4.7 Article

Selective recovery of lithium from mother liquor of Li2CO3 by synergistic hydrophobic deep eutectic solvents: Performance and mechanistic insight

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Engineering, Chemical

Tailoring hydrophobic deep eutectic solvent for selective lithium recovery from dilute aqueous solutions

Liu-Ying Yu et al.

Summary: This study demonstrated the application of a hydrophobic deep eutectic solvent system for the efficient recovery of lithium ions from dilute aqueous solutions. The results showed that the system had high selectivity for Li+ and remained stable during multiple extraction cycles.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Geochemistry & Geophysics

Ionic Liquids for the Selective Solvent Extraction of Lithium from Aqueous Solutions: A Theoretical Selection Using COSMO-RS

Felipe Olea et al.

Summary: In this study, the theoretical design of ionic liquids (ILs) for predicting selective extraction of lithium from brines has been conducted. Theoretical results were validated using experimental extraction percentages. Based on the model, an IL was proposed to improve selectivity for lithium extraction over sodium.

MINERALS (2022)

Article Environmental Sciences

A fundamental study on selective extraction of Li+ with dibenzo-14-crown-4 ether: Toward new technology development for lithium recovery from brines

Yanhang Xiong et al.

Summary: In this study, a selective Li+ extraction process using a novel extractant DB14C4-C16 synthesized based on ion imprinting technology (IIT) was proposed. Theoretical analysis and experimental results demonstrated the good selectivity of DB14C4-C16 towards Li+ over competing ions.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

Article Chemistry, Analytical

Systematic evaluation of hydrophobic deep eutectic solvents as alternative media for the extraction of metal ions from aqueous solution

Michael J. Kaul et al.

Summary: The recent development of hydrophobic deep eutectic solvents (HDESs) has sparked interest in their potential as environmentally friendly alternatives to conventional organic media in various applications, including metal ion separations by liquid-liquid extraction. This study evaluates the facilitated transfer of selected alkali and alkaline earth cations into HDESs from aqueous solution in the presence of a macrocyclic polyether. The results suggest that the distribution of metal ions in HDES-aqueous systems is more similar to that in alcohols rather than ionic liquids.

TALANTA (2022)

Review Metallurgy & Metallurgical Engineering

Review of Lithium Production and Recovery from Minerals, Brines, and Lithium-Ion Batteries

Fei Meng et al.

Summary: This paper discusses the importance of extraction and recycling of lithium, a critical element in LIBs, as well as methods and industry standards for recovery from different sources. The article points out the potential supply crisis in the future and the need for sustainable recycling technologies.

MINERAL PROCESSING AND EXTRACTIVE METALLURGY REVIEW (2021)

Review Materials Science, Multidisciplinary

Materials for lithium recovery from salt lake brine

Ping Xu et al.

Summary: The paper provides a comprehensive overview of Mg2+/Li+ separation materials and methods in lithium recovery from salt lake brines, covering global demand for lithium resources, various separation techniques, and future directions. Strategies for developing novel methods with high separation selectivity, stability, low cost, and environmentally friendly characteristics are discussed as key to advancing the field.

JOURNAL OF MATERIALS SCIENCE (2021)

Article Chemistry, Multidisciplinary

Synergistic Deep Eutectic Solvents for Lithium Extraction

Takafumi Hanada et al.

Summary: A novel synergistic DES concept was proposed to improve the performance of liquid-liquid extraction of lithium, in which two different conventional extractants were mixed to form a liquid DES. The extraction performance of Li was greatly enhanced with the synergistic DESs, achieving highly selective recovery over Na and K. This study represents the first efficient and selective extraction of Li with DES-based liquid-liquid extraction.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Chemistry, Physical

Separation of lithium from alkaline solutions with hydrophobic deep eutectic solvents based on β-diketone

Licheng Zhang et al.

Summary: This study proposed a series of beta-diketone based DES composed of benzoyl trifluoroacetone as a hydrogen donor and compounds with different functional groups as hydrogen acceptors, which showed higher lithium capacity compared to traditional solvents. TRPO and HBTA at a specific ratio exhibited the best lithium extraction efficiency and separation effect. The stoichiometry of the complex was determined by single crystal X-ray diffraction, and the DES maintained stable extraction ability after multiple cycles.

JOURNAL OF MOLECULAR LIQUIDS (2021)

Article Engineering, Chemical

Permeability of Vesicles for Imidazolium-Based Ionic Liquids in Aqueous Solution: A Molecular Dynamic Simulation Study

Kun Jiang et al.

Summary: The self-assembly behavior of ionic liquids in aqueous solution was studied through molecular dynamics simulations, revealing the dominant role of interactions between tail groups in stabilizing vesicles and the influence of membrane thickness and alkyl chain arrangement on vesicle permeability. The interdigitated structure of tail groups reduced water exchange rate, while the orientation of the imidazolium ring promoted water molecules approaching hydrophobic regions. These findings suggest the potential for obtaining vesicles with excellent permeability properties by screening the hydrophilic and hydrophobic properties of ILs for applications in separation and drug delivery processes.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

Article Engineering, Chemical

Recent advances in magnesium/lithium separation and lithium extraction technologies from salt lake brine

Ying Sun et al.

Summary: In recent years, there has been extensive research on technologies for extracting and separating magnesium/lithium from salt lake brines, including adsorption, membrane, electrochemical, and reaction-coupled methods. While various methods have different characteristics and adaptabilities, membrane methods have attracted attention due to their low energy consumption and high separation rates.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Chemical

Novel ionic liquid as co-extractant for selective extraction of lithium ions from salt lake brines with high Mg/Li ratio

Rujie Li et al.

Summary: A novel ionic liquid was synthesized and used as co-extractants for selective extraction of lithium ions from salt lake brines with high magnesium to lithium ratio. The extraction process showed high separation efficiency and environmental friendliness, making it a promising method for lithium extraction.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Review Chemistry, Multidisciplinary

Hydrophobic deep eutectic solvents: Current progress and future directions

Mohamad Hamdi Zainal-Abidin et al.

Summary: Deep eutectic solvents (DESs) are a promising category of green solvents with biocompatibility and tunable properties. Hydrophobic DESs (HDESs), a subclass of traditional DESs, are considered to address stability issues when in contact with water. Although HDESs remain briefly addressed in the literature, they have been widely studied for the isolation and extraction of various compounds.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2021)

Article Engineering, Environmental

Tailoring hydrophobic deep eutectic solvent for selective lithium recovery from the mother liquor of Li2CO3

Wang Chen et al.

Summary: This study successfully extracted high concentration Li+ from the mother liquor using a hydrophobic deep eutectic solvent as a novel coextraction reagent, showing good selectivity, stability, and reusability.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Engineering, Chemical

An ionic liquid extractant dissolved in an ionic liquid diluent for selective extraction of Li(I) from salt lakes

Chunqing Cai et al.

Summary: This study presents an efficient extraction method for recovering lithium from salt lake solutions using a novel extraction system. The research systematically investigated the extraction conditions, demonstrating the effective use of ionic liquids as extractants for lithium, even under acidic conditions. The results also showed high selectivity for lithium over sodium and potassium in the extraction process.

DESALINATION (2021)

Article Chemistry, Medicinal

Force-Field-Based Computational Study of the Thermodynamics of a Large Set of Aqueous Alkanolamine Solvents for Post-Combustion CO2 Capture

Javad Noroozi et al.

Summary: In this study, the thermodynamic properties of a large set of aqueous alkanolamine solvent systems were successfully predicted, including pK(a) and pK(c) values, using a hybrid approach of classical molecular dynamics simulations and composite quantum chemical calculations. The newly derived H3O+ force field allowed for accurate prediction of protonation enthalpies for various alkanolamines. Additionally, the stability of carbamates and their sensitivity to electronic and steric effects were investigated.

JOURNAL OF CHEMICAL INFORMATION AND MODELING (2021)

Article Chemistry, Physical

Phase separation property of a hydrophobic deep eutectic solvent-water binary mixture: A molecular dynamics simulation study

Rabindranath Paul et al.

Summary: Deep eutectic solvents have been used in numerous fields as greener alternatives to conventional organic solvents. A hydrophobic DES composed of a 1:1 mixture of oleic acid and lidocaine possesses a unique phase separation property in water, which can be used for dye extraction from aqueous solutions.

JOURNAL OF CHEMICAL PHYSICS (2021)

Article Engineering, Chemical

Mechanism study on the synergistic effect and emulsification formation of phosphine oxide with β-diketone for lithium extraction from alkaline systems

Jian Zhang et al.

Summary: The synergistic mechanism of beta-diketone and phosphine oxide in lithium extraction has been studied intensively, revealing that the presence of one molar water in the extracted species can help mitigate emulsification formation and improve lithium selectivity.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Chemical

Highly selective extraction of lithium ions from salt lake brines with sodium tetraphenylborate as co-extractant

Zhongqi Ren et al.

Summary: This study developed a new method for selectively extracting lithium ions from high Mg/Li salt lake brine, achieving efficient extraction and separation under optimized conditions with new co-extractant and diluent. The extraction system demonstrated excellent stability and reusability, showing potential for further research and industrial applications.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Environmental

Lithium recovery from effluent of spent lithium battery recycling process using solvent extraction

Licheng Zhang et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

Article Engineering, Environmental

Boron extraction from aqueous medium using novel hydrophobic deep eutectic solvents

Ghaiath Almustafa et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Chemistry, Multidisciplinary

Understanding the Mechanism of Lithium Ion Extraction Using Tributyl Phosphate in Room Temperature Ionic Liquid

Abderrazak Masmoudi et al.

SOLVENT EXTRACTION AND ION EXCHANGE (2020)

Review Chemistry, Multidisciplinary

Deep eutectic solvents and their applications as green solvents

Filippo Maria Perna et al.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2020)

Article Engineering, Chemical

Selective recovery of lithium from simulated brine using different organic synergist

Huifang Li et al.

CHINESE JOURNAL OF CHEMICAL ENGINEERING (2019)

Article Engineering, Chemical

Lithium extraction from low-grade salt lake brine with ultrahigh Mg/Li ratio using TBP - kerosene - FeCl3 system

Dong Shi et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2019)

Article Engineering, Chemical

Lithium Recovery from the Mother Liquor Obtained in the Process of Li2CO3 Production

Junfeng Wang et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Article Chemistry, Physical

Solvent extraction of lithium from ammoniacal solution using thenoyltrifluoroacetone and neutral ligands

Licheng Zhang et al.

JOURNAL OF MOLECULAR LIQUIDS (2019)

Article Metallurgy & Metallurgical Engineering

Recovery of lithium from alkaline brine by solvent extraction with β-diketone

Licheng Zhang et al.

HYDROMETALLURGY (2018)

Article Thermodynamics

Development of a thermodynamic model for the Li2CO3-NaCl-Na2SO4-H2O system and its application

Junfeng Wang et al.

JOURNAL OF CHEMICAL THERMODYNAMICS (2018)

Article Engineering, Chemical

Selective extraction of lithium from alkaline brine using HBTA-TOPO synergistic extraction system

Licheng Zhang et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2017)

Article Engineering, Environmental

Design of lithium selective crown ethers: Synthesis, extraction and theoretical binding studies

Rey Eliseo C. Torrejos et al.

CHEMICAL ENGINEERING JOURNAL (2017)

Article Metallurgy & Metallurgical Engineering

Lithium Extraction with a Synergistic System of Dioctyl Phthalate and Tributyl Phosphate in Kerosene and FeCl3

Lianmin Ji et al.

HYDROMETALLURGY (2016)

Article Chemistry, Multidisciplinary

Hydrophobic deep eutectic solvents as water-immiscible extractants

Dannie J. G. P. van Osch et al.

GREEN CHEMISTRY (2015)

Article Metallurgy & Metallurgical Engineering

Separation of lithium from sodium in chloride solutions using SSX systems with LIX 54 and Cyanex 923

Yoko Pranolo et al.

HYDROMETALLURGY (2015)

Article Chemistry, Inorganic & Nuclear

A Study of the Hydration of the Alkali Metal Ions in Aqueous Solution

Johan Mahler et al.

INORGANIC CHEMISTRY (2012)

Article Chemistry, Inorganic & Nuclear

Synthesis, characterization, and biological activity of some lanthanide ternary complexes

Zhihui Shen et al.

JOURNAL OF COORDINATION CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

PACKMOL: A Package for Building Initial Configurations for Molecular Dynamics Simulations

L. Martinez et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2009)

Article Spectroscopy

Synthesis, spectral, and thermal characterizations of Ni(II) and Cu(II) β-diketone complexes with thenoyltrifluoroacetone ligand

Zhimin Chen et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2007)

Review Chemistry, Multidisciplinary

GROMACS: Fast, flexible, and free

D Van der Spoel et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2005)

Article Chemistry, Multidisciplinary

Development and testing of a general amber force field

JM Wang et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2004)