☆ 4.8 Article

Transition metal-free ketene formation from carbon monoxide through isolable ketenyl anions

SCIENCE (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Multidisciplinary Sciences

Accessing the main-group metal formyl scaffold through CO-activation in beryllium hydride complexes

Terrance J. Hadlington et al.

Summary: This article describes the reactivity of a range of amido-beryllium hydride complexes towards carbon monoxide and sheds light on the underexplored chemistry of beryllium hydrides, leading to a stable example of a main group metal-formyl complex.

NATURE COMMUNICATIONS (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Alkali-Metal Mediation: Diversity of Applications in Main-Group Organometallic Chemistry

Thomas X. Gentner et al.

Summary: This review highlights the longstanding importance of organolithium compounds in synthetic chemistry, while also discussing the emerging challenges presented by sodium and potassium in the field. It showcases recent examples of diverse organic reactions mediated by alkali metals, emphasizing the evolving landscape of this area of research.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reactions of a Dilithiomethane with CO and N2O: An Avenue to an Anionic Ketene and a Hexafunctionalized Benzene

Maotong Xu et al.

Summary: This study presents a transition metal-free method for synthesizing hexa-substituted benzene derivatives from simple C1 feedstocks, which is viable on a gram scale and allows for the incorporation of C-13 labels. The mechanisms of these reactions are elucidated through extensive density functional theory computations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Lithium Dicyclohexylamide in Transition-Metal-Free Fischer-Tropsch Chemistry

Maotong Xu et al.

Summary: The reaction of lithium dicyclohexylamide with syn-gas or CO generates transient intermediates with carbene character, capable of further reacting with CO or H-2 to promote C-C and C-H bond formations, providing a transition-metal-free route for fundamental Fischer-Tropsch process reactions. Experimental and computational data suggest that reactions with CO and H-2 are thermodynamically feasible, with a kinetic preference for CO homologation.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Facile Synthesis of Cyanide and Isocyanides from CO

Maotong Xu et al.

Summary: The study describes the reaction of K[N(SiMe3)(2)] with (CO)-C-13 to obtain C-13 labeled compounds under mild conditions and high yields. Crystallographic characterization and reliable DFT calculations were used to investigate the reaction mechanism.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl- and Amino-Substituted Metallated Ylide

Mike Joerges et al.

Summary: In this study, a versatile reagent for the introduction of ylide groups, alpha-Metallated ylides, was synthesized via a four-step procedure starting from diphenylmethylphosphine sulfide. The metallation of ylide intermediate with different alkali metal bases successfully delivered lithium, sodium, and potassium salts. Structural analyses of the lithium and potassium compounds revealed different aggregates in the solid state.

CHEMISTRYOPEN (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A silicon-carbonyl complex stable at room temperature

Chelladurai Ganesamoorthy et al.

NATURE CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Silylated silicon-carbonyl complexes as mimics of ubiquitous transition-metal carbonyls

Dominik Reiter et al.

NATURE CHEMISTRY (2020)

添加到收藏夹

Article Astronomy & Astrophysics

An Experimental and Theoretical Investigation into the Formation of Ketene (H2CCO) and Ethynol (HCCOH) in Interstellar Analog Ices

Andrew M. Turner et al.

ASTROPHYSICAL JOURNAL (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reduction of Carbon Oxides by an Acyclic Silylene: Reductive Coupling of CO

Andrey V. Protchenko et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Silicon-Mediated Selective Homo- and Heterocoupling of Carbon Monoxide

Yuwen Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Carbon Chain Growth by Sequential Reactions of CO and CO2 with [W(CO)6] and an Aluminum(I) Reductant

Richard Y. Kong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

The Bonding Situation in Metalated Ylides

Lennart T. Scharf et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Article Chemistry, Physical

MN15-L: A New Local Exchange-Correlation Functional for Kohn-Sham Density Functional Theory with Broad Accuracy for Atoms, Molecules, and Solids

Haoyu S. Yu et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mechanism of Molybdenum-Mediated Carbon Monoxide Deoxygenation and Coupling: Mono- and Dicarbyne Complexes Precede C-O Bond Cleavage and C-C Bond Formation

Joshua A. Buss et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reductive Cleavage of Carbon Monoxide by a Disilenide

Moumita Majumdar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis

Mathew D. Anker et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bridging the Gap between Bisylides and Methandiides: Isolation, Reactivity, and Electronic Structure of an Yldiide

Thorsten Scherpf et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Multidisciplinary Sciences

Multiple complexation of CO and related ligands to a main-group element

Holger Braunschweig et al.

NATURE (2015)

添加到收藏夹

Article Chemistry, Organic

A transition-metal-free Heck-type reaction between alkenes and alkyl iodides enabled by light in water

Wenbo Liu et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

Transition-Metal-Catalyzed Carbonylation Reactions of Olefins and Alkynes: A Personal Account

Xiao-Feng Wu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

添加到收藏夹

Review Chemistry, Multidisciplinary

Ketenes and Other Cumulenes as Reactive Intermediates

Annette D. Allen et al.

CHEMICAL REVIEWS (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Metal-free binding and coupling of carbon monoxide at a boron-boron triple bond

Holger Braunschweig et al.

NATURE CHEMISTRY (2013)

添加到收藏夹

Review Chemistry, Multidisciplinary

Applied Hydroformylation

Robert Franke et al.

CHEMICAL REVIEWS (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Multiwfn: A multifunctional wavefunction analyzer

Tian Lu et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Effect of the Damping Function in Dispersion Corrected Density Functional Theory

Stefan Grimme et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2011)

添加到收藏夹

Article Chemistry, Physical

Carbonylation of Metal Carbene with Carbon Monoxide: Generation of Ketene

Zhenhua Zhang et al.

ACS CATALYSIS (2011)

添加到收藏夹

Article Chemistry, Physical

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

Stefan Grimme et al.

JOURNAL OF CHEMICAL PHYSICS (2010)

添加到收藏夹

Review Multidisciplinary Sciences

Main-group elements as transition metals

Philip P. Power

NATURE (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Coordination chemistry at carbon

Manuel Alcarazo et al.

NATURE CHEMISTRY (2009)

添加到收藏夹

Article Chemistry, Physical

The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals

Yan Zhao et al.

THEORETICAL CHEMISTRY ACCOUNTS (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

A short history of SHELX

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2008)

添加到收藏夹

Review Chemistry, Multidisciplinary

Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels

Andrei Y. Khodakov et al.

CHEMICAL REVIEWS (2007)

添加到收藏夹

Article Multidisciplinary Sciences

Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center

Guido D. Frey et al.

SCIENCE (2007)

添加到收藏夹

Review Chemistry, Physical

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions

Yan Zhao et al.

JOURNAL OF CHEMICAL PHYSICS (2006)

添加到收藏夹

Article Chemistry, Multidisciplinary

CO fixation to stable acyclic and cyclic alkyl amino carbenes: Stable amino ketenes with a small HOMO-LUMO gap

Vincent Lavallo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

添加到收藏夹

Article Chemistry, Physical

Design of density functionals that are broadly accurate for thermochemistry, thermochemical kinetics, and nonbonded interactions

Y Zhao et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2005)

添加到收藏夹

Article Chemistry, Physical

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy

F Weigend et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2005)

添加到收藏夹

Article Chemistry, Physical

Efficient hybrid density functional calculations in solids: Assessment of the Heyd-Scuseria-Ernzerhof screened Coulomb hybrid functional

J Heyd et al.

JOURNAL OF CHEMICAL PHYSICS (2004)

添加到收藏夹

Article Chemistry, Multidisciplinary

The first structural characterisation of a group 2 metal alkylperoxide complex:: Comments on the cleavage of dioxygen by magnesium alkyl complexes

PL Bailey et al.

CHEMISTRY-A EUROPEAN JOURNAL (2003)

添加到收藏夹

Article Physics, Multidisciplinary

Climbing the density functional ladder: Nonempirical meta-generalized gradient approximation designed for molecules and solids

JM Tao et al.

PHYSICAL REVIEW LETTERS (2003)

添加到收藏夹

Article Chemistry, Multidisciplinary

Tris(trifluoromethyl)borane carbonyl, (CF3)3BCO -: Synthesis, physical, chemical and spectroscopic properties, gas phase, and solid state structure

M Finze et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.