期刊
SCRIPTA MATERIALIA
卷 224, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2022.115146
关键词
Carbides; Sintering; Acoustic methods; Mechanical properties; Ionic nature
In this study, pure polycrystalline Cr3C2 was synthesized using high pressure and high temperature method, and its sound velocities, elasticity, and mechanical properties were investigated. The results showed that Cr3C2 is more ductile than most covalent carbides, and its Vickers hardness is higher than that reported in previous studies. The intrinsic properties of Cr3C2 were obtained, relying on the advantages of sintering the pure polycrystalline ceramics.
The widespread industrial applications of binary transition metal carbides (TMCs) are closely related to their complex chemical bonds. Owing to the high number of ionic components of chromium carbide (Cr3C2), it is a challenge to accurately estimate its elasticity and mechanical properties. Pure polycrystalline Cr3C2 was syn-thesized via high pressure and high temperature method, and its sound velocities, elasticity, and mechanical properties were investigated using high-pressure ultrasonic interferometry combined with density functional theory calculations. Furthermore, its bulk modulus, shear modulus, Young's modulus, Poisson's ratio, and Vickers hardness were 319 GPa, 182 GPa, 459 GPa, 0.26, and 24.0 GPa, respectively. The results revealed that Cr3C2 is more ductile than most covalent carbides, and its Vickers hardness is higher than that reported in previous studies. The intrinsic properties of Cr3C2 were obtained, which are relying on the advantages of sin-tering the pure polycrystalline ceramics.
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