期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 7, 期 2, 页码 266-271出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.5b02639
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资金
- J.C. Bose Fellowship [EMR/2015/000582]
- PURSE Grant of the Department of Science and Technology (DST), Government of India
- Council of Scientific and Industrial Research (CSIR)
Study of the emission behavior of all-inorganic perovskite nanocrystals CsPbBr3 and CsPbBr2I as a function of the excitation power employing fluorescence correlation spectroscopy and conventional techniques reveals fluorescence blinking in the microsecond time scale and photoinduced emission enhancement. The observation provides insight into the radiative and nonradiative deactivation pathways of these promising substances. Because both blinking and photo activation processes are intimately linked to the charge separation efficiency and dynamics of the nanocrystals, these key findings are likely to be helpful in realizing the true potential of these substances in photovoltaic and optoelectronic applications.
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