☆ 4.7 Editorial Material

Bimetal-containing covalent organic framework boosted photocatalytic amination

SCIENCE CHINA-CHEMISTRY (2023)

Dual Metalation in a Two-Dimensional Covalent Organic Framework for Photocatalytic C-N Cross-Coupling Reactions

Ayan Jati et al.

Summary: This study presents a dual metalation strategy using a COF TpBpy for C-N cross-coupling reactions. The strategy demonstrates controlled metalation, recyclability, and visible-light-mediated catalysis. Experimental and theoretical studies provide insights into the catalyst and reaction mechanism.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Physical

Photoredox Heterobimetallic Dual Catalysis Using Engineered Covalent Organic Frameworks

Alberto Lopez-Magano et al.

Summary: The functionalization of an imine-based layered covalent organic framework has allowed the obtention of a heterobimetallated material with photoactive Ir and Ni fragments immobilized within the porous structure. These heterogeneous light-mediated reactions showed enhanced activity and stability compared to analogous homogeneous systems.

ACS CATALYSIS (2021)

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Review Chemistry, Multidisciplinary