期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 120, 期 23, 页码 5301-5311出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcb.6b03870
关键词
-
资金
- Royal Society [RG130739]
- Seagate Technology (Ireland)
- Hercules Foundation [AUGE/09/024]
- Ghent University's Special Research Fund (BOF) [BOF15/PDO/091]
- EPSRC
A range of liquid rare earth chlorometallate complexes, with the alkyl-phosphoniuni cation, [P-666 14](+), has been synthesized and characterized. EXAFS Confirmed the predominant liquid-state speciation of the [LnCl(6)](3-) ion in the series with Ln = Nd, Eu, Dy. The crystal structure of the shorter-alkyl-chain cation analogue [P-4444](+) has been determined and exhibits a very large unit cell. The luminescence properties, with visible-light emissions of the liquid Tb, Eu, Pr, and Sm and the NIR emissions for the Nd and Er compounds, were determined. The effective magnetie moments were measured and fitted for the Nd, Tb, Ho, Dy, Gd, and Er samples.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据