4.1 Article

Copper and Silver Complexes of N-Heterocyclic Carbene-Parent Phosphinidene Adducts

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Organic

N-Heterocyclic Carbene-Phosphinidenide Complexes as Hydroboration Catalysts

Jayeeta Bhattacharjee et al.

Summary: The reactions of N-heterocyclic carbene-phosphinidene adducts with dinuclear ruthenium and osmium complexes resulted in the formation of half-sandwich complexes with different geometries. The ruthenium complex showed high activity in the hydroboration of various substrates under mild reaction conditions. Preliminary mechanistic and kinetic studies suggested the formation of a monohydride complex as the catalytically active species.

JOURNAL OF ORGANIC CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

NHC-Stabilized Parent Phosphinidene Adducts of Metal(II) Hexamethyldisilazanides of Manganese - Cobalt and Their Lability in Solution

Ruth Weller et al.

Summary: The behavior of the N-heterocyclic carbene stabilized phosphinidene towards 3d-metal(II) hexamethyldisilazanides was studied. It was found that three-coordinated phosphinidene adducts were formed. These compounds exhibited strong paramagnetism in solution, limiting NMR spectroscopic examinations.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2022)

Article Chemistry, Inorganic & Nuclear

Cationic Iridium(I) NHC-Phosphinidene Complexes and Their Application in Hydrogen Isotope Exchange Reactions

Marius Peters et al.

Summary: This study reports the synthesis of novel iridium complexes and their application in catalytic reactions. Neutral and cationic complexes were obtained through reactions with specific ligands, and these complexes exhibited high activity in catalytic reactions of aromatic substrates.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Isoselective Polymerization of rac-Lactide by Aluminum Complexes of N-Heterocyclic Carbene-Phosphinidene Adducts

Jayeeta Bhattacharjee et al.

Summary: The NHC-phosphinidene adducts reacted with AlMe3 to generate monoaluminum and dialuminum complexes, which were found to act as efficient initiators for ring-opening polymerization of rac-lactide. The monoaluminum complexes produced highly isoselective poly(rac-lactide), while the dialuminum complex resulted in almost atactic polymers, indicating the importance of the coordination-insertion mechanism with carbene-phosphinidene ligands as stereodirecting groups.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Review Chemistry, Multidisciplinary

N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry

Adinarayana Doddi et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Inorganic & Nuclear

Synthesis and Structures of RhI and IrI Complexes Supported by N-Heterocyclic Carbene-Phosphinidene Adducts

Adinarayana Doddi et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2019)

Article Chemistry, Multidisciplinary

Synthesis, properties & applications of N-heterocyclic olefins in catalysis

Stefan Naumann

CHEMICAL COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Recent Advances in Imidazoliumyl-Substituted Phosphorus Compounds

Kai Schwedtmann et al.

CHEMISTRY-AN ASIAN JOURNAL (2018)

Review Chemistry, Inorganic & Nuclear

N-Heterocyclic Carbene-Phosphinidene Adducts: Synthesis, Properties, and Applications

Tetiana Krachko et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Preparation and Characterization of P2BCh Ring Systems (Ch=S, Se) and Their Reactivity with N-Heterocyclic Carbenes

Cameron M. E. Graham et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Chemistry, Inorganic & Nuclear

N-Heterocyclic Carbene-Phosphinidene and Carbene-Phosphinidenide Transition Metal Complexes

Marius Peters et al.

INORGANIC CHEMISTRY (2017)

Review Chemistry, Multidisciplinary

Pushing Chemical Boundaries with N-Heterocyclic Olefins (NHOs): From Catalysis to Main Group Element Chemistry

Matthew M. D. Roy et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

Article Chemistry, Inorganic & Nuclear

Direct Access to Inversely Polarized Phosphaalkenes from Elemental Phosphorus or Polyphosphides

Mario Cicac-Hudi et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2016)

Article Chemistry, Inorganic & Nuclear

Transition-Metal Carbonyl Complexes and Electron-Donating Properties of N-Heterocyclic-Carbene-Phosphinidene Adducts

Dirk Bockfeld et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2016)

Article Chemistry, Inorganic & Nuclear

NHC-stabilized tungsten pentacarbonyl and boron trihydride phosphinidene adducts

Otfried Lemp et al.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS (2016)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Phosphinidene Complexes of the Coinage Metals

Adinarayana Doddi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Article Chemistry, Inorganic & Nuclear

Copper(I), silver(I) and gold(I) complexes of N-heterocyclic carbene-phosphinidene

Venkata A. K. Adiraju et al.

DALTON TRANSACTIONS (2015)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Phosphinidyne Transition Metal Complexes

Adinarayana Doddi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

Reactivity study of low-coordinate phosphaalkene IMes=PPh with Grubbs first-generation ruthenium benzylidene complexes

Timothy G. Larocque et al.

NEW JOURNAL OF CHEMISTRY (2014)

Article Chemistry, Multidisciplinary

31PNMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

Olivier Back et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Article Chemistry, Multidisciplinary

Triphenylphosphane complex formation with hexyn-1-yl silver

U Létinois-Halbes et al.

MAGNETIC RESONANCE IN CHEMISTRY (2004)

Article Chemistry, Inorganic & Nuclear

Copper complexes of inversely polarized phosphaalkenen RP=C(NMe2)(2) (R = t-Bu, Ph). Molecular structure of [Cu3Cl3{mu-P(t-Bu)C(NMe2)(2)}(3)]

L Weber et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2004)

Article Chemistry, Inorganic & Nuclear

Substituent effects in polarized phosphaalkenes: a theoretical study of aminocarbene-phosphinidene adducts

G Frison et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2002)