期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 120, 期 11, 页码 6256-6261出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.6b00062
关键词
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资金
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- Office of Biological and Environmental Research
- PNNL Institutional Computing at Pacific Northwest National Laboratory
- [NSF-CHE-1255519]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1255519] Funding Source: National Science Foundation
We report the complete X-ray crystallographic structure as determined through single-crystal X-ray diffraction and a thorough theoretical analysis of the green gold Au-30(S-tBu)(18). While the structure of Au30S(S-tBu)(18) with 19 sulfur atoms has been reported, the crystal structure of Au-30(S-tBu)(18) without the mu(3)-sulfur has remained elusive until now, though matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) and electrospray ionization mass spectrometry (ESI-MS) data unequivocally show its presence in abundance. The Au-30(S-tBu)(18) nanomolecule not only is distinct in its crystal structure but also has unique temperature-dependent optical properties. Structure determination allows a rigorous comparison and an excellent agreement with theoretical predictions of structure, stability, and optical response.
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