期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 120, 期 8, 页码 4653-4659出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b12441
关键词
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资金
- JSPS [24651132]
- Grants-in-Aid for Scientific Research [24651132] Funding Source: KAKEN
The frequencies of Raman active modes of few-layer ZrS3 and ZrSe3 and their dependence on the number of layers have been investigated by Raman scattering spectroscopy and first-principles calculations. We find a considerable downshift of the frequency of the A(g)(3) mode with decreasing the number of layers, and a slight downshift of the A(g)(5) mode. The same frequency shifts are reproduced by the calculations with remarkable accuracy. We explain the difference in the frequency shifts of the A(g)(3) and A(g)(5) modes in terms of intrachain, interchain, and interlayer force constants in simple one-dimensional lattice models. We thus show that the large shift of the A(g)(3) mode reflects the quasi-one-dimensional structure of ZrS3 and ZrSe3, which does not exist in the more widely studied two-dimensional materials.
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