Dual-mode detection sensor based on nitrogen-doped carbon dots from pine needles for the determination of Fe3+ and folic acid

In this study, nitrogen-doped carbon dots (N-CDs) from pine needles were obtained by one-step hydrothermal synthesis without any chemical reagents. The fluorescence quenching and absorbance enhancement of N-CDs occurred when Fe3+ and folic acid (FA) were added. Based on this, the dual-mode detection sensor by fluorescence and ultraviolet-visible (UV-Vis) spectrophotometry for the determination of Fe3+ and FA was established. Detected by the dual-mode detection sensor under the optimized condition, the linear range of Fe3+ was 0.1-540 mu M and FA was 0.1-165 mu M. At the same time, the two inputs NOR and OR logic gates are constructed successfully according to the dual-mode sensor signals. The proposed dual-mode detection sensor is simple, efficient and stable; it can be applied to determinate Fe3+ and FA in practical samples successfully and the results are satisfactory.

Automated summary

Nitrogen-doped carbon dots (N-CDs) were synthesized from pine needles through one-step hydrothermal synthesis without the use of any chemical reagents. The fluorescence quenching and absorbance enhancement of N-CDs were observed upon the addition of Fe3+ and folic acid (FA). A dual-mode detection sensor utilizing fluorescence and UV-Vis spectrophotometry was established for the determination of Fe3+ and FA. The sensor exhibited a linear range of 0.1-540 μM for Fe3+ and 0.1-165 μM for FA under optimized conditions. Additionally, NOR and OR logic gates were successfully constructed based on the dual-mode sensor signals. The proposed dual-mode detection sensor is simple, efficient, and stable, demonstrating successful application in the determination of Fe3+ and FA in practical samples with satisfactory results.