4.8 Article

Surface charge as activity descriptors for electrochemical CO2 reduction to multi-carbon products on organic-functionalised Cu

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Multidisciplinary Sciences

Achieving net-zero greenhouse gas emission plastics by a circular carbon economy

Raoul Meys et al.

Summary: Achieving net-zero emission plastics can be done by combining biomass and CO2 utilization with increased recycling rates, which can save a significant amount of energy. To realize the potential cost savings, it is important to lower production costs, incentivize large-scale recycling, and reduce investment barriers for technologies using renewable carbon feedstock.

SCIENCE (2021)

Article Multidisciplinary Sciences

Bayesian data analysis reveals no preference for cardinal Tafel slopes in CO2 reduction electrocatalysis

Aditya M. Limaye et al.

Summary: The authors introduce a Bayesian data analysis approach to estimate the Tafel slope of electrochemical catalysts, providing robust uncertainty estimates and alleviating the need for human intervention. By re-analyzing data from the CO2 reduction literature, they find no systematic preference for certain cardinal Tafel slopes.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Dynamic Boundary Layer Simulation of Pulsed CO2 Electrolysis on a Copper Catalyst

Justin C. Bui et al.

Summary: The study found that pulsed electrolysis induces dynamic changes in pH and CO2 concentration near the Cu surface, leading to an enhanced faradaic efficiency of C2+ products. By exploring various pulse shapes, operating conditions that maximize the rate of C2+ product formation while minimizing the rates of other products formation can be established.

ACS ENERGY LETTERS (2021)

Article Electrochemistry

Reconstruction of Copper Nanoparticles at Electrochemical CO2 Reduction Reaction Conditions Occurs via Two-step Dissolution/Redeposition Mechanism

Stefan Popovic et al.

Summary: In this study, pulse-electrodeposited copper nanoparticles were exposed to different ERC relevant reductive potentials and tracked with identical location scanning electron microscopy (IL-SEM) to gain insight into the reconstruction events. The observed structural changes were interpreted as two separate electrochemical processes occurring sequentially, involving copper dissolution and redeposition of dissolved copper species.

CHEMELECTROCHEM (2021)

Article Chemistry, Physical

Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution

Mariana C. O. Monteiro et al.

Summary: The study found that metal cations play a crucial role in stabilizing the CO2 intermediate during the reduction process on gold electrodes. Density functional theory simulations confirmed that partially desolvated metal cations enable the reduction by stabilizing the CO2- intermediate through short-range electrostatic interactions. In conclusion, the positively charged species from the electrolyte are key to stabilizing the crucial reaction intermediate.

NATURE CATALYSIS (2021)

Article Green & Sustainable Science & Technology

Techno-economic assessment of low-temperature carbon dioxide electrolysis

Haeun Shin et al.

Summary: This work provides a comprehensive techno-economic assessment of four major products of low-temperature CO2 electrolysis and prioritizes technological development with systematic guidelines to facilitate market deployment.

NATURE SUSTAINABILITY (2021)

Article Multidisciplinary Sciences

Electrochemical impedance spectroscopy

Shangshang Wang et al.

Summary: This paper introduces the application of electrochemical impedance spectroscopy (EIS), analyzes the error structure and sensitivity of impedance measurements in the reduction of ferricyanide process, and provides guidelines for experimental design. The relevance of accuracy contour plots to wiring and instrumentation selection is highlighted, as well as the importance of the Kramers-Kronig relations to data validation and analysis.

NATURE REVIEWS METHODS PRIMERS (2021)

Article Multidisciplinary Sciences

Accelerated discovery of CO2 electrocatalysts using active machine learning

Miao Zhong et al.

NATURE (2020)

Article Chemistry, Multidisciplinary

Dynamic Reoxidation/Reduction-Driven Atomic Interdiffusion for Highly Selective CO2 Reduction toward Methane

Chia-Jui Chang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Multidisciplinary Sciences

Key role of chemistry versus bias in electrocatalytic oxygen evolution

Hong Nhan Nong et al.

NATURE (2020)

Review Chemistry, Multidisciplinary

Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts

Yao Zheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Physical

Self-gating in semiconductor electrocatalysis

Yongmin He et al.

NATURE MATERIALS (2019)

Article Chemistry, Physical

Bio-inspired hydrophobicity promotes CO2 reduction on a Cu surface

David Wakerley et al.

NATURE MATERIALS (2019)

Article Chemistry, Physical

How cations affect the electric double layer and the rates and selectivity of electrocatalytic processes

Matthias M. Waegele et al.

JOURNAL OF CHEMICAL PHYSICS (2019)

Article Nanoscience & Nanotechnology

On the Role of Sulfur for the Selective Electrochemical Reduction of CO2 to Formate on CuSx Catalysts

Yilin Deng et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Efficient electrochemical transformation of CO2 to C2/C3 chemicals on benzimidazole-functionalized copper surfaces

Shenghong Zhong et al.

CHEMICAL COMMUNICATIONS (2018)

Review Chemistry, Physical

Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques

Albertus D. Handoko et al.

NATURE CATALYSIS (2018)

Review Chemistry, Physical

What Should We Make with CO2 and How Can We Make It?

Oleksandr S. Bushuyev et al.

Article Chemistry, Multidisciplinary

Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide

Joaquin Resasco et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Multidisciplinary Sciences

Selective increase in CO2 electroreduction activity at grain-boundary surface terminations

Ruperto G. Mariano et al.

SCIENCE (2017)

Article Engineering, Environmental

Reaction kinetics and mechanism between histidine and carbon dioxide

Guoping Hu et al.

CHEMICAL ENGINEERING JOURNAL (2017)

Article Chemistry, Physical

Mechanistic Insights into the Selective Electroreduction of Carbon Dioxide to Ethylene on Cu2O-Derived Copper Catalysts

Albertus D. Handoko et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

Article Chemistry, Multidisciplinary

Introducing structural sensitivity into adsorption-energy scaling relations by means of coordination numbers

Federico Calle-Vallejo et al.

NATURE CHEMISTRY (2015)

Article Biochemical Research Methods

Structure of the ordered hydration of amino acids in proteins: analysis of crystal structures

Lada Biedermannova et al.

ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY (2015)

Article Multidisciplinary Sciences

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials

Brian A. Rosen et al.

SCIENCE (2011)

Article Chemistry, Physical

A climbing image nudged elastic band method for finding saddle points and minimum energy paths

G Henkelman et al.

JOURNAL OF CHEMICAL PHYSICS (2000)