

Lei Lei et al.

Summary: In this study, a 3D bifunctional electrocatalyst was successfully fabricated by merging bimetallic Co-Mo oxides with metallic Co on a graphite felt substrate. It exhibited multi-site functionality for water reduction and urea oxidation simultaneously. The electrocatalyst showed low overpotentials for both oxygen evolution reaction (OER) and urea oxidation reaction (UOR) in an alkaline medium, indicating high efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Engineering, Environmental

MOF-derived N-doped ZnO carbon skeleton@hierarchical Bi2MoO6 S-scheme heterojunction for photodegradation of SMX: Mechanism, pathways and DFT calculation

Aiwen Wang et al.

Summary: The study successfully prepared nitrogen-doped ZnO carbon skeleton@Bi2MoO6 for photocatalytic degradation of sulfamethoxazole, achieving enhanced separation and migration of photo-generated electrons and holes through the construction of a special 3D layered structure and oxygen vacancies.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Chemistry, Physical

Ti3+ self-doped TiO2 nanotubes photoelectrode decorated with Ar-Fe2O3 derived from MIL-100(Fe): Enhanced photo-electrocatalytic performance for antibiotic degradation

Meiying Jia et al.

Summary: This study successfully prepared Ar-Fe2O3/Ti3+-TiO2-NTs photoelectrodes through multiple processes and achieved efficient degradation of antibiotics. The photoelectrodes exhibited excellent performance in various applications.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Engineering, Chemical

Biochar supported magnetic MIL-53-Fe derivatives as an efficient catalyst for peroxydisulfate activation towards antibiotics degradation

Jing Tong et al.

Summary: The study successfully improved the dispersibility and stability of catalysts by loading biochar onto MIL-53(Fe) derivatives, and showed high catalytic activity in degrading antibiotic wastewater.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Engineering, Environmental

Insight into metal-free carbon catalysis in enhanced permanganate oxidation: Changeover from electron donor to electron mediator

Peng Zhang et al.

Summary: Recent studies have shown that metal-free carbon materials can enhance permanganate oxidation for organic pollutant removal in water. However, the activation mechanism and active sites are still unclear due to the complex physicochemical properties of carbon. This study investigates the use of reduced graphene oxide (rGO) as a carbon material to boost permanganate oxidation and demonstrates two reaction pathways involved, namely electron donation by rGO and electron transfer mediation. The presence of oxygen-containing groups and structural defects in rGO are found to play crucial roles in electron transfer. Controlling the oxidation pathway in the rGO/PM system can be achieved by regulating the oxygen functional groups and structural defects.

WATER RESEARCH (2022)

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Article Chemistry, Physical

Sulfurization-functionalized 2D metal-organic frameworks for high-performance urea fuel cell

Xiang Ao et al.

Summary: Urea electrolysis is an effective solution for energy and environment issues. The use of a hierarchical structure derived from metal-organic framework improves catalytic activity and durability, offering potential for cost-effective hydrogen production and urea fuel cells.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Biotechnology & Applied Microbiology

Bio-electrocatalyst Fe3O4/Fe@C derived from MOF as a high-performance bioanode in single-chamber microbial fuel cell

Xu Pan et al.

Summary: The carbonized derivatives of MOF show potential application in MFC, with the CM53 derivative carbonized at 750 degrees C performing the best as a bioanode. It exhibits higher power density and lower charge transfer resistance compared to derivatives carbonized at lower temperatures. The synergy between carbon, iron, and Fe3O4 nanoparticles contributes to the improved performance.

BIOCHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Inorganic & Nuclear

Quasi-metal organic frameworks: Preparation, applications and future perspectives

Minoo Bagheri et al.

Summary: Metal-organic frameworks (MOFs) have outstanding features, but the binding of metal centers to linkers or solvent molecules limits their potential use in applications. Therefore, creating defects and forming defective MOFs with open metal centers are more suitable for a wide range of applications. This review provides an overview of defect engineering in MOFs and presents a comprehensive study of recent advances in various applications of quasi-MOFs.

COORDINATION CHEMISTRY REVIEWS (2022)

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Review Environmental Sciences

The application of transition metal-modified biochar in sulfate radical based advanced oxidation processes

Qingkai Shi et al.

Summary: Sulfate radical-based advanced oxidation processes are important for degrading organic pollutants in water. Transition metal-modified biochar is widely used as a catalyst in these processes, providing excellent properties and synergistic effects.

ENVIRONMENTAL RESEARCH (2022)

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Review Chemistry, Multidisciplinary

Single atoms meet metal-organic frameworks: collaborative efforts for efficient photocatalysis

Hongda Liu et al.

Summary: Photocatalysts with metal single atoms as active sites have gained much attention for their high efficiency and well-defined active centers. Metal-organic frameworks (MOFs) have emerged as promising supports for creating single atom catalysts. This review comprehensively summarizes the development of MOF-supported single atom catalysts in photocatalysis and discusses their applications in energy conversion.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

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Article Environmental Sciences

Progress and challenges of metal-organic frameworks-based materials for SR-AOPs applications in water treatment

Danlian Huang et al.

Summary: This paper provides an overview of the application of metal-organic frameworks (MOFs) in sulfate radical (SO4 center dot-) based advanced oxidation processes (SR-AOPs), highlighting the development and challenges in synthesizing different types of MOFs, their combination with other materials, and the construction of catalysts with special structures. It also discusses the mechanisms of MOFs and MOF-based materials as catalysts in activating PMS/PS in different systems, emphasizing the need for further improvements in this field.

CHEMOSPHERE (2021)

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Review Chemistry, Inorganic & Nuclear

Metal-organic framework-derived nanomaterials in environment related fields: Fundamentals, properties and applications

Yangzhuo He et al.

Summary: Metal-organic frameworks (MOFs) are a new class of crystalline porous materials composed of metal nodes and organic linkers, which have been widely used as versatile precursors in the preparation of various nanomaterials. The advantages of MOF-derived nanomaterials, such as controllable composition and high porosity, make them highly potential in environmental applications. This article summarizes the fundamental properties of these nanomaterials, highlights the strategies for enhancing performance, and discusses their recent progress in environmental cleaning and monitoring.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Physical

One-dimensional nitrogen-doped carbon frameworks embedded with zinc-cobalt nanoparticles for efficient overall water splitting

Yaoyao Deng et al.

Summary: In this study, Ag@ZnCo/NCF nanohybrids were successfully prepared as bifunctional electrocatalysts for hydrogen and oxygen evolution reactions, showing lower overpotentials and higher catalytic activity. This work offers a new perspective for designing low-cost and highly efficient electrocatalysts for overall water splitting.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Rational Fabrication of Low-Coordinate Single-Atom Ni Electrocatalysts by MOFs for Highly Selective CO2 Reduction

Yan Zhang et al.

Summary: A single-atom Ni catalyst with different N coordination numbers was fabricated using a post-synthetic metal substitution strategy. The Ni-N-3-C catalyst showed significantly enhanced COOH* formation leading to accelerated CO2 reduction, achieving high CO Faradaic efficiency and excellent performance in Zn-CO2 battery. This work provides a new approach for modulation of coordination microenvironment in single-atom catalysts for CO2 utilization.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Atomic-Level Modulation of Electronic Density at Cobalt Single-Atom Sites Derived from Metal-Organic Frameworks: Enhanced Oxygen Reduction Performance

Yuanjun Chen et al.

Summary: This study demonstrates the correlation between atomic configuration induced electronic density of single-atom Co active sites and oxygen reduction reaction (ORR) performance. The designed and synthesized Co-1-N3PS/HC catalyst shows outstanding ORR activity in alkaline and acidic media, surpassing Pt/C and most non-precious ORR electrocatalysts. Insights from this work promote rational design of efficient catalysts.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Ru doped bimetallic phosphide derived from 2D metal organic framework as active and robust electrocatalyst for water splitting

Yu Lin et al.

Summary: This study successfully developed a Ru-doped NiFeP/NF electrocatalyst with excellent hydrogen evolution performance in acid, neutral, and alkaline media. The OER in alkaline media only requires an overpotential of 179 mV to achieve 10 mA.cm(-2).

APPLIED SURFACE SCIENCE (2021)

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Article Materials Science, Ceramics

MOFs template derived Co/Fe binary phosphide nanocomposite embedded in ternary-doped carbon matrix for efficient water splitting

Yanan Zhang et al.

Summary: In this study, transition metal phosphides (TMPs) were prepared as highly efficient electrocatalysts using a simple and controllable strategy. The optimized ceramic material CoFeP@NSOC-400 showed remarkable bifunctional electrocatalytic performances, with low overpotentials for HER and OER in an alkaline electrolyte. Furthermore, when loaded on a conductive nickel foam, CoFeP@NSOC-400 exhibited superior performance in water splitting with negligible degradation over extended operation. These results highlight the potential of CoFeP@NSOC derived by MOFs through pyrolysis-phosphating as ideal electrocatalysts for energy conversion applications.

CERAMICS INTERNATIONAL (2021)

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Review Engineering, Environmental

The application of Zeolitic imidazolate frameworks (ZIFs) and their derivatives based materials for photocatalytic hydrogen evolution and pollutants treatment

Yang Liu et al.

Summary: This paper presents the application of zeolitic imidazolate frameworks and their derivatives in visible-light-induced photocatalytic hydrogen evolution and pollutants treatment, emphasizing the synergistic effects between the components in the composite catalyst for enhanced photocatalysis.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

A Complementary Co-Ni Phosphide/Bimetallic Alloy-Interspersed N-Doped Graphene Electrocatalyst for Overall Alkaline Water Splitting

Paulraj Arunkumar et al.

Summary: The Echinops-like bimetallic CoNiP-CoNi alloy synthesized from a metal-organic framework serves as an efficient catalyst for the oxygen evolution reaction (OER) in alkaline conditions. The integrated N-doped graphene enhances the activity of the catalyst towards the hydrogen evolution reaction, ultimately demonstrating excellent electrocatalytic activity and durability suitable for efficient alkaline water splitting.

CHEMSUSCHEM (2021)

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Article Engineering, Environmental

Bimetal-organic framework derived CoFe/NC porous hybrid nanorods as high-performance persulfate activators for bisphenol a degradation

Yu Wang et al.

Summary: The study utilizes bimetallic aminofunctionalized metal-organic frameworks to synthesize functional N-doped carbonaceous hybrid nanorods for efficient degradation of BPA without heat and light, achieving an 85% removal rate with the catalyst being reusable. By simultaneously generating ROS at the catalytic site and efficiently degrading BPA at the adsorption site, the research effectively overcomes the issue of short half-life of ROS and enhances catalytic activity.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Engineering, Environmental

Synthesis strategies and emerging mechanisms of metal-organic frameworks for sulfate radical-based advanced oxidation process: A review

Zhaokun Xiong et al.

Summary: This article provides an in-depth overview of the state-of-the-art metal-organic frameworks (MOFs)-based materials for sulfate radical-based advanced oxidation processes (SR-AOPs) applications, summarizing synthetic strategies, applications in wastewater treatment, and theoretical calculations to predict reaction mechanisms. Special emphasis is placed on the effects of structure on catalytic activities and the circumstances of radical and non-radical reaction mechanisms in MOFs-based SR-AOPs. Future research directions and unresolved challenges are also discussed.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Engineering, Environmental

Optimal preparation of catalytic Metal-organic framework derivatives and their efficient application in advanced oxidation processes

Danlian Huang et al.

Summary: Metal-organic frameworks (MOFs) derivatives show excellent user-configuration flexibility and improved stability, conductivity, and inherited characteristics after pyrolysis. Although the synthetic method of MOF derivatives is relatively rough, they are gradually being proven as potential alternative catalysts in advanced oxidation processes (AOPs).

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Dual-metal-organic frameworks derived manganese and zinc oxides nanohybrids as high performance anodes for lithium-ion batteries

Fuyuan Guo et al.

Summary: A novel approach was applied to synthesize Mn-Zn oxide nanohybrids embedded in porous carbon matrix, demonstrating superior lithium storage capabilities and high-rate cycling stability. The improved performance can be attributed to the interconnected porous structure of carbon frameworks and uniform heterostructure nanohybrids, facilitating charge transfer efficiency and buffering volume expansion.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

Scanty graphene-driven phase control and heteroatom functionalization of ZIF-67-derived CoP-draped N-doped carbon/graphene as a hybrid electrode for high-performance asymmetric supercapacitor

Sampath Gayathri et al.

Summary: ZIF-derived CoP-NPC/GS hybrid electrode exhibits superior electrochemical performance with high capacitance, enhanced rate capability, and stable cycling performance. The role of graphene in promoting redox-active CoP phase and enhanced electronic conductivity is key to the excellent performance of the electrode.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Environmental Sciences

Ag NPs decorated C-TiO2/Cd0.5Zn0.5S Z-scheme heterojunction for simultaneous RhB degradation and Cr(VI) reduction

Yuhan Wang et al.

Summary: In this study, heterojunction photocatalysts XAg@C-TCZ based on MOF-derived C-TiO2 and Cd0.5Zn0.5S decorated with Ag nanoparticles were successfully synthesized and exhibited efficient photocatalytic degradation and reduction properties. The Z-scheme heterojunction was confirmed through various characterization techniques, and the catalyst demonstrated stable performance in purifying complex pollutant systems.

ENVIRONMENTAL POLLUTION (2021)

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Article Environmental Sciences

Preparation of nitrogen self-doped hierarchical porous carbon with rapid-freezing support for cooperative pollutant adsorption and catalytic oxidation of persulfate

Keren Lu et al.

Summary: A method for synthesizing nitrogen self-doped hierarchical porous carbon materials derived from chitosan using KOH activation and rapid-freezing technology is reported. The resulting catalyst exhibits excellent persulfate activation ability, high resistance to inorganic anions, and a high proportion of graphitic nitrogen, providing sufficient active sites for persulfate activation. The catalyst also has a large specific surface area and a hierarchical pore structure, improving mass transfer efficiency.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Review Chemistry, Multidisciplinary

MOFs-Derived Carbon-Based Metal Catalysts for Energy-Related Electrocatalysis

Tongzhou Wang et al.

Summary: Electrochemical devices show great potential for sustainable development, but the lack of efficient electrocatalysts hinders their practical applications. Metal-organic frameworks (MOFs) derived catalysts with tunable structures and high activity have been intensively studied. These catalysts have shown promising applications in energy-related electrocatalysis such as hydrogen evolution, oxygen evolution, oxygen reduction, carbon dioxide reduction, and nitrogen reduction reactions.

SMALL (2021)

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Article Chemistry, Physical

Atomically Dispersed Fe-Heteroatom (N, S) Bridge Sites Anchored on Carbon Nanosheets for Promoting Oxygen Reduction Reaction

Mengran Wang et al.

Summary: This study developed a method to fabricate single Fe atom catalysts with good oxygen reduction activity. The FeN3S atomic sites induced charge redistribution, lowering the binding strength of oxygenated reaction intermediates and leading to improved reaction kinetics.

ACS ENERGY LETTERS (2021)

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Article Electrochemistry

Copper embedded in nitrogen-doped carbon matrix derived from metal-organic frameworks for boosting peroxide production and electro-Fenton catalysis

Yunting Wang et al.

Summary: In this study, we demonstrated that MOFs-derived Cu/N-C can serve as a highly efficient catalyst for two-electron ORR, producing H2O2 and OH simultaneously for pollutant degradation. Through physical characterization and electrochemical analysis, the Cu/N-C catalyst showed superior ORR performance and long-term stability. The synergetic effect between dispersed copper and nitrogen groups contributes to the enhanced two-electron ORR properties.

ELECTROCHIMICA ACTA (2021)

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Article Chemistry, Physical

In situ confinement pyrolysis of ZIF-67 nanocrystals on hollow carbon spheres towards efficient electrocatalysts for oxygen reduction

Lin Zhong et al.

Summary: An in situ confinement pyrolysis protocol was reported to transform ZIF-67 nanocrystals on hollow carbon spheres to cobalt and nitrogen-enriched carbon shell, resulting in the formation of hierarchical HCS@Co/NC. The catalyst exhibited excellent oxygen reduction reaction performance due to its structure and composition advantages, outperforming the commercial Pt/C benchmark.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Engineering, Environmental

Metal organic frameworks derived C/TiO2 for visible light photocatalysis: Simple synthesis and contribution of carbon species

Xin He et al.

Summary: In this study, carbon-doped TiO2 composites with a porous and crystalline structure were successfully synthesized via one-step and low-temperature calcination of titanium MOF. These composites exhibited outstanding photocatalytic activity and durability for BPA degradation, making them promising candidates for the photodegradation of organic pollutants.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Inorganic & Nuclear

Fabricating iron-cobalt layered double hydroxide derived from metal-organic framework for the activation of peroxymonosulfate towards tetracycline degradation

Yue Wang et al.

Summary: Iron-cobalt layered double hydroxide (FeCo-LDH) was synthesized by sacrificing Co-containing zeolite imidazolate framework materials (ZIF-67) in iron ethanolic solution at room temperature. FeCo-LDH-1.5 exhibited the highest catalytic activity for tetracycline degradation, with O-2(center dot-) and SO4 center dot- radicals identified as the primary reactive species. The FeCo-LDH-1.5/PMS system showed advantages in catalytic activity and reusability compared to Fe3+/PMS and Co2+/PMS homogeneous systems, demonstrating remarkable performance in actual wastewater treatment.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Engineering, Chemical

ZIF-67 derived magnetic nanoporous carbon coated by poly (m-phenylenediamine) for hexavalent chromium removal

Kaige Gao et al.

Summary: A novel core-shell magnetic nanomaterial has been successfully synthesized for the removal of highly toxic chromium (Cr(VI)) from water, showing high adsorption capacity, easy magnetic separation, and high structure stability. The adsorption mechanism is based on the synergistic effect of adsorption and reduction, with the removal rate following the pseudo-second-order model and fitting well to the modified Langmuir isothermal model. The promising application of the magnetic nanomaterial for Cr(VI) remediation in wastewater is highlighted.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Review Chemistry, Multidisciplinary

Single-Atom Catalysts Derived from Metal-Organic Frameworks for Electrochemical Applications

Lianli Zou et al.

Summary: This review summarizes the progress in the synthesis of MOF-derived SACs and their electrochemical applications. The synthetic approaches based on MOFs, characterization techniques for SACs, and their electrochemical applications including ORR, OER, HER, CO2RR, NRR, and other energy-related reactions are discussed. Insights into the current challenges and future prospects of this field are also briefly presented.

SMALL (2021)

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Article Engineering, Environmental

Ultrathin 2D catalysts with N-coordinated single Co atom outside Co cluster for highly efficient Zn-air battery

Hongbin Li et al.

Summary: A group of ultrathin 2D electrocatalysts, synthesized from a new metal-organic framework, show superior oxygen reduction reaction (ORR) activity and durability for zinc-air batteries, outperforming Pt/C catalysts. The strategy of designing and synthesizing these MOF-derived ultrathin electrocatalysts holds promise for developing metal-air batteries with higher power density.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Photocatalytic Hydrogen Evolution Coupled with Production of Highly Value-Added Organic Chemicals by a Composite Photocatalyst CdIn2S4@MIL-53-SO3Ni1/2

Huan-Huan Zhang et al.

Summary: The composite photocatalyst CdIn2S4@MIL-53-SO3Ni1/2 shows superior photocatalytic properties in promoting water splitting and selective oxidation of organic molecules under visible light irradiation. This is achieved by coating suspended ion catalyst (SIC) consisting of Ni-II ions on the surface of photoactive CdIn2S4, leading to efficient separation of photogenerated electron-hole pairs and high rate production of H-2 and selective production of valuable organic products. The composite photocatalyst demonstrates great potential for practical applications.

CHEMISTRY-AN ASIAN JOURNAL (2021)

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Article Energy & Fuels

Metal-organic framework derived NiO/Ni@C composites as electrode materials with excellent electrochemical performance for supercapacitors

XianYan Jiang et al.

Summary: In this study, NiO/Ni@C composites were successfully prepared as electrode materials and showed high specific capacitance and cycle stability after calcination at 500 degrees Celsius. The assembled ASC exhibited a wide working voltage range and high specific energy.

JOURNAL OF ENERGY STORAGE (2021)

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Article Engineering, Environmental

Engineering iron single atomic sites with adjacent ZrO2 nanoclusters via ligand-assisted strategy for effective oxygen reduction reaction and high-performance Zn-air batteries

Jie Zhang et al.

Summary: A ligand-assisted strategy was proposed to synthesize single atomic Fe-N-C catalyst derived from Zr-metal-organic frameworks (Zr-MOFs) to enhance ORR activity in Zn-air batteries. The resulting catalyst exhibited comparable ORR activity and outstanding stability due to the optimized Fe-N-4 configuration and strong interface interaction. Density functional theory calculation results further supported the improved ORR process and activity with adjacent ZrO2 nanocluster modulation.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Chemistry, Inorganic & Nuclear

Bismuth-based metal-organic frameworks and their derivatives: Opportunities and challenges

Ziwei Wang et al.

Summary: Bismuth-based metal-organic frameworks (Bi-MOFs) and their derivatives are a promising class of emerging coordination polymers with potential applications in catalysis, energy storage, biomedical imaging, drug delivery, fluorescence sensing, adsorption, and separation. Despite being in its early stages, recent pioneering studies in the field have provided insights and possibilities for further development.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Green & Sustainable Science & Technology

Heterogeneous fenton-like degradation of amoxicillin using MOF-derived Feo embedded in mesoporous carbon as an effective catalyst

Wuming Xie et al.

Summary: The study demonstrated that the FMC/H2O2 system has high efficiency in degrading AMX, with the FMC catalyst derived from Metal-organic frameworks showing accelerated production of .OH and enhanced removal efficiency of amoxicillin due to its carbon structures facilitating electron transfer.

JOURNAL OF CLEANER PRODUCTION (2021)

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Article Engineering, Environmental

Metal organic framework derived one-dimensional porous Fe/N-doped carbon nanofibers with enhanced catalytic performance

Saisai Chen et al.

Summary: This study presents a novel carbon catalyst based on hollow and porous one-dimensional Fe/N-doped carbon nanofibers (Fe/NCNFs) for activating peroxymonosulfate (PMS) towards efficient removal of phenol. The unique hierarchical architecture, large active surface area, well-dispersed Fe species, and abundant Fe-N active sites in Fe/NCNFs-9 contribute to its superior catalytic performance compared to PAN derived carbon (PAN-C-9) and Fe-MIL-101 derived carbon (Fe-C-9). Through inhibitor experiments and electrochemical tests, it was found that the radical pathway dominates in the BPA removal process with the participation of the non-radical pathway in the Fe/NCNFs-9/PMS/BPA system. Surprisingly, this strategy successfully disperses Fe species and reduces Fe leaching, providing a novel method for designing efficient MOFs-derived carbon catalysts for micropollutants removal.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Simultaneously Engineering the Coordination Environment and Pore Architecture of Metal-Organic Framework-Derived Single-Atomic Iron Catalysts for Ultraefficient Oxygen Reduction

Feng Liu et al.

Summary: By synergizing single iron active centers with local S atoms in metal-organic frameworks, this study has significantly enhanced the oxygen reduction reaction performance, leading to improved catalytic activity and battery performance.

SMALL (2021)

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Article Multidisciplinary Sciences

Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)

Tian Luo et al.

Summary: The study presents a highly efficient system for the photoreductive coupling of aldehydes and ketones to the corresponding 1,2-diols under mild conditions, addressing the challenge of constructing C-C bonds via reductive coupling of carbonyl compounds in organic transformations.

NATURE COMMUNICATIONS (2021)

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Article Engineering, Environmental

Co/Fe co-doped porous graphite carbon derived from metal organic framework for microelectrolysis-Fenton catalytic degradation of Rhodamine B

Peng Liu et al.

Summary: Co/Fe co-doped porous graphite carbon (Co/Fe-PGC) nanocomposites were successfully prepared and utilized for the efficient degradation of rhodamine B, achieving high removal rates of color and TOC, ultimately degrading it into harmless CO2 and H2O. The excellent catalytic performance of the catalyst is mainly attributed to the coupling effect between microelectrolysis and Fenton reaction, as well as the promotion of cobalt on electron transport and Fe2+ reduction.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Chemistry, Physical

Design of an amorphous and defect-rich CoMoOF layer as a pH-universal catalyst for the hydrogen evolution reaction

Lei Lei et al.

Summary: A brief structural design strategy was proposed to fabricate amorphous CoMo bimetallic oxyfluoride catalyst for efficient hydrogen evolution reaction. Theoretical calculations revealed a synergistic catalytic effect from the CoMo bimetallic components, enhancing the electrochemically active surface area. The constructed CoMoOF catalyst showed remarkable mass transfer ability, sufficient exposed atoms, and displayed excellent activity in both alkaline and acidic media with low overpotential and Tafel slope values.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis

Qi Wang et al.

CHEMICAL REVIEWS (2020)

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Article Engineering, Environmental

Oxidative degradation of pharmaceutical losartan potassium with N-doped hierarchical porous carbon and peroxymonosulfate

Julia Resende de Andrade et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Multidisciplinary

Creation of Redox-Active PdSx Nanoparticles Inside the Defect Pores of MOF UiO-66 with Unique Semihydrogenation Catalytic Properties

Ming-Jie Dong et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Hierarchically Porous Multimetal-Based Carbon Nanorod Hybrid as an Efficient Oxygen Catalyst for Rechargeable Zinc-Air Batteries

Dezhang Ren et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Metal-Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction

Xue Feng Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

In Situ Generation and Stabilization of Accessible Cu/Cu2O Heterojunctions inside Organic Frameworks for Highly Efficient Catalysis

Kai Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Engineering, Environmental

MOF-derived CoN/N-C@SiO2 yolk-shell nanoreactor with dual active sites for highly efficient catalytic advanced oxidation processes

Shouwei Zhang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Novel carbon based Fe-Co oxides derived from Prussian blue analogues activating peroxymonosulfate: Refractory drugs degradation without metal leaching

Chao Liu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

MOF derived ZnO/C nanocomposite with enhanced adsorption capacity and photocatalytic performance under sunlight

Cuicui Hu et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Accelerated Dinitrogen Electroreduction to Ammonia via Interfacial Polarization Triggered by Single-Atom Protrusions

Jie Li et al.

CHEM (2020)

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Article Multidisciplinary Sciences

Metal-organic framework-derived Ni@C and NiO@C as anode catalysts for urea fuel cells

Thao Quynh Ngan Tran et al.

SCIENTIFIC REPORTS (2020)

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Article Chemistry, Multidisciplinary

Cobalt Single-Atom Catalysts with High Stability for Selective Dehydrogenation of Formic Acid

Xiang Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Metal-Organic Framework-Based Catalysts with Single Metal Sites

Yong-Sheng Wei et al.

CHEMICAL REVIEWS (2020)

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Review Chemistry, Inorganic & Nuclear

Applications of metal-organic framework-derived materials in fuel cells and metal-air batteries

Xudong Wen et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Engineering, Environmental

Controlled pyrolysis of MIL-88A to prepare iron/carbon composites for synergistic persulfate oxidation of phenol: Catalytic performance and mechanism

Xiaojuan Li et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Metal-Organic Framework-Derived Co2P Nanoparticle/Multi-Doped Porous Carbon as a Trifunctional Electrocatalyst

Haitao Liu et al.

ADVANCED MATERIALS (2020)

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Article Engineering, Environmental

Uniform N-coordinated single-atomic iron sites dispersed in porous carbon framework to activate PMS for efficient BPA degradation via high-valent iron-oxo species

Yang Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

Assembly of MOFs/polymer hydrogel derived Fe3O4-CuO@hollow carbon spheres for photochemical oxidation: Freezing replacement for structural adjustment

Lei Qin et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Physical

Magnetic MIL(Fe)-type MOF-derived N-doped nano-ZVI@C rods as heterogeneous catalyst for the electro-Fenton degradation of gemfibrozil in a complex aqueous matrix

Zhihong Ye et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Physical

Atomically dispersed Ni species on N-doped carbon nanotubes for electroreduction of CO2 with nearly 100% CO selectivity

Ying Hou et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Physical

A facile synthesis for uniform tablet-like TiO2/C derived from Materials of Institut Lavoisier-125(Ti) (MIL-125(Ti)) and their enhanced visible light-driven photodegradation of tetracycline

Jinfeng Chen et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

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Article Nanoscience & Nanotechnology

MOF-Derived 2D/3D Hierarchical N-Doped Graphene as Support for Advanced Pt Utilization in Ethanol Fuel Cell

Jiaojiao Gao et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Physical

Salt-sealing-pyrolysis derived Ag/ZnO@C hollow structures towards efficient photo-oxidation of organic dye and water-born bacteria

Bingxuan Niu et al.

APPLIED SURFACE SCIENCE (2020)

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Review Chemistry, Physical

Electrocatalysis of Single-Atom Sites: Impacts of Atomic Coordination

Bingzhang Lu et al.

ACS CATALYSIS (2020)

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Review Chemistry, Physical

Recent Advances in MOF-Derived Single Atom Catalysts for Electrochemical Applications

Zhongxin Song et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Engineering, Environmental

MOFs-derived conductive structure for high-performance removal/release of phosphate as electrode material

Ruiting Liu et al.

WATER RESEARCH (2020)

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Article Multidisciplinary Sciences

Iron phthalocyanine with coordination induced electronic localization to boost oxygen reduction reaction

Kejun Chen et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Metal-Organic Framework Derived Fe7S8 Nanoparticles Embedded in Heteroatom-Doped Carbon with Lithium and Sodium Storage Capability

Huihua Li et al.

SMALL METHODS (2020)

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Article Chemistry, Physical

Anchoring Zn-phthalocyanines in the pore matrices of UiO-67 to improve highly the photocatalytic oxidation efficiency

Cai-Xia Lu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Physical

Single-Iron Site Catalysts with Self-Assembled Dual-size Architecture and Hierarchical Porosity for Proton-Exchange Membrane Fuel Cells

Xiaolin Zhao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Physical

Single Mn atom anchored on N-doped porous carbon as highly efficient Fenton-like catalyst for the degradation of organic contaminants

Jingren Yang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Multidisciplinary

A metal-organic framework/polymer derived catalyst containing single-atom nickel species for electrocatalysis

Shuliang Yang et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Physical

Structural engineering and surface modification of MOF-derived cobalt-based hybrid nanosheets for flexible solid-state supercapacitors

Shude Liu et al.

ENERGY STORAGE MATERIALS (2020)

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Review Chemistry, Physical

Megamerger of MOFs and g-C3N4 for energy and environment applications: upgrading the framework stability and performance

Gaoxia Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Bottom-up preparation of hierarchically porous MOF-modified carbon sphere derivatives for efficient oxygen reduction

Lulu Chai et al.

NANOSCALE (2020)

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Article Nanoscience & Nanotechnology

Metal-Organic-Framework-Derived N-, P-, and O-Codoped Nickel/Carbon Composites Homogeneously Decorated on Reduced Graphene Oxide for Energy Storage

Xiaoyan Shi et al.

ACS APPLIED NANO MATERIALS (2020)

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Article Chemistry, Physical

Ternary ZIF-8-derived dual-metal CoCu nanoparticles in porous carbon polyhedra as efficient catalysts for methanol oxidation

Chaoyun Tang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Core-shell-structured MOF-derived 2D hierarchical nanocatalysts with enhanced Fenton-like activities

Wenjie Shao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Generation of Nanoparticle, Atomic-Cluster, and Single-Atom Cobalt Catalysts from Zeolitic Imidazole Frameworks by Spatial Isolation and Their Use in Zinc-Air Batteries

Xiaopeng Han et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Engineering, Environmental

Activation of persulfate with metal-organic framework-derived nitrogen-doped porous Co@C nanoboxes for highly efficient p-Chloroaniline removal

Ying Liu et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Chemistry, Physical

MOF-derived C-doped ZnO composites for enhanced photocatalytic performance under visible light

Ying Zhang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

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Article Chemistry, Multidisciplinary

Co-Fe Alloy/N-Doped Carbon Hollow Spheres Derived from Dual Metal-Organic Frameworks for Enhanced Electrocatalytic Oxygen Reduction

Song Lin Zhang et al.

SMALL (2019)

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Article Chemistry, Physical

Oriented Transformation of Co-LDH into 2D/3D ZIF-67 to Achieve Co-N-C Hybrids for Efficient Overall Water Splitting

Ziliang Chen et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Solar-powered overall water splitting system combing metal-organic frameworks derived bimetallic nanohybrids based electrocatalysts and one organic solar cell

Rui Lin et al.

NANO ENERGY (2019)

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Review Chemistry, Multidisciplinary

Electrochemical CO2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

Md Golam Kibria et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Transformation of Metal-Organic Frameworks into Stable Organic Frameworks with Inherited Skeletons and Catalytic Properties

Kai Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Engineering, Environmental

Metal-organic framework-derived hollow Co3O4/carbon as efficient catalyst for peroxymonosulfate activation

Muhammad Abdul Nasir Khan et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Chemistry, Physical

Co-based MOF-derived Co/CoN/Co2P ternary composite embedded in N- and P-doped carbon as bifunctional nanocatalysts for efficient overall water splitting

Lei Hu et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

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Article Chemistry, Multidisciplinary

Photocatalytic Degradation of Tetracycline Antibiotics over CdS/Nitrogen-Doped-Carbon Composites Derived from in Situ Carbonization of Metal-Organic Frameworks

Hai-Lei Cao et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Chemistry, Physical

High-performance single atom bifunctional oxygen catalysts derived from ZIF-67 superstructures

Xueping Sun et al.

NANO ENERGY (2019)

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Article Chemistry, Multidisciplinary

Fe-Nanoporous Carbon Derived from MIL-53(Fe): A Heterogeneous Catalyst for Mineralization of Organic Pollutants

Thi Xuan Huong Le et al.

NANOMATERIALS (2019)

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Article Nanoscience & Nanotechnology

MOF-Derived Isolated Fe Atoms Implanted in N -Doped 3D Hierarchical Carbon as an Efficient ORR Electrocatalyst in Both Alkaline and Acidic Media

Xiaodong Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Suspending Ion Electrocatalysts in Charged Metal-Organic Frameworks to Improve the Conductivity and Selectivity in Electroorganic Synthesis

Wei-Wei Guo et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

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Article Chemistry, Physical

Nitrogen-coordinated single iron atom catalysts derived from metal organic frameworks for oxygen reduction reaction

Fei Xiao et al.

NANO ENERGY (2019)

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Article Chemistry, Physical

Nitrogen-doped carbon shell-confined Ni3S2 composite nanosheets derived from Ni-MOF for high performance sodium-ion battery anodes

Wei Shuang et al.

NANO ENERGY (2019)

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Article Chemistry, Multidisciplinary

Bi-Microporous Metal-Organic Frameworks with Cubane [M4(OH)4] (M=Ni, Co) Clusters and Pore-Space Partition for Electrocatalytic Methanol Oxidation Reaction

Ya-Pan Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Physical

Coupling metal-organic frameworks and g-C3N4 to derive Fe@N-doped graphene-like carbon for peroxymonosulfate activation: Upgrading framework stability and performance

Chao Liu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Engineering, Environmental

MOF-derived three-dimensional flower-like FeCu@C composite as an efficient Fenton-like catalyst for sulfamethazine degradation

Juntao Tang et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Review Chemistry, Analytical

Metal-organic frameworks as an emerging tool for sensing various targets in aqueous and biological media

Waseem Raza et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2019)

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Article Engineering, Environmental

Strengthened Fenton degradation of phenol catalyzed by core/shell Fe-Pd@C nanocomposites derived from mechanochemically synthesized Fe-Metal organic frameworks

Dongwei He et al.

WATER RESEARCH (2019)

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Article Chemistry, Multidisciplinary

Puffing Up Energetic Metal-Organic Frameworks to Large Carbon Networks with Hierarchical Porosity and Atomically Dispersed Metal Sites

Ruo Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Bimetallic Metal-Organic Framework Derived Metal-Carbon Hybrid for Efficient Reversible Oxygen Electrocatalysis

Yu Zhou et al.

FRONTIERS IN CHEMISTRY (2019)

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Article Chemistry, Physical

Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions

Yaru Luo et al.

JOULE (2019)

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Review Chemistry, Physical

Recent Advances for MOF-Derived Carbon-Supported Single-Atom Catalysts

Aijuan Han et al.

SMALL METHODS (2019)

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Article Chemistry, Physical

Metal-organic framework-derived Co9S8 embedded in N, O and S-tridoped carbon nanomaterials as an efficient oxygen bifunctional electrocatalyst

Jin-Yan Zhao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

One-step MOF-derived Co/Co9S8 nanoparticles embedded in nitrogen, sulfur and oxygen ternary-doped porous carbon: an efficient electrocatalyst for overall water splitting

Jiao Du et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Physical

Metal-organic framework-derived, Zn-doped porous carbon polyhedra with enhanced activity as bifunctional catalysts for rechargeable zinc-air batteries

Xuan Wu et al.

NANO RESEARCH (2018)

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Review Chemistry, Multidisciplinary

Metal-Organic Framework-Derived Materials for Sodium Energy Storage

Guoqiang Zou et al.

SMALL (2018)

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Article Nanoscience & Nanotechnology

Metal Organic Frameworks-Derived Co2P@N-C@rGO with Dual Protection Layers for Improved Sodium Storage

Ran Jin et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Multidisciplinary

Single Tungsten Atoms Supported on MOF-Derived N-Doped Carbon for Robust Electrochemical Hydrogen Evolution

Wenxing Chen et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells

Xiao Xia Wang et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Physical

NiSn bimetallic nanoparticles as stable electrocatalysts for methanol oxidation reaction

Junshan Li et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Magnetic porous Fe3O4/carbon octahedra derived from iron-based metal-organic framework as heterogeneous Fenton-like catalyst

Wenhui Li et al.

APPLIED SURFACE SCIENCE (2018)

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Article Chemistry, Multidisciplinary

Isolated Fe and Co dual active sites on nitrogen-doped carbon for a highly efficient oxygen reduction reaction

Diyang Zhang et al.

CHEMICAL COMMUNICATIONS (2018)

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Article Engineering, Environmental

Fenton-like degradation of sulfamethoxazole using Fe-based magnetic nanoparticles embedded into mesoporous carbon hybrid as an efficient catalyst

Juntao Tang et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Review Chemistry, Inorganic & Nuclear

Metal-organic framework-derived porous materials for catalysis

Yu-Zhen Chen et al.

COORDINATION CHEMISTRY REVIEWS (2018)

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Article Chemistry, Inorganic & Nuclear

Synthesis of octahedral like Cu-BTC derivatives derived from MOF calcined under different atmosphere for application in CO oxidation

Yiqiong Yang et al.

JOURNAL OF SOLID STATE CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Core-Shell ZIF-8@ZIF-67-Derived CoP Nanoparticle-Embedded N-Doped Carbon Nanotube Hollow Polyhedron for Efficient Overall Water Splitting

Yuan Pan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Multidisciplinary

Metal organic framework-derived CoPS/N-doped carbon for efficient electrocatalytic hydrogen evolution

Yuzhi Li et al.

NANOSCALE (2018)

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Article Chemistry, Multidisciplinary

Co9S8 Nanoparticles-Embedded N/S-Codoped Carbon Nanofibers Derived from Metal-Organic Framework-Wrapped CdS Nanowires for Efficient Oxygen Evolution Reaction

Lan-Lan Wu et al.

SMALL (2018)

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Article Chemistry, Multidisciplinary

Porous Carbon-Hosted Atomically Dispersed Iron-Nitrogen Moiety as Enhanced Electrocatalysts for Oxygen Reduction Reaction in a Wide Range of pH

Shaofang Fu et al.

SMALL (2018)

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Article Chemistry, Physical

Earthworm-like N, S-Doped carbon tube-encapsulated Co9S8 nanocomposites derived from nanoscaled metal-organic frameworks for highly efficient bifunctional oxygen catalysis

Tao Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Physical

Metal-organic frameworks derived hollow NiS2 spheres encased in graphene layers for enhanced sodium-ion storage

Ran Bi et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Physical

Layered Metal-Organic Framework-Derived Metal Oxide/Carbon Nanosheet Arrays for Catalyzing the Oxygen Evolution Reaction

Jian Zhou et al.

ACS ENERGY LETTERS (2018)

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Article Chemistry, Multidisciplinary

Metal-Organic Framework Derived Spindle-like Carbon Incorporated alpha-Fe2O3 Grown on Carbon Nanotube Fiber as Anodes for High-Performance Wearable Asymmetric Supercapacitors

Zhenyu Zhou et al.

ACS NANO (2018)

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Article Engineering, Environmental

Enhancement of Fe@porous carbon to be an efficient mediator for peroxymonosulfate activation for oxidation of organic contaminants: Incorporation NH2-group into structure of its MOF precursor

Chao Liu et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Engineering, Environmental

Magnetic nitrogen-doped nanocarbons for enhanced metal-free catalytic oxidation: Integrated experimental and theoretical investigations for mechanism and application

Huarui Li et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Chemistry, Multidisciplinary

Key Single-Atom Electrocatalysis in Metal-Organic Framework (MOF)-Derived Bifunctional Catalysts

Wanpeng Zhao et al.

CHEMSUSCHEM (2018)

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Article Chemistry, Physical

Facile synthesis of metal-organic framework-derived Co3O4 with different morphologies coated graphene foam as integrated anodes for lithium-ion batteries

Jinxiao Shao et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2018)

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Article Chemistry, Physical

Metal organic frameworks derived cobalt sulfide/reduced graphene oxide composites with fast reaction kinetic and excellent structural stability for sodium storage

Jing Huang et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2018)

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Article Chemistry, Multidisciplinary

Single Cobalt Atoms Anchored on Porous N-Doped Graphene with Dual Reaction Sites for Efficient Fenton-like Catalysis

Xuning Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Multidisciplinary

Edge-Site Engineering of Atomically Dispersed Fe-N4 by Selective C-N Bond Cleavage for Enhanced Oxygen Reduction Reaction Activities

Rui Jiang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Multidisciplinary

N2 Electrochemical Reduction: Achieving a Record-High Yield Rate of 120.9 μgNH3 mgcat.−1 h−1 for N2 Electrochemical Reduction over Ru Single-Atom Catalysts (Adv. Mater. 40/2018)

Zhigang Geng et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Physical

Apically Co- nanoparticles- wrapped nitrogendoped carbon nanotubes from a single- source MOF for efficient oxygen reduction

Lin Ma et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Review Chemistry, Multidisciplinary

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