期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 120, 期 9, 页码 5114-5123出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b12243
关键词
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资金
- Russian Science Foundation [14-22-00143]
- China 863 project [2015AA034203]
- Ministry of Education and Science of the Russian Federation [RFMEFI59414X0009]
The barium hexaferrite, BaFe12O19, microcrystals were obtained by the flux crystal growth method and were characterized by XRD, SEM, and TEM methods. XPS measurements were carried out on a powder sample. The binding energy differences between the O 1s and cation core levels, Delta(Ba) = BE(O 1s) - BE(Ba 3d(5/2)) and Delta(Fe) = BE(O 1s) - BE(Fe 2p(3/2)), were used to characterize the valence electron transfer on the formation of Ba-O and Fe-O bonds. The chemical bonding effects were considered on the basis of our XPS results measured for BaFe12O19 and the earlier published structural and XPS data for other Ba- or Fe-containing oxide compounds. The band structure of BaFe12O19 was calculated by spin-polarized DFT methods and compared to the valence band spectrum measured by the XPS method.
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