A Robust Switchable Oil-In-Water Emulsion Stabilized by Electrostatic Repulsions between Surfactant and Similarly Charged Carbon Dots

How to control the stability of oil-in-water (O/W) emulsions is one of the main topics for scientists working in colloidal systems. Recently, carbon dots (CDs) have received great interest as smart materials because of their excellent physicochemical properties and versatile applications. Herein, for the first time, advanced and switchable O/W emulsions are presented that are stabilized by the synergistic effect of cationic surfactant cetyltrimethylammonium bromide CTAB (emulsifier) and similarly charged CDs (stabilizer). In the formulated emulsion, the cationic surfactant molecules are adsorbed at the oil and water interface to decrease the interfacial tension and enrich the drops with a positive charge to ensure intensive electrostatic repulsions among them. On the contrary, cationic CDs are distributed in the water phase among the droplets to reduce the water secretion and prevent flocculation and droplet coalescence. The stabilizing effect is found to be universal for emulsions of a range of oil phases. Furthermore, the formulated emulsion is found to be switchable between stable and unstable modes by adding an equivalent of anionic surfactant sodium dodecyl benzene sulphonate (SDBS). The stabilized and switchable O/W emulsions are believed to have wide practical applications in water purification, pharmaceuticals, protein recognition, as well as catalysis.

Automated summary

Controlling the stability of oil-in-water emulsions is a key focus for scientists studying colloidal systems. Carbon dots have gained significant interest as smart materials due to their exceptional physicochemical properties and versatile applications. This study presents advanced and switchable O/W emulsions stabilized by the combined effect of the cationic surfactant CTAB and similarly charged CDs. The formulated emulsion shows universal stabilizing effects for a range of oil phases and can be switched between stable and unstable modes by adding anionic surfactant SDBS, with potential applications in water purification, pharmaceuticals, protein recognition, and catalysis.