The Collision between g-C3N4 and QDs in the Fields of Energy and Environment: Synergistic Effects for Efficient Photocatalysis

Recently, graphitic carbon nitride (g-C3N4) has attracted increasing interest due to its visible light absorption, suitable energy band structure, and excellent stability. However, low specific surface area, finite visible light response range (<460 nm), and rapid photogenerated electron-hole (e(-)-h(+)) pairs recombination of the pristine g-C3N4 limit its practical applications. The small size of quantum dots (QDs) endows the properties of abundant active sites, wide absorption spectrum, and adjustable bandgap, but inevitable aggregation. Studies have confirmed that the integration of g-C3N4 and QDs not only overcomes these limitations of individual component, but also successfully inherits each advantage. Encouraged by these advantages, the synthetic strategies and the fundamental of QDs/g-C3N4 composites are briefly elaborated in this review. Particularly, the synergistic effects of QDs/g-C3N4 composites are analyzed comprehensively, including the enhancement of the photocatalytic performance and the avoidance of aggregation. Then, the photocatalytic applications of QDs/g-C3N4 composites in the fields of environment and energy are described and further combined with DFT calculation to further reveal the reaction mechanisms. Moreover, the stability and reusability of QDs/g-C3N4 composites are analyzed. Finally, the future development of these composites and the solution of existing problems are prospected.

Automated summary

Recently, the integration of graphitic carbon nitride (g-C3N4) and quantum dots (QDs) has attracted attention due to its ability to overcome limitations and inherit advantages from both components. This review provides a brief elaboration on the synthetic strategies and fundamental properties of QDs/g-C3N4 composites. The synergistic effects of these composites, including enhanced photocatalytic performance and prevention of aggregation, are comprehensively analyzed. Additionally, the photocatalytic applications, reaction mechanisms, stability, and reusability of QDs/g-C3N4 composites are discussed, followed by a prospect on future developments and solutions to existing problems.