期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 120, 期 11, 页码 6252-6255出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b12447
关键词
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资金
- National Basic Research Program [2012CB932901]
- National Natural Science Foundation of China [21203205, 61227902, 51472248]
- Beijing Natural Science Foundation [2162050]
- Chinese Academy of Sciences [KGZD-EW-T02]
The paramagnetic metallofullerenes wrapped lanthanide metals have many special properties and potential applications, especially as a single-molecule magnet. Herein, we report a spin probe of nitroxide radical for the magnetic dysprosium metallofullerenes. The nitroxide radical was connected to dysprosium metallofullerene though a cycloaddition reaction. Two kinds of dysprosium metallofullerene, DySc2N@C-80 and Dy2ScN@C-80 with different characters of molecule magnet, were selected. By means of analyzing electronic spin resonance spectra of nitroxide radical, the spin-paramagnet interactions between nitroxide and dysprosium metallofullerenes were investigated.
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