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Nanoplastic detection with surface enhanced Raman spectroscopy: Present and future

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2023)

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Summary: The novel nanowell-enhanced Raman spectroscopy (NWERS) substrate developed by exploiting the coffee ring effect on self-assembled SiO2 sputtered with silver films can capture nanoplastics and provide a uniform testing environment. This method allows direct visualization of single polystyrene nanoplastic particles down to 200 nm and achieved a detection limit of 5 ppm in various water samples. The NWERS methodology opens a way for highly consistent SERS substrate engineering and shows great potential in nanoplastic detection.

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Particle-in-Molybdenum Disulfide-Coated Cavity Structure with a Raman Internal Standard for Sensitive Raman Detection of Water Contaminants from Ions to <300 nm Nanoplastics

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Nanoplastic occurrence in a soil amended with plastic debris

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Summary: Novel Raman substrates were prepared and utilized for sensitive detection of submicron-sized plastic spheres in water, with efficient identification achieved through the insertion of silver-coated gold nanostars into aluminum oxide nanopores to enhance detection efficiency, yielding a detection limit of 0.005%.

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Identification of polystyrene nanoplastics using surface enhanced Raman spectroscopy

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Summary: The accumulation of micro- and nanoplastics in the environment is a major global issue, with concerns about potential harm to wildlife. Identification of nanoplastics in environmental samples remains a challenge, but surface enhanced Raman spectroscopy (SERS) has been shown as a feasible approach to quickly identify and analyze trace polystyrene (PS) nanoplastics. The proposed method has the potential to further study the occurrence, formation, and transports of nanoplastics in the natural environment.

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Can Hot Spots Be Stable Enough for Surface-Enhanced Raman Scattering?

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Does triclosan adsorption on polystyrene nanoplastics modify the toxicity of single contaminants?

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