期刊
POLYMER
卷 265, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2022.125588
关键词
Cyclic perfluoroalkylene groups; Hydro-and lipo-phobicity; Fluorinated polystyrenes
In this study, a styrene derivative bearing a cyclic perfluoroalkylene group was synthesized and polymerized to obtain a polymer with increased thermal stability and comparable hydro- and oleo-phobicities to previously reported polystyrene. The newly synthesized polymer is suitable for various applications requiring high-Tg optical polymeric materials.
Perfluoroalkyl-containing aromatic compounds are predicted to have fascinating material properties. In this work, a styrene derivative bearing a cyclic perfluoroalkylene group, -(CF2)4-, was synthesized and polymerized to afford the corresponding polymer. The styrene derivative was obtained via the Ullmann coupling of I-(CF2)4-I with 3 '-bromo-4 '-iodoacetophenone, NaBH4 reduction of the ketone moiety, and dehydration using P4O10. Free-radical polymerization (FRP) of the styrene derivative afforded polymer with number-average molecular weight (Mn) and dispersity index (DI) of 1.1 x 104 and 3.1, respectively. The thermal stability of the synthesized polymer (Td10% 359 degrees C, Tg 149 degrees C) was greater than the previously reported n-C4F9-substituted polystyrene (Td10% 296 degrees C, Tg 19 degrees C). The increased thermal stability of the newly synthesized polymer is hypothesized to arise from the lack of terminal CF3 moieties. The cyclic perfluoroalkylene-substituted polystyrene exhibited hydro-and oleo-phobicities comparable to those of the n-C4F9-substituted polystyrene, suggesting that the introduction of cyclic perfluoroalkylene groups instead of the commonly used Rf groups may have the potential to develop thermo-resistant polymers with hydro-and lipo-phobicity. Thew newly synthesized polymer is suit-able for a variety of applications requiring high-Tg optical polymeric materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据