4.7 Article

Influence of tungsten carbide raw materials to microstructure and wear performance on PTA hard-facing materials with its micro-mechanism analysis

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SURFACE & COATINGS TECHNOLOGY
卷 454, 期 -, 页码 -

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2022.129200

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Tungsten carbide (WC); Plasma transferred arc (PTA) welding; Metal matrix composites (MMCs); Hardness; Wear performance; Cast tungsten carbide(WC; W2C)

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The wear performance of plasma transferred arc (PTA) welding hard-facing materials reinforced by cast WC/W2C and coarse grain WC with different shapes is investigated. The results show that the coating with coarse grain WC-Ni exhibits the best wear resistance under high applied load, and spherical reinforced particles have higher wear performance compared to angular shape. The hardness of the reinforced particles plays a more significant role in determining wear resistance. The formation of precipitates between the carbides and matrix improves the bonding strength and prevents the cast WC/W2C from being pulled out during wear.
The wear performance of the plasma transferred arc (PTA) welding hard-facing materials manufactured rein-forced by cast WC/W2C and coarse grain WC with different shapes are investigated. Coarse grain WC-Ni coating shows the best wear resistance in a high applied load condition, with spherical reinforced particles give higher wear performance than angular shape. WC, W2C, gamma-Ni, M23C6, and M7C3 (M = Cr, Fe, W, and Ni) are detected in PTA coatings. The spherical cast and angular cast WC/W2C particles contain a higher volume of W2C, which is easier to be dissolved during the PTA welding process, resulting in lower retained reinforced particle volume and more precipitates concentration. In the PTA coating, the cast WC/W2C particles have a higher hardness, whereas the matrix has a relatively low hardness. The wear performance of PTA coating is more affected by the hardness rather than the coefficient of friction (COF). At a load of 5 N applied on the Si3N4 ball, the contact area between reinforced particles and counterparts, resulting in wear resistance is controlled by the hardness of the reinforced particles. When the load increases to 10 N, the hardness of the matrix controls wear performance. The pre-cipitates formed between the carbides and matrix smooth the interface and strengthen the bonding, which prevents the cast WC/W2C from being pulled out from the matrix during the wear test.

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